Effects of annealing on the structure and magnetic properties of Fe–Si–Cr flakes and composite sheets

• Published in: Journal of magnetism and magnetic materials Vol. 377; pp. 436 - 440
• Main Authors: Jang, Pyungwoo, Moon, Sujin, Han, Dongwoo, Lee, Kyungsub
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-03-2015
• Subjects: Electrical resistivity; Fe–Si films; Fe–Si–Cr flake; Ordered phase; Random anisotropy; Residual stress; Random anisotropy; Fe–Si films; Electrical resistivity; Fe–Si–Cr flake; Residual stress; Ordered phase
• ISSN: 0304-8853
• DOI: 10.1016/j.jmmm.2014.10.156

Gas atomized Fe–Si–Cr powder was used in the application of a bypass sheet in near field communication. The powder was ball-milled, annealed at different temperatures and then manufactured to the sheet. Changes in microstructure and magnetic properties were investigated by XRD, VSM and an impedance analyzer. The as-milled Fe–Si–Cr flake consisted mainly of disordered A2 and ordered B2 phases while the atomized powder consisted of A2, B2 and DO3 phases. Increases in the annealing temperature caused the formation of a DO3 phase. At temperatures higher than 923K, the final flake consisted of only A2 and DO3 phases. Grain size increased abruptly from 823K, while the size of the DO3 phase increased rapidly from 623K. Coercivity of the flake decreased after annealing, with the lowest coercivity obtained after 923K annealing while saturation magnetization showed a minimum value of 928kA/m after 523K annealing. Sputtered Fe–12%Si films showed a highest electrical resistivity value of 191μΩ·cm after 623K annealing while the resistivity of Fe–4%Si sputtered films decreased almost linearly with annealing temperature. Therefore it could be concluded that high permeability of the 623K sheet at 13.56MHz and low permeability of the 923K sheet at 80MHz were due to the high resistivity as well as nanostructure of the 623K flake.
•Phase analysis in the atomized, milled and annealed powder by XRD.•Relationship between permeability and microstructure.•Variation of resistivity of Fe–Si films with annealing temperature.