Thermal properties of poly (vinyl alcohol)(PVA)/halloysite nanotubes reinforced nanocomposites
Natural halloysite nano clay with tubular structure was used for the preparation of polyvinyl alcohol (PVA) nanocomposites. A systematic and detailed study was conducted on the effect of nanotubes on the properties such as flame retardancy, water absorption capacity, and thermal stability of poly (v...
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Published in: | International journal of plastics technology Vol. 19; no. 1; pp. 124 - 136 |
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01-06-2015
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Abstract | Natural halloysite nano clay with tubular structure was used for the preparation of polyvinyl alcohol (PVA) nanocomposites. A systematic and detailed study was conducted on the effect of nanotubes on the properties such as flame retardancy, water absorption capacity, and thermal stability of poly (vinyl alcohol) matrix. Morphological and structural characterizations of nanocomposites were performed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and fourier transform infra red (FTIR) spectroscopy. XRD results showed peak broadening and disappearance in nanocomposites when compared to the peaks for nanotubes, indicating the better dispersion of nanotubes in the matrix. Owing to the hydrophilicity of nanotubes the nanocomposites exhibited enhanced water sorption properties. At higher temperature nano filler reinforced PVA showed better thermal stability and flammability due to barrier effect. |
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AbstractList | Natural halloysite nano clay with tubular structure was used for the preparation of polyvinyl alcohol (PVA) nanocomposites. A systematic and detailed study was conducted on the effect of nanotubes on the properties such as flame retardancy, water absorption capacity, and thermal stability of poly (vinyl alcohol) matrix. Morphological and structural characterizations of nanocomposites were performed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and fourier transform infra red (FTIR) spectroscopy. XRD results showed peak broadening and disappearance in nanocomposites when compared to the peaks for nanotubes, indicating the better dispersion of nanotubes in the matrix. Owing to the hydrophilicity of nanotubes the nanocomposites exhibited enhanced water sorption properties. At higher temperature nano filler reinforced PVA showed better thermal stability and flammability due to barrier effect. |
Author | M.P., Rahana P., Selvin Thomas K.I., Suresh V., Saranya Stephen, Ranimol V.P., Swapna |
Author_xml | – sequence: 1 givenname: Swapna surname: V.P. fullname: V.P., Swapna organization: Post Graduate & Research Department of Chemistry, St. Joseph’s College – sequence: 2 givenname: Selvin Thomas surname: P. fullname: P., Selvin Thomas organization: Advanced Materials and Core Facility, Yanbu Research Center, Royal Commission for Yanbu-Colleges and Institutes – sequence: 3 givenname: Suresh surname: K.I. fullname: K.I., Suresh organization: Polymers & Functional Materials Division, CSIR-Indian Institute of Chemical Technology – sequence: 4 givenname: Saranya surname: V. fullname: V., Saranya organization: Post Graduate & Research Department of Chemistry, St. Joseph’s College – sequence: 5 givenname: Rahana surname: M.P. fullname: M.P., Rahana organization: Post Graduate & Research Department of Chemistry, St. Joseph’s College – sequence: 6 givenname: Ranimol surname: Stephen fullname: Stephen, Ranimol email: ranistephen@gmail.com organization: Post Graduate & Research Department of Chemistry, St. Joseph’s College |
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Cites_doi | 10.1002/app.11743 10.1006/snmr.2002.0059 10.1016/S0142-9612(03)00080-2 10.1016/S0141-3910(03)00155-1 10.1016/S0032-3861(99)00682-5 10.1021/cm034505a 10.1021/jp100902e 10.1002/macp.200700487 10.1021/jp805657t 10.1021/nl0202152 10.1016/j.clay.2010.01.015 10.1016/S0032-3861(00)00287-1 10.3390/ma3094580 10.1007/3-540-46414-X_2 10.1002/(SICI)1099-0488(19970130)35:2<389::AID-POLB14>3.0.CO;2-E 10.1021/cm0001760 10.1016/j.polymdegradstab.2010.05.014 10.1002/pi.2222 10.1016/S0032-3861(02)00778-4 10.1039/c2jm33156j 10.1016/j.compscitech.2009.09.012 10.1002/fam.810040202 10.1016/j.clay.2012.06.014 10.1080/10426910903022346 |
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Keywords | Flame retardant Halloysite nanotubes Poly (vinyl alcohol) Thermal degradation |
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Title | Thermal properties of poly (vinyl alcohol)(PVA)/halloysite nanotubes reinforced nanocomposites |
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