Adsorption studies of Cu(II) on Boston fern (Nephrolepis exaltata Schott cv. Bostoniensis) leaves

• Published in: Applied water science Vol. 7; no. 4; pp. 2051 - 2061
• Main Authors: Rao, Rifaqat Ali Khan, Khan, Umra
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01-07-2017; Springer Nature B.V
• Subjects: Adsorbents; Adsorption; Aquatic Pollution; Aqueous solutions; Capacity; Comparative Law; Copper; Desorption; Earth and Environmental Science; Earth Sciences; Ferns; Heavy metals; Hydrogeology; Industrial and Production Engineering; Innovation; Innovations; International & Foreign Law; Ion concentration; Ions; Isotherms; Kinetics; Leaves; Metal concentrations; Metals; Nanotechnology; Nephrolepis exaltata; Original Article; Private International Law; Removal; Studies; Temperature; Temperature effects; Waste Water Technology; Water Industry/Water Technologies; Water Management; Water Pollution Control; Breakthrough capacity; Boston fern; Kinetics; Adsorption; Isotherms; Thermodynamic
• ISSN: 2190-5487; 2190-5495
• DOI: 10.1007/s13201-016-0386-3

Adsorption studies were done on Boston fern leaves for the effective removal of Cu(II) ions from aqueous solution. It has been tested for the first time for heavy metal adsorption from aqueous solution. This promising material has shown remarkable adsorption capacity towards Cu(II) ions which confirm its novelty, ease of availability, non-toxic nature, cheapness, etc., and give the main innovation to the present study. The adsorbent was analyzed by FT-IR, SEM and EDS. The effect of pH, contact time, initial metal ion concentration and temperature on the adsorption was investigated using batch process to optimize conditions for maximum adsorption. The adsorption of Cu(II) was maximum (96 %) at pH 4. The experimental data were analyzed by Langmuir, Freundlich and Tempkin isotherms. The kinetic studies of Cu(II)were carried out at room temperature (30 °C) in the concentration range 10–100 mg L
−1
. The data obtained fitted well with the Langmuir isotherm and pseudo-second-order kinetics model. The maximum adsorption capacity (
q
m
) obtained from Langmuir adsorption isotherm was found to be 27.027 mg g
−1
at 30 °C. The process was found to be exothermic and spontaneous in nature. The breakthrough and exhaustive capacities were found to be 12.5 and 37.5 mg g
−1
, respectively. Desorption studies showed that 93.3 % Cu(II) could be desorbed with 0.1 M HCl by continuous mode.