Mixture model applied to the development of polymeric fibre diaphragms
ABSTRACT The extraction and use of asbestos have been banned around the world because of its damage effects to the human health, it leads to studies of new materials in order to replace asbestos in several processes. The objective of this paper is to apply the simplex lattice planning and the mixtur...
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| Published in: | Matéria Vol. 26; no. 4 |
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Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro; em cooperação com a Associação Brasileira do Hidrogênio, ABH2
2021
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| Abstract | ABSTRACT The extraction and use of asbestos have been banned around the world because of its damage effects to the human health, it leads to studies of new materials in order to replace asbestos in several processes. The objective of this paper is to apply the simplex lattice planning and the mixture model in the manufacture of diaphragms. A mixture model was performed according to the simplex lattice, using four polyethylene microfibers (MF's) of different lengths, with 1st degree polynomial, adding inner and central points and a repetition, generating 18 mixtures. The results showed that microfibers of greater length have a greater influence on the diaphragms properties, presenting a more significant result on permeability. From the linear regression it was possible to estimate a mathematical model combining the three properties of the diaphragm, presenting a correlation of 92.12%. |
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| AbstractList | ABSTRACT The extraction and use of asbestos have been banned around the world because of its damage effects to the human health, it leads to studies of new materials in order to replace asbestos in several processes. The objective of this paper is to apply the simplex lattice planning and the mixture model in the manufacture of diaphragms. A mixture model was performed according to the simplex lattice, using four polyethylene microfibers (MF's) of different lengths, with 1st degree polynomial, adding inner and central points and a repetition, generating 18 mixtures. The results showed that microfibers of greater length have a greater influence on the diaphragms properties, presenting a more significant result on permeability. From the linear regression it was possible to estimate a mathematical model combining the three properties of the diaphragm, presenting a correlation of 92.12%. |
| Author | Moura Junior, Celso Fidelis de Silva, Rafael Teles Cruz Lira, Hélio de Lucena Nunes, Raquel Araújo Vilar, Eudésio Oliveira Cunha, Carlos Thiago Cândido |
| AuthorAffiliation | Universidade Federal de Campina Grande |
| AuthorAffiliation_xml | – name: Universidade Federal de Campina Grande |
| Author_xml | – sequence: 1 givenname: Celso Fidelis de orcidid: 0000-0002-9952-8360 surname: Moura Junior fullname: Moura Junior, Celso Fidelis de organization: Universidade Federal de Campina Grande, Brasil – sequence: 2 givenname: Raquel Araújo orcidid: 0000-0002-6812-3010 surname: Nunes fullname: Nunes, Raquel Araújo organization: Universidade Federal de Campina Grande, Brasil – sequence: 3 givenname: Rafael Teles Cruz orcidid: 0000-0003-4895-2556 surname: Silva fullname: Silva, Rafael Teles Cruz organization: Universidade Federal de Campina Grande, Brasil – sequence: 4 givenname: Hélio de Lucena orcidid: 0000-0002-1527-9935 surname: Lira fullname: Lira, Hélio de Lucena organization: Universidade Federal de Campina Grande, Brasil – sequence: 5 givenname: Carlos Thiago Cândido orcidid: 0000-0002-8469-1798 surname: Cunha fullname: Cunha, Carlos Thiago Cândido organization: Universidade Federal de Campina Grande, Brasil – sequence: 6 givenname: Eudésio Oliveira orcidid: 0000-0002-8613-1938 surname: Vilar fullname: Vilar, Eudésio Oliveira organization: Universidade Federal de Campina Grande, Brasil |
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| Cites_doi | 10.1016/j.cherd.2010.08.007 10.1080/00401706.1973.10489071 10.1111/j.2517-6161.1958.tb00299.x 10.1080/00401706.1962.10490034 10.1016/j.energy.2010.01.039 |
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| Issue | 4 |
| Keywords | polymeric diaphragm model Simplex lattice microfibers |
| Language | English |
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| References | ROMINE R. (ref5) 1977 VIANA K.M.S (ref10) 2008; 3 HINE F (ref3) 2005 NUNES D.B. (ref16) 1998 CORNELL J.A. (ref15) 1981; 3 CALDWELL D.L (ref19) 1982 CURLIN L.C (ref7) 1990; 4 CUNHA C.T.C. (ref9) 2015 SCHEFFÉ H. (ref17) 1958; 20 VIANA K.M.S (ref11) 2009 (ref2) 2017 ALMEIDA FILHO E.M. (ref20) 2011; 89 ANDRADE J.E.P (ref1); 1 POUSH K.A (ref12) 1983 CALDWELL D.L. (ref4) 1983; 229 GORMAN J.W (ref13) 1962; 4 DUBOIS D.W (ref6) 1993 CORNELL J. (ref14) 1973; 15 LIMA P.R (ref18) 2010; 35 KUNTZBURGER F (ref8) 1998; 7 LIMA, P.R; MIRAPALHETA, A; DOS SANTOS ANDRADE, M.H. 2010; 35 CURLIN, L.C; FLORKIEWICZ, T.F; MATOUSEK, R.C. 1990; 4 POUSH, K.A; CALDWELL, D.L; VAN ZEE, J. 1983 VIANA, K.M.S; VILAR, E.O; LIRA, H.L. 2008; 3 HINE, F; O’BRIEN, T.F; BOMMARAJU, T.V. 2005 ANDRADE, J.E.P; ZAPORSKI, J.; 1 CORNELL, J.A. 1981; 3 ROMINE, R. 1977 CALDWELL, D.L; POUSH, K.A; WHITE, R.E. 1982 CUNHA, C.T.C. 2015 2017 CALDWELL, D.L.; Alkire, R.C.; Der-Tau, Chin 1983; 229 KUNTZBURGER, F; HORBEZ, D; LEHELLOCO, J.G. 1998; 7 NUNES, D.B. 1998 ALMEIDA FILHO, E.M.; VILAR, E.O; FEITOZA, A.C.O. 2011; 89 VIANA, K.M.S 2009 CORNELL, J. 1973; 15 SCHEFFÉ, H. 1958; 20 DUBOIS, D.W; DILMORE, C.R. 1993 GORMAN, J.W; HINMAN, J.E. 1962; 4 |
| References_xml | – year: 2015 ident: ref9 contributor: fullname: CUNHA C.T.C. – volume-title: Mathematical model of the chlorine cell diaphragm year: 1982 ident: ref19 contributor: fullname: CALDWELL D.L – year: 1998 ident: ref16 contributor: fullname: NUNES D.B. – year: 1977 ident: ref5 contributor: fullname: ROMINE R. – volume: 89 start-page: 491 year: 2011 ident: ref20 article-title: Physical-chemical characterization and statistical modeling applied in a chlor-alkali diaphragm-cell process publication-title: Chemical Engineering Research and Design doi: 10.1016/j.cherd.2010.08.007 contributor: fullname: ALMEIDA FILHO E.M. – year: 2005 ident: ref3 contributor: fullname: HINE F – volume: 4 start-page: 334 year: 1990 ident: ref7 article-title: Polymarix: A depositable replacement for asbestos diaphragms publication-title: Modern Chlor-Alkali Technology contributor: fullname: CURLIN L.C – year: 1993 ident: ref6 contributor: fullname: DUBOIS D.W – volume-title: Characterization of asbestos diaphgrams for chlor-alkali electrolysis year: 1983 ident: ref12 contributor: fullname: POUSH K.A – year: 2009 ident: ref11 contributor: fullname: VIANA K.M.S – volume: 7 start-page: 181 year: 1998 ident: ref8 article-title: New developments in built-in precathode diaphragm technology publication-title: Modem Chlor-Alkali Technology contributor: fullname: KUNTZBURGER F – volume: 15 start-page: 437 issue: 3 year: 1973 ident: ref14 article-title: Experiments with mixtures: A review publication-title: Technometrics doi: 10.1080/00401706.1973.10489071 contributor: fullname: CORNELL J. – volume: 20 start-page: 344 year: 1958 ident: ref17 article-title: Experiments with wixtures publication-title: Journal of the statistical society series b doi: 10.1111/j.2517-6161.1958.tb00299.x contributor: fullname: SCHEFFÉ H. – year: 2017 ident: ref2 – volume: 3 start-page: 12 year: 2008 ident: ref10 article-title: Avaliação do desempenho do compósito amianto/polietileno durante a eletrólise da salmoura publication-title: Revista eletrônica de materiais e processos contributor: fullname: VIANA K.M.S – volume: 4 start-page: 463 issue: 4 year: 1962 ident: ref13 article-title: Simplex Lattice Designs for Multicomponent Systems publication-title: Technometrics doi: 10.1080/00401706.1962.10490034 contributor: fullname: GORMAN J.W – volume: 1 start-page: 491 issue: 2 ident: ref1 article-title: A indústria de cloro-soda publication-title: Revista do BNDS contributor: fullname: ANDRADE J.E.P – volume: 229 year: 1983 ident: ref4 contributor: fullname: CALDWELL D.L. – volume: 3 issue: 23 year: 1981 ident: ref15 article-title: Experiments with mixtures: Designs, models, and the analysis of misture data publication-title: John Wiley & Sons, Inc contributor: fullname: CORNELL J.A. – volume: 35 start-page: 2174 issue: 5 year: 2010 ident: ref18 article-title: Energy loss in electrochemical diaphragm process of chlorine and alkali industry–A collateral effect of the undesirable generation of chlorate publication-title: Energy doi: 10.1016/j.energy.2010.01.039 contributor: fullname: LIMA P.R – volume: 4 start-page: 463 issue: 4 year: 1962 end-page: 487 article-title: Simplex Lattice Designs for Multicomponent Systems publication-title: Technometrics contributor: fullname: GORMAN, J.W; HINMAN, J.E. – year: 1993 publication-title: Diaphragm for use in chlor-alkali cells contributor: fullname: DUBOIS, D.W; DILMORE, C.R. – volume: 35 start-page: 2174 issue: 5 year: 2010 end-page: 2178 article-title: Energy loss in electrochemical diaphragm process of chlorine and alkali industry–A collateral effect of the undesirable generation of chlorate publication-title: Energy contributor: fullname: LIMA, P.R; MIRAPALHETA, A; DOS SANTOS ANDRADE, M.H. – year: 1977 publication-title: Diaphgram cell technology, oxytech systems, Inc., Chardon, Ohio Usa, Presented at The Electrode Corp. Chlorine/Chlorate Seminar contributor: fullname: ROMINE, R. – year: 1982 publication-title: Electrochemical Society 161st Meeting contributor: fullname: CALDWELL, D.L; POUSH, K.A; WHITE, R.E. – volume: 89 start-page: 491 year: 2011 end-page: 498 article-title: Physical-chemical characterization and statistical modeling applied in a chlor-alkali diaphragm-cell process publication-title: Chemical Engineering Research and Design contributor: fullname: ALMEIDA FILHO, E.M.; VILAR, E.O; FEITOZA, A.C.O. – year: 1983 publication-title: Modern Chlor-Alkali Technology contributor: fullname: POUSH, K.A; CALDWELL, D.L; VAN ZEE, J. – volume: 20 start-page: 344 year: 1958 end-page: 360 article-title: Experiments with wixtures publication-title: Journal of the statistical society series b contributor: fullname: SCHEFFÉ, H. – volume: 3 start-page: 12 year: 2008 end-page: 19 article-title: Avaliação do desempenho do compósito amianto/polietileno durante a eletrólise da salmoura publication-title: Revista eletrônica de materiais e processos contributor: fullname: VIANA, K.M.S; VILAR, E.O; LIRA, H.L. – year: 1998 publication-title: Rotinas para otimização experimental de misturas contributor: fullname: NUNES, D.B. – volume: 1 start-page: 491 issue: 2 end-page: 498 article-title: A indústria de cloro-soda publication-title: Revista do BNDS contributor: fullname: ANDRADE, J.E.P; ZAPORSKI, J. – volume: 3 issue: 23 year: 1981 article-title: Experiments with mixtures: Designs, models, and the analysis of misture data publication-title: John Wiley & Sons, Inc contributor: fullname: CORNELL, J.A. – year: 2005 publication-title: Handbook of chlor-alkali technology contributor: fullname: HINE, F; O’BRIEN, T.F; BOMMARAJU, T.V. – year: 2009 publication-title: Diafragmas de PEUAPM para aplicação no processo de produção eletrolítica de cloro-soda contributor: fullname: VIANA, K.M.S – year: 2017 publication-title: Industry Review – volume: 229 year: 1983 publication-title: Tutorial Lectures in Electrochemical Engineering and Technology contributor: fullname: CALDWELL, D.L.; Alkire, R.C.; Der-Tau, Chin – year: 2015 publication-title: Desenvolvimento e avaliação de diafragmas poliméricos para aplicação no processo de produção eletrolítica de cloro-soda contributor: fullname: CUNHA, C.T.C. – volume: 7 start-page: 181 year: 1998 end-page: 181 article-title: New developments in built-in precathode diaphragm technology publication-title: Modem Chlor-Alkali Technology contributor: fullname: KUNTZBURGER, F; HORBEZ, D; LEHELLOCO, J.G. – volume: 15 start-page: 437 issue: 3 year: 1973 end-page: 455 article-title: Experiments with mixtures: A review publication-title: Technometrics contributor: fullname: CORNELL, J. – volume: 4 start-page: 334 year: 1990 end-page: 335 article-title: Polymarix: A depositable replacement for asbestos diaphragms publication-title: Modern Chlor-Alkali Technology contributor: fullname: CURLIN, L.C; FLORKIEWICZ, T.F; MATOUSEK, R.C. |
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| Title | Mixture model applied to the development of polymeric fibre diaphragms |
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