Infiltration as a frontier bandgap engineering strategy in MOFs: A critical review

•Best mechanism of bandgap modulation is the creation of intermediate energetic states between the VB and CB of the host induced by guest species infiltration.•Electron-deficient guests provide a new lower energy level conduction band of the host–guest system.•Electron-releasing guests provide a new...

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Bibliographic Details
Published in:	Coordination chemistry reviews Vol. 505; p. 215658
Main Authors:	Alfonso Herrera, Luis Ángel, Beltrán, Hiram Isaac
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 15-04-2024
Subjects:	PONs AMPA EPR DNT FeCp2 DFT BTQBT UiO ssDNA Cu-CAT-1 POMs Fluo SDS MgCp2 DOS NU-901 Py [TBA]2[Zn(DTD)2] MOFs AM DOX TGA Btc IRMOF MIL RE BCEbpy CVI PhNH2 TMOF NKU Pery SEM FLE BF TCHDE VWFs CO2 PPF RB21 PHE An PW12 BPDC NDI PtSA TCNQ EBT SO2 PPY Tpt XPS PCBM BMI CB CD ACE AgNC H3NSO3 Cor MaPbBr3 MnTBAPy OX-1 Pyr SBUs BR14 EDTA DCNA 3-TPPA BET Alq3 TTFTB CV pydc TP ZnQ DH6T mABA DMSO ImH DBF FT-IR HKUST XAS XRD Alz 3,5-PDA Td eV PBE 2-QLBM πS MB Cz DBT Ru(bpy)3Cl2·6H2O Odpt ZNT MO DPNDI MR An2Py HTTP H4TBAPy VB DCP PtNps NUS 27–29 θ bpee = 1 pBZQ PCN RGO PTA Ina g-C3N4 π NP PCU Å BY24 TTF HOMO LUMO SRG Bpy BHP Rhb DMASM DMF TNPP DUT DEF DMP H2 Lut RPM3-Zn CSMCRI-4 Pur SION-8 NENU-3 PFC-8 PTCDA FAM DNA ZIF DPAn D-D HB NZF PDOS TMU HAADF
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