The Selenium-Based Hexameric Macrocycle [(Se)P(μ-NtBu)2P(μ-Se)]6

Head‐to‐Tail: The Wurtz reaction of the dimer [(Cl)(Se)P(μ‐NtBu)]2 (1) with sodium metal gives the inorganic macrocycle [(Se)P(μ‐NtBu)2P(μ‐Se)]6 (2), arising from cyclization of a selenium‐centered nucleophilic intermediate. The inorganic macrocyclic backbone contains alternating PIII and PV cente...

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Published in:	Angewandte Chemie International Edition Vol. 47; no. 6; pp. 1111 - 1114
Main Authors:	González-Calera, Silvia, Eisler, Dana J., Morey, James V., McPartlin, Mary, Singh, Sanjay, Wright, Dominic S.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 25-01-2008 WILEY‐VCH Verlag
Subjects:	macrocycles phosphazenes selenium sodium X-ray diffraction
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Abstract	Head‐to‐Tail: The Wurtz reaction of the dimer [(Cl)(Se)P(μ‐NtBu)]2 (1) with sodium metal gives the inorganic macrocycle [(Se)P(μ‐NtBu)2P(μ‐Se)]6 (2), arising from cyclization of a selenium‐centered nucleophilic intermediate. The inorganic macrocyclic backbone contains alternating PIII and PV centers and possesses an 8.2‐Å‐diameter cavity.
AbstractList	Head‐to‐Tail: The Wurtz reaction of the dimer [(Cl)(Se)P(μ‐NtBu)]2 (1) with sodium metal gives the inorganic macrocycle [(Se)P(μ‐NtBu)2P(μ‐Se)]6 (2), arising from cyclization of a selenium‐centered nucleophilic intermediate. The inorganic macrocyclic backbone contains alternating PIII and PV centers and possesses an 8.2‐Å‐diameter cavity.
Author	Singh, Sanjay Wright, Dominic S. Eisler, Dana J. Morey, James V. González-Calera, Silvia McPartlin, Mary
Author_xml	– sequence: 1 givenname: Silvia surname: González-Calera fullname: González-Calera, Silvia organization: Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK, Fax: (+44) 122-333-6362 – sequence: 2 givenname: Dana J. surname: Eisler fullname: Eisler, Dana J. organization: Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK, Fax: (+44) 122-333-6362 – sequence: 3 givenname: James V. surname: Morey fullname: Morey, James V. organization: Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK, Fax: (+44) 122-333-6362 – sequence: 4 givenname: Mary surname: McPartlin fullname: McPartlin, Mary organization: Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK, Fax: (+44) 122-333-6362 – sequence: 5 givenname: Sanjay surname: Singh fullname: Singh, Sanjay email: ss724@cam.ac.uk organization: Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK, Fax: (+44) 122-333-6362 – sequence: 6 givenname: Dominic S. surname: Wright fullname: Wright, Dominic S. email: dsw1000@cus.cam.ac.uk organization: Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK, Fax: (+44) 122-333-6362
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/18172844$$D View this record in MEDLINE/PubMed
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Notes	ArticleID:ANIE200703981 EPSRC We gratefully acknowledge the EPSRC (S.G.-C., D.J.E., J.V.M., M.McP., S.S., D.S.W.) for financial support. We also thank the referees for valuable discussions. ark:/67375/WNG-5JTZBLZC-7 istex:D498875250E2E0A6567CE8DF0EC8A34B64F1650A We gratefully acknowledge the EPSRC (S.G.‐C., D.J.E., J.V.M., M.McP., S.S., D.S.W.) for financial support. We also thank the referees for valuable discussions. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
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Snippet	Head‐to‐Tail: The Wurtz reaction of the dimer [(Cl)(Se)P(μ‐NtBu)]2 (1) with sodium metal gives the inorganic macrocycle [(Se)P(μ‐NtBu)2P(μ‐Se)]6 (2), arising...
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SubjectTerms	macrocycles phosphazenes selenium sodium X-ray diffraction
Title	The Selenium-Based Hexameric Macrocycle [(Se)P(μ-NtBu)2P(μ-Se)]6
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