Copper(I) complexes bases on a new indazol-4,7-dione ligand
The synthesis of two new isomeric ligands, 1-(1-((2,6-diisopropylphenyl)imino)ethyl)-1H-benzo[f]indazole-4,9-dione (La) and 2-(1-((2,6-diisopropylphenyl)imino)ethyl)-2H-benzo[f]indazole-4,9-dione (Lb), and of their [Cu(I)(Lb)2] (ClO4) (1) homoleptic and [Cu(I)(Lb(PPh3)2] (ClO4) (2) heteroleptic copp...
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| Published in: | Polyhedron Vol. 62; pp. 66 - 74 |
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| Main Authors: | , , , , , , |
| Format: | Journal Article |
| Language: | English |
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07-10-2013
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| Abstract | The synthesis of two new isomeric ligands, 1-(1-((2,6-diisopropylphenyl)imino)ethyl)-1H-benzo[f]indazole-4,9-dione (La) and 2-(1-((2,6-diisopropylphenyl)imino)ethyl)-2H-benzo[f]indazole-4,9-dione (Lb), and of their [Cu(I)(Lb)2] (ClO4) (1) homoleptic and [Cu(I)(Lb(PPh3)2] (ClO4) (2) heteroleptic copper(I) complex derivatives is reported. The chemical stability, and the spectroscopic and electrochemical properties of the complexes are discussed.
Two new isomeric ligands, 1-(1-((2,6-diisopropylphenyl)imino)ethyl)-1H-benzo[f]indazole-4,9-dione (La) and 2-(1-((2,6-diisopropylphenyl)imino)ethyl)-2H-benzo[f]indazole-4,9-dione (Lb), were synthesized and fully characterized as well the derivative copper complexes; [CuI(Lb)2] (ClO4) (1) homoleptic and [CuI(Lb(PPh3)2] (ClO4) (2) heteroleptic copper(I) complexes.
The X-ray diffraction shows an irregular tetrahedral coordination around of metal in both monometallic complexes with little differences in Cu–N distances and N–Cu–N bite angles than involved the indazole ligand between two complexes.
The proton spectra show a different variation in chemical shift relative to free ligand, which was discussed by steric and magnetic current effects of another coordinated ligand. The differences in the energy of metal-to ligand-charge-transfer (MLCT) and in redox potentials to CuII/CuI process in both complexes show the notorious influence of the phosphine which by back-donating effect, modified the energy of HOMO orbital centered in Cu atom. The coordinative and redox stability in solution was established for several days in non-coordinating solvent. However in acetonitrile the ligand substitution is very fast. |
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| AbstractList | The synthesis of two new isomeric ligands, 1-(1-((2,6-diisopropylphenyl)imino)ethyl)-1H-benzo[f]indazole-4,9-dione (La) and 2-(1-((2,6-diisopropylphenyl)imino)ethyl)-2H-benzo[f]indazole-4,9-dione (Lb), and of their [Cu(I)(Lb)2] (ClO4) (1) homoleptic and [Cu(I)(Lb(PPh3)2] (ClO4) (2) heteroleptic copper(I) complex derivatives is reported. The chemical stability, and the spectroscopic and electrochemical properties of the complexes are discussed.
Two new isomeric ligands, 1-(1-((2,6-diisopropylphenyl)imino)ethyl)-1H-benzo[f]indazole-4,9-dione (La) and 2-(1-((2,6-diisopropylphenyl)imino)ethyl)-2H-benzo[f]indazole-4,9-dione (Lb), were synthesized and fully characterized as well the derivative copper complexes; [CuI(Lb)2] (ClO4) (1) homoleptic and [CuI(Lb(PPh3)2] (ClO4) (2) heteroleptic copper(I) complexes.
The X-ray diffraction shows an irregular tetrahedral coordination around of metal in both monometallic complexes with little differences in Cu–N distances and N–Cu–N bite angles than involved the indazole ligand between two complexes.
The proton spectra show a different variation in chemical shift relative to free ligand, which was discussed by steric and magnetic current effects of another coordinated ligand. The differences in the energy of metal-to ligand-charge-transfer (MLCT) and in redox potentials to CuII/CuI process in both complexes show the notorious influence of the phosphine which by back-donating effect, modified the energy of HOMO orbital centered in Cu atom. The coordinative and redox stability in solution was established for several days in non-coordinating solvent. However in acetonitrile the ligand substitution is very fast. |
| Author | Escobar, Manuel A. Fröhlich, Roland Rojas, René S. Tapia, Ricardo A. Jara, Danilo H. Guerrero, Juan Lemus, Luis |
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| Cites_doi | 10.1021/ic0201809 10.1021/ic0615224 10.1039/b910305h 10.1107/S0108767390000277 10.1021/ic970385v 10.1016/j.ica.2007.02.007 10.1039/b109518h 10.1002/adfm.200601053 10.1021/ic9018986 10.1016/S0076-6879(97)76066-X 10.1107/S0108767307043930 10.1039/b808491b 10.1107/S1600536807011932 10.1039/dt9940001649 10.1021/ja0436190 10.1016/S1387-7003(03)00036-4 10.1039/b102520c 10.1016/S0010-8545(00)00309-X 10.1002/adma.200502365 10.1002/jhet.5570390540 10.1002/adma.200306414 10.1021/ja012247h 10.1021/ic200811a 10.1021/ic951217a 10.1002/ejic.201101414 10.1002/ejic.201101356 10.1063/1.2345826 10.1021/ic0504893 10.1021/cr9601167 10.1016/j.ica.2009.01.008 10.1002/9780470132500.ch18 10.1107/S0108767303005488 10.1016/j.ica.2010.07.032 10.1021/jp3123693 10.1016/j.inoche.2011.09.005 10.1016/j.solener.2011.01.018 10.1021/ic051412h 10.1021/ja0506814 10.1039/a805548c 10.1021/ic00270a004 10.1016/S1389-5567(03)00026-1 10.1039/b000703j 10.1002/adfm.200500691 10.1016/j.ica.2008.08.036 |
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| Keywords | Homoleptic copper(I) Heteroleptic copper(I) Copper(I) complex Indazol-4,7 dione |
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| References | Douce, Charbonniere, Cesario, Ziessel (b0220) 2001; 25 Kuang, Cuttell, McMillin, Fanwick, Walton (b0120) 2002; 41 Sakaki, Kurori, Hamada (b0020) 2002 Hattori, Wada, Yanagida, Fukuzumi (b0095) 2005; 127 Grätzel (b0075) 2003; 4 Amaroli, Accorsi, Holler, Moudam, Nierengarten, Zhou, Wegh, Welter (b0115) 2006; 18 Kubas (b0155) 1979; 19 McMillin, McNett (b0060) 1998; 98 Guerrero, Cortéz, Lemus, Farías, Costamagna, Pettinari, Rossi, Caruso (b0130) 2010; 363 Wang, Klein, Humphry-Baker, Zakeeruddin, Grätzel (b0080) 2005; 127 McCormick, Jia, Wang (b0200) 2006; 45 Hu, Schneider, Price, Pye, Dawe, Kerton (b0190) 2012 Nazeeruddin, Baranoff, Grätzel (b0070) 2011; 45 Jara, Lemus, Farías, Freire, Baggio, Guerrero (b0135) 2012 Lemus, Guerrero, Costamagna, Estiu, Ferraudi, Lappin, Oliver, Noll (b0140) 2010; 49 Kunkely, Vogler (b0050) 2003; 6 Gandhi, Green, Burstyn (b0010) 2007; 46 Alonse-Vante, Nierengarten, Sauvage (b0025) 1994 Zhang, Zhou, Cheng, Wang, Ma, Jing, Wang (b0035) 2004; 16 Che, Su, Li, Chu, Li (b0055) 2006; 89 Scott, Gordon, Burrell (b0215) 1996; 35 Scaltrito, Thompson, O’Callaghan, Meyer (b0015) 2000; 208 Czerwieniec, Yu, Yersin (b0045) 2011; 50 Cuttel, Kuang, Fanwick, McMillin, Walton (b0125) 2002; 124 Chen, Cao, Gu, Wen, Shi, Rong, Luo (b0185) 2011; 14 Fu, Gan, Jiao, Chen, Yuan, Chi, Yu, Xiong (b0210) 2007; 360 Palmer, McMillin (b0180) 1987; 26 Jahng, Hazelrigg, Kimball, Riesgo, Wu, Thummel (b0205) 1997; 36 Jia, McCormick, Tao, Lu, Wang (b0110) 2005; 44 Tapia, Carrasco, Ojeda, Salas, Valderrama, Morello, Repetto (b0150) 2002; 39 Ashbrook, Elliott (b0085) 2013; 117 Zhang, Ding, Cheng (b0100) 2007; 17 Sheldrick (b0175) 2008; 64 Otwinowski, Borek, Majewski, Minor (b0165) 2003; 59 Massa, Dehghanpour, Jahani (b0005) 2009; 362 Zhang, Zhou, Cheng, Wang, Ma, Jing, Wang (b0105) 2006; 16 Armaroli (b0030) 2001; 30 Boeré, Klassen, Wolmershäuser (b0145) 1998 Sheldrick (b0170) 1990; 46 Boudebous, Constable (b0065) 2009; 362 Bessho, Constable, Grätzel, Hernandez, Housecroft, Kylberg, Nazeeruddin, Neuburger, Shaffner (b0090) 2008 Otwinowski, Minor (b0160) 1997; 276 Wang, Li, Liu, Zhang, Zuo, Shi (b0040) 2009; 39 Navarro, Corona, Gonzalez (b0195) 2007; 63 Amaroli (10.1016/j.poly.2013.06.020_b0115) 2006; 18 Otwinowski (10.1016/j.poly.2013.06.020_b0160) 1997; 276 Boeré (10.1016/j.poly.2013.06.020_b0145) 1998 Wang (10.1016/j.poly.2013.06.020_b0040) 2009; 39 Fu (10.1016/j.poly.2013.06.020_b0210) 2007; 360 Nazeeruddin (10.1016/j.poly.2013.06.020_b0070) 2011; 45 Jara (10.1016/j.poly.2013.06.020_b0135) 2012 Armaroli (10.1016/j.poly.2013.06.020_b0030) 2001; 30 Hattori (10.1016/j.poly.2013.06.020_b0095) 2005; 127 Che (10.1016/j.poly.2013.06.020_b0055) 2006; 89 Otwinowski (10.1016/j.poly.2013.06.020_b0165) 2003; 59 Ashbrook (10.1016/j.poly.2013.06.020_b0085) 2013; 117 Massa (10.1016/j.poly.2013.06.020_b0005) 2009; 362 Kunkely (10.1016/j.poly.2013.06.020_b0050) 2003; 6 Palmer (10.1016/j.poly.2013.06.020_b0180) 1987; 26 Jahng (10.1016/j.poly.2013.06.020_b0205) 1997; 36 McCormick (10.1016/j.poly.2013.06.020_b0200) 2006; 45 Lemus (10.1016/j.poly.2013.06.020_b0140) 2010; 49 Zhang (10.1016/j.poly.2013.06.020_b0105) 2006; 16 Sheldrick (10.1016/j.poly.2013.06.020_b0175) 2008; 64 Scaltrito (10.1016/j.poly.2013.06.020_b0015) 2000; 208 Alonse-Vante (10.1016/j.poly.2013.06.020_b0025) 1994 Boudebous (10.1016/j.poly.2013.06.020_b0065) 2009; 362 Kuang (10.1016/j.poly.2013.06.020_b0120) 2002; 41 Grätzel (10.1016/j.poly.2013.06.020_b0075) 2003; 4 Chen (10.1016/j.poly.2013.06.020_b0185) 2011; 14 Guerrero (10.1016/j.poly.2013.06.020_b0130) 2010; 363 Wang (10.1016/j.poly.2013.06.020_b0080) 2005; 127 Bessho (10.1016/j.poly.2013.06.020_b0090) 2008 Cuttel (10.1016/j.poly.2013.06.020_b0125) 2002; 124 Scott (10.1016/j.poly.2013.06.020_b0215) 1996; 35 Hu (10.1016/j.poly.2013.06.020_b0190) 2012 Tapia (10.1016/j.poly.2013.06.020_b0150) 2002; 39 Jia (10.1016/j.poly.2013.06.020_b0110) 2005; 44 Navarro (10.1016/j.poly.2013.06.020_b0195) 2007; 63 Zhang (10.1016/j.poly.2013.06.020_b0035) 2004; 16 Czerwieniec (10.1016/j.poly.2013.06.020_b0045) 2011; 50 Zhang (10.1016/j.poly.2013.06.020_b0100) 2007; 17 Gandhi (10.1016/j.poly.2013.06.020_b0010) 2007; 46 Kubas (10.1016/j.poly.2013.06.020_b0155) 1979; 19 Douce (10.1016/j.poly.2013.06.020_b0220) 2001; 25 Sakaki (10.1016/j.poly.2013.06.020_b0020) 2002 McMillin (10.1016/j.poly.2013.06.020_b0060) 1998; 98 Sheldrick (10.1016/j.poly.2013.06.020_b0170) 1990; 46 |
| References_xml | – volume: 127 start-page: 808 year: 2005 ident: b0080 publication-title: J. Am. Chem. Soc. contributor: fullname: Grätzel – volume: 89 start-page: 103511 year: 2006 ident: b0055 publication-title: Appl. Phys. Lett. contributor: fullname: Li – volume: 63 start-page: 1153 year: 2007 ident: b0195 publication-title: Acta Crystallogr., Sect. E contributor: fullname: Gonzalez – volume: 45 start-page: 1172 year: 2011 ident: b0070 publication-title: Sol. Energy contributor: fullname: Grätzel – volume: 50 start-page: 8293 year: 2011 ident: b0045 publication-title: Inorg. Chem. contributor: fullname: Yersin – volume: 19 start-page: 90 year: 1979 ident: b0155 publication-title: Inorg. Synth. contributor: fullname: Kubas – volume: 17 start-page: 2983 year: 2007 ident: b0100 publication-title: Adv. Funct. Mater. contributor: fullname: Cheng – volume: 41 start-page: 3313 year: 2002 ident: b0120 publication-title: Inorg. Chem. contributor: fullname: Walton – volume: 208 start-page: 243 year: 2000 ident: b0015 publication-title: Coord. Chem. Rev. contributor: fullname: Meyer – start-page: 4147 year: 1998 ident: b0145 publication-title: J. Chem. Soc., Dalton Trans. contributor: fullname: Wolmershäuser – start-page: 1649 year: 1994 ident: b0025 publication-title: J. Chem. Soc., Dalton Trans. contributor: fullname: Sauvage – volume: 124 start-page: 6 year: 2002 ident: b0125 publication-title: J. Am. Chem. Soc. contributor: fullname: Walton – volume: 16 start-page: 432 year: 2004 ident: b0035 publication-title: Adv. Mater. contributor: fullname: Wang – volume: 4 start-page: 145 year: 2003 ident: b0075 publication-title: J. Photochem. Photobiol. C contributor: fullname: Grätzel – volume: 16 start-page: 1203 year: 2006 ident: b0105 publication-title: Adv. Funct. Mater. contributor: fullname: Wang – volume: 59 start-page: 228 year: 2003 ident: b0165 publication-title: Acta Crystallogr., Sect. A contributor: fullname: Minor – volume: 117 start-page: 3853 year: 2013 ident: b0085 publication-title: J. Phys. Chem. C contributor: fullname: Elliott – volume: 46 start-page: 3816 year: 2007 ident: b0010 publication-title: Inorg. Chem. contributor: fullname: Burstyn – volume: 362 start-page: 2872 year: 2009 ident: b0005 publication-title: Inorg. Chim. Acta contributor: fullname: Jahani – volume: 44 start-page: 5706 year: 2005 ident: b0110 publication-title: Inorg. Chem. contributor: fullname: Wang – volume: 276 start-page: 307 year: 1997 ident: b0160 publication-title: Methods Enzymol. contributor: fullname: Minor – volume: 64 start-page: 112 year: 2008 ident: b0175 publication-title: Acta Crystallogr., Sect. A contributor: fullname: Sheldrick – start-page: 1773 year: 2012 ident: b0190 publication-title: Eur. J. Inorg. Chem. contributor: fullname: Kerton – volume: 362 start-page: 1825 year: 2009 ident: b0065 publication-title: Inorg. Chim. Acta contributor: fullname: Constable – start-page: 3717 year: 2008 ident: b0090 publication-title: Chem. Commun. contributor: fullname: Shaffner – volume: 39 start-page: 5868 year: 2009 ident: b0040 publication-title: Chem. Commun. contributor: fullname: Shi – volume: 39 start-page: 1093 year: 2002 ident: b0150 publication-title: J. Heterocycl. Chem. contributor: fullname: Repetto – volume: 98 start-page: 1201 year: 1998 ident: b0060 publication-title: Chem. Rev. contributor: fullname: McNett – volume: 6 start-page: 543 year: 2003 ident: b0050 publication-title: Inorg. Chem. Commun. contributor: fullname: Vogler – volume: 36 start-page: 5390 year: 1997 ident: b0205 publication-title: Inorg. Chem. contributor: fullname: Thummel – volume: 25 start-page: 1024 year: 2001 ident: b0220 publication-title: New J. Chem. contributor: fullname: Ziessel – volume: 18 start-page: 1313 year: 2006 ident: b0115 publication-title: Adv. Mater. contributor: fullname: Welter – volume: 26 start-page: 3837 year: 1987 ident: b0180 publication-title: Inorg. Chem. contributor: fullname: McMillin – start-page: 1579 year: 2012 ident: b0135 publication-title: Eur. J. Inorg. Chem. contributor: fullname: Guerrero – volume: 30 start-page: 113 year: 2001 ident: b0030 publication-title: Chem. Soc. Rev. contributor: fullname: Armaroli – volume: 35 start-page: 2452 year: 1996 ident: b0215 publication-title: Inorg. Chem. contributor: fullname: Burrell – volume: 360 start-page: 2758 year: 2007 ident: b0210 publication-title: Inorg. Chim. Acta contributor: fullname: Xiong – volume: 127 start-page: 9648 year: 2005 ident: b0095 publication-title: J. Am. Chem. Soc. contributor: fullname: Fukuzumi – volume: 45 start-page: 147 year: 2006 ident: b0200 publication-title: Inorg. Chem. contributor: fullname: Wang – start-page: 840 year: 2002 ident: b0020 publication-title: J. Chem. Soc., Dalton Trans. contributor: fullname: Hamada – volume: 46 start-page: 467 year: 1990 ident: b0170 publication-title: Acta Crystallogr., Sect. A contributor: fullname: Sheldrick – volume: 363 start-page: 3809 year: 2010 ident: b0130 publication-title: Inorg. Chim. Acta contributor: fullname: Caruso – volume: 49 start-page: 4023 year: 2010 ident: b0140 publication-title: Inorg. Chem. contributor: fullname: Noll – volume: 14 start-page: 1894 year: 2011 ident: b0185 publication-title: Inorg. Chem. Commun. contributor: fullname: Luo – volume: 41 start-page: 3313 year: 2002 ident: 10.1016/j.poly.2013.06.020_b0120 publication-title: Inorg. Chem. doi: 10.1021/ic0201809 contributor: fullname: Kuang – volume: 46 start-page: 3816 year: 2007 ident: 10.1016/j.poly.2013.06.020_b0010 publication-title: Inorg. Chem. doi: 10.1021/ic0615224 contributor: fullname: Gandhi – volume: 39 start-page: 5868 year: 2009 ident: 10.1016/j.poly.2013.06.020_b0040 publication-title: Chem. Commun. doi: 10.1039/b910305h contributor: fullname: Wang – volume: 46 start-page: 467 year: 1990 ident: 10.1016/j.poly.2013.06.020_b0170 publication-title: Acta Crystallogr., Sect. A doi: 10.1107/S0108767390000277 contributor: fullname: Sheldrick – volume: 36 start-page: 5390 year: 1997 ident: 10.1016/j.poly.2013.06.020_b0205 publication-title: Inorg. Chem. doi: 10.1021/ic970385v contributor: fullname: Jahng – volume: 360 start-page: 2758 year: 2007 ident: 10.1016/j.poly.2013.06.020_b0210 publication-title: Inorg. Chim. Acta doi: 10.1016/j.ica.2007.02.007 contributor: fullname: Fu – start-page: 840 year: 2002 ident: 10.1016/j.poly.2013.06.020_b0020 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/b109518h contributor: fullname: Sakaki – volume: 17 start-page: 2983 year: 2007 ident: 10.1016/j.poly.2013.06.020_b0100 publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.200601053 contributor: fullname: Zhang – volume: 49 start-page: 4023 year: 2010 ident: 10.1016/j.poly.2013.06.020_b0140 publication-title: Inorg. Chem. doi: 10.1021/ic9018986 contributor: fullname: Lemus – volume: 276 start-page: 307 year: 1997 ident: 10.1016/j.poly.2013.06.020_b0160 publication-title: Methods Enzymol. doi: 10.1016/S0076-6879(97)76066-X contributor: fullname: Otwinowski – volume: 64 start-page: 112 year: 2008 ident: 10.1016/j.poly.2013.06.020_b0175 publication-title: Acta Crystallogr., Sect. A doi: 10.1107/S0108767307043930 contributor: fullname: Sheldrick – start-page: 3717 year: 2008 ident: 10.1016/j.poly.2013.06.020_b0090 publication-title: Chem. Commun. doi: 10.1039/b808491b contributor: fullname: Bessho – volume: 63 start-page: 1153 year: 2007 ident: 10.1016/j.poly.2013.06.020_b0195 publication-title: Acta Crystallogr., Sect. E doi: 10.1107/S1600536807011932 contributor: fullname: Navarro – start-page: 1649 year: 1994 ident: 10.1016/j.poly.2013.06.020_b0025 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/dt9940001649 contributor: fullname: Alonse-Vante – volume: 127 start-page: 808 year: 2005 ident: 10.1016/j.poly.2013.06.020_b0080 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0436190 contributor: fullname: Wang – volume: 6 start-page: 543 year: 2003 ident: 10.1016/j.poly.2013.06.020_b0050 publication-title: Inorg. Chem. Commun. doi: 10.1016/S1387-7003(03)00036-4 contributor: fullname: Kunkely – volume: 25 start-page: 1024 year: 2001 ident: 10.1016/j.poly.2013.06.020_b0220 publication-title: New J. Chem. doi: 10.1039/b102520c contributor: fullname: Douce – volume: 208 start-page: 243 year: 2000 ident: 10.1016/j.poly.2013.06.020_b0015 publication-title: Coord. Chem. Rev. doi: 10.1016/S0010-8545(00)00309-X contributor: fullname: Scaltrito – volume: 18 start-page: 1313 year: 2006 ident: 10.1016/j.poly.2013.06.020_b0115 publication-title: Adv. Mater. doi: 10.1002/adma.200502365 contributor: fullname: Amaroli – volume: 39 start-page: 1093 year: 2002 ident: 10.1016/j.poly.2013.06.020_b0150 publication-title: J. Heterocycl. Chem. doi: 10.1002/jhet.5570390540 contributor: fullname: Tapia – volume: 16 start-page: 432 year: 2004 ident: 10.1016/j.poly.2013.06.020_b0035 publication-title: Adv. Mater. doi: 10.1002/adma.200306414 contributor: fullname: Zhang – volume: 124 start-page: 6 year: 2002 ident: 10.1016/j.poly.2013.06.020_b0125 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja012247h contributor: fullname: Cuttel – volume: 50 start-page: 8293 year: 2011 ident: 10.1016/j.poly.2013.06.020_b0045 publication-title: Inorg. Chem. doi: 10.1021/ic200811a contributor: fullname: Czerwieniec – volume: 35 start-page: 2452 year: 1996 ident: 10.1016/j.poly.2013.06.020_b0215 publication-title: Inorg. Chem. doi: 10.1021/ic951217a contributor: fullname: Scott – start-page: 1773 year: 2012 ident: 10.1016/j.poly.2013.06.020_b0190 publication-title: Eur. J. Inorg. Chem. doi: 10.1002/ejic.201101414 contributor: fullname: Hu – start-page: 1579 year: 2012 ident: 10.1016/j.poly.2013.06.020_b0135 publication-title: Eur. J. Inorg. Chem. doi: 10.1002/ejic.201101356 contributor: fullname: Jara – volume: 89 start-page: 103511 year: 2006 ident: 10.1016/j.poly.2013.06.020_b0055 publication-title: Appl. Phys. Lett. doi: 10.1063/1.2345826 contributor: fullname: Che – volume: 44 start-page: 5706 year: 2005 ident: 10.1016/j.poly.2013.06.020_b0110 publication-title: Inorg. Chem. doi: 10.1021/ic0504893 contributor: fullname: Jia – volume: 98 start-page: 1201 year: 1998 ident: 10.1016/j.poly.2013.06.020_b0060 publication-title: Chem. Rev. doi: 10.1021/cr9601167 contributor: fullname: McMillin – volume: 362 start-page: 2872 year: 2009 ident: 10.1016/j.poly.2013.06.020_b0005 publication-title: Inorg. Chim. Acta doi: 10.1016/j.ica.2009.01.008 contributor: fullname: Massa – volume: 19 start-page: 90 year: 1979 ident: 10.1016/j.poly.2013.06.020_b0155 publication-title: Inorg. Synth. doi: 10.1002/9780470132500.ch18 contributor: fullname: Kubas – volume: 59 start-page: 228 year: 2003 ident: 10.1016/j.poly.2013.06.020_b0165 publication-title: Acta Crystallogr., Sect. A doi: 10.1107/S0108767303005488 contributor: fullname: Otwinowski – volume: 363 start-page: 3809 year: 2010 ident: 10.1016/j.poly.2013.06.020_b0130 publication-title: Inorg. Chim. Acta doi: 10.1016/j.ica.2010.07.032 contributor: fullname: Guerrero – volume: 117 start-page: 3853 year: 2013 ident: 10.1016/j.poly.2013.06.020_b0085 publication-title: J. Phys. Chem. C doi: 10.1021/jp3123693 contributor: fullname: Ashbrook – volume: 14 start-page: 1894 year: 2011 ident: 10.1016/j.poly.2013.06.020_b0185 publication-title: Inorg. Chem. Commun. doi: 10.1016/j.inoche.2011.09.005 contributor: fullname: Chen – volume: 45 start-page: 1172 year: 2011 ident: 10.1016/j.poly.2013.06.020_b0070 publication-title: Sol. Energy doi: 10.1016/j.solener.2011.01.018 contributor: fullname: Nazeeruddin – volume: 45 start-page: 147 year: 2006 ident: 10.1016/j.poly.2013.06.020_b0200 publication-title: Inorg. Chem. doi: 10.1021/ic051412h contributor: fullname: McCormick – volume: 127 start-page: 9648 year: 2005 ident: 10.1016/j.poly.2013.06.020_b0095 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0506814 contributor: fullname: Hattori – start-page: 4147 year: 1998 ident: 10.1016/j.poly.2013.06.020_b0145 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/a805548c contributor: fullname: Boeré – volume: 26 start-page: 3837 year: 1987 ident: 10.1016/j.poly.2013.06.020_b0180 publication-title: Inorg. Chem. doi: 10.1021/ic00270a004 contributor: fullname: Palmer – volume: 4 start-page: 145 year: 2003 ident: 10.1016/j.poly.2013.06.020_b0075 publication-title: J. Photochem. Photobiol. C doi: 10.1016/S1389-5567(03)00026-1 contributor: fullname: Grätzel – volume: 30 start-page: 113 year: 2001 ident: 10.1016/j.poly.2013.06.020_b0030 publication-title: Chem. Soc. Rev. doi: 10.1039/b000703j contributor: fullname: Armaroli – volume: 16 start-page: 1203 year: 2006 ident: 10.1016/j.poly.2013.06.020_b0105 publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.200500691 contributor: fullname: Zhang – volume: 362 start-page: 1825 year: 2009 ident: 10.1016/j.poly.2013.06.020_b0065 publication-title: Inorg. Chim. Acta doi: 10.1016/j.ica.2008.08.036 contributor: fullname: Boudebous |
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| Title | Copper(I) complexes bases on a new indazol-4,7-dione ligand |
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