Recognition of simplexes with immiscibility in ionic salt systems on the basis of phase trees for design of electrolytes for chemical current sources
An algorithm is developed for searching secant elements and simplexes having immiscibility in multinary systems; phase trees of systems are the only initial data set required for the implementation of this algorithm. The Li,Na,Rb||F,Br four-component reciprocal system is used for testing the algorit...
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| Published in: | Russian journal of inorganic chemistry Vol. 55; no. 1; pp. 112 - 129 |
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| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
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SP MAIK Nauka/Interperiodica
2010
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| Abstract | An algorithm is developed for searching secant elements and simplexes having immiscibility in multinary systems; phase trees of systems are the only initial data set required for the implementation of this algorithm. The Li,Na,Rb||F,Br four-component reciprocal system is used for testing the algorithm. As a result of experimental studies, immiscibility regions are demarcated inside the Li,Rb||F,Br ternary reciprocal system, in LiF-NaF-RbBr and LiF-NaBr-RbBr stable secant triangles, and in the LiF-LiBr-NaBr-RbBr stable tetrahedron. The low-melting alloy corresponding to the four-component invariant point, with a melting temperature of 272°C, may be recommended for use as an electrolyte in chemical current sources. |
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| AbstractList | An algorithm is developed for searching secant elements and simplexes having immiscibility in multinary systems; phase trees of systems are the only initial data set required for the implementation of this algorithm. The Li,Na,Rb||F,Br four-component reciprocal system is used for testing the algorithm. As a result of experimental studies, immiscibility regions are demarcated inside the Li,Rb||F,Br ternary reciprocal system, in LiF-NaF-RbBr and LiF-NaBr-RbBr stable secant triangles, and in the LiF-LiBr-NaBr-RbBr stable tetrahedron. The low-melting alloy corresponding to the four-component invariant point, with a melting temperature of 272°C, may be recommended for use as an electrolyte in chemical current sources. |
| Author | Garkushin, I. K. Garkushin, A. I. Istomova, M. A. Egortsev, G. E. |
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| Keywords | Immiscibility Region RbBr Reciprocal System NaBr Crystallization Field |
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| SubjectTerms | Chemistry Chemistry and Materials Science Inorganic Chemistry Physicochemical Analysis of Inorganic Systems |
| Title | Recognition of simplexes with immiscibility in ionic salt systems on the basis of phase trees for design of electrolytes for chemical current sources |
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