Molecular sensing behavior of the first Mn(I)-compound of di-2-pyridylketone- p-nitrophenylhydrazone (dpknph), fac-[Mn(CO) 3(dpknph)Br]

Optical and thermodynamic measurement on fac-Mn(CO) 3(dpknph)Br in polar solvents reveal reversible interconversion between two intense electronic states and use as an optical sensor. Group 12 metal ions in concentration as low as 1.0 × 10 −9 M can be detected and determined using fac-Mn(CO) 3(dpknp...

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Bibliographic Details

Published in:	Inorganica Chimica Acta Vol. 358; no. 6; pp. 1835 - 1840
Main Authors:	Bakir, Mohammed, Green, Orville, Gyles, Colin
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 30-03-2005
Subjects:	Carbonyl Di-2-pyridyl ketone Hydrazones Manganese Sensors Hydrazones Sensors Carbonyl Di-2-pyridyl ketone Manganese
Online Access:	Get full text
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