Treatment of oily sludge by two-stage wet air oxidation
Oily sludge produced in petrochemical industries contains a large amount of toxic and hazardous substances. High oil sludge yield and high treatment cost have become major obstacles to the development of the petrochemical industry. In this study, the treatment and disposal of oily sludge using the w...
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| Published in: | Journal of the Energy Institute Vol. 92; no. 5; pp. 1451 - 1457 |
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| Main Authors: | , , , , , , |
| Format: | Journal Article |
| Language: | English |
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01-10-2019
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| Abstract | Oily sludge produced in petrochemical industries contains a large amount of toxic and hazardous substances. High oil sludge yield and high treatment cost have become major obstacles to the development of the petrochemical industry. In this study, the treatment and disposal of oily sludge using the wet oxidation method was investigated. Firstly, the orthogonal optimization experiment was designed to discuss the influence of reaction time, reaction temperature, oxidant amount, and emulsion splitter amount on the removal efficiency of oil and sludge volume. On this basis, a two-stage wet air oxidation method was employed to treat oily sludge. The results show that the two-stage oxidation method could remove 93.1% oil from the oil sludge and reduce the volume of oil sludge by 85.4%. Furthermore, the oil sludge treated with wet oxidation could be more easily separated from water, and the waste oil could be recycled. The proposed two-stage wet oxidation method shows excellent performance in treating oily sludge, from which resources can be recycled while reducing the amount of sludge.
•The oil sludge treated with wet oxidation could be more easily separated from water.•The waste oil could be recycled.•The biodegradability of oily sludge was enhanced.•The maximum oil content removal ratio of 93.1% and the maximum volume removal ratio of 85.4%. |
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| AbstractList | Oily sludge produced in petrochemical industries contains a large amount of toxic and hazardous substances. High oil sludge yield and high treatment cost have become major obstacles to the development of the petrochemical industry. In this study, the treatment and disposal of oily sludge using the wet oxidation method was investigated. Firstly, the orthogonal optimization experiment was designed to discuss the influence of reaction time, reaction temperature, oxidant amount, and emulsion splitter amount on the removal efficiency of oil and sludge volume. On this basis, a two-stage wet air oxidation method was employed to treat oily sludge. The results show that the two-stage oxidation method could remove 93.1% oil from the oil sludge and reduce the volume of oil sludge by 85.4%. Furthermore, the oil sludge treated with wet oxidation could be more easily separated from water, and the waste oil could be recycled. The proposed two-stage wet oxidation method shows excellent performance in treating oily sludge, from which resources can be recycled while reducing the amount of sludge.
•The oil sludge treated with wet oxidation could be more easily separated from water.•The waste oil could be recycled.•The biodegradability of oily sludge was enhanced.•The maximum oil content removal ratio of 93.1% and the maximum volume removal ratio of 85.4%. |
| Author | Deng, Ruonan Yan, Xiuyi Yang, Shuai Li, Rui Zhou, Jinghui Zhao, Yanan Wang, Baofeng |
| Author_xml | – sequence: 1 givenname: Yanan surname: Zhao fullname: Zhao, Yanan organization: College of Geosciences, China University of Petroleum, Beijing, 102249, China – sequence: 2 givenname: Xiuyi surname: Yan fullname: Yan, Xiuyi email: yanxiuyi@cup.edu.cn organization: College of Geosciences, China University of Petroleum, Beijing, 102249, China – sequence: 3 givenname: Jinghui surname: Zhou fullname: Zhou, Jinghui organization: College of Geosciences, China University of Petroleum, Beijing, 102249, China – sequence: 4 givenname: Rui surname: Li fullname: Li, Rui organization: College of Geosciences, China University of Petroleum, Beijing, 102249, China – sequence: 5 givenname: Shuai surname: Yang fullname: Yang, Shuai organization: Beijing Water Business Doctor Co., Ltd, Beijing, 100875, China – sequence: 6 givenname: Baofeng surname: Wang fullname: Wang, Baofeng organization: Beijing Water Business Doctor Co., Ltd, Beijing, 100875, China – sequence: 7 givenname: Ruonan surname: Deng fullname: Deng, Ruonan organization: Beijing Water Business Doctor Co., Ltd, Beijing, 100875, China |
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| Keywords | Removal efficiency of oil content Oxidation Oily sludge WAO Volume removal ratio |
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| Title | Treatment of oily sludge by two-stage wet air oxidation |
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