Thermal properties of poly (vinyl alcohol)(PVA)/halloysite nanotubes reinforced nanocomposites

Natural halloysite nano clay with tubular structure was used for the preparation of polyvinyl alcohol (PVA) nanocomposites. A systematic and detailed study was conducted on the effect of nanotubes on the properties such as flame retardancy, water absorption capacity, and thermal stability of poly (v...

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Published in:International journal of plastics technology Vol. 19; no. 1; pp. 124 - 136
Main Authors: V.P., Swapna, P., Selvin Thomas, K.I., Suresh, V., Saranya, M.P., Rahana, Stephen, Ranimol
Format: Journal Article
Language:English
Published: New Delhi Springer India 01-06-2015
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Abstract Natural halloysite nano clay with tubular structure was used for the preparation of polyvinyl alcohol (PVA) nanocomposites. A systematic and detailed study was conducted on the effect of nanotubes on the properties such as flame retardancy, water absorption capacity, and thermal stability of poly (vinyl alcohol) matrix. Morphological and structural characterizations of nanocomposites were performed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and fourier transform infra red (FTIR) spectroscopy. XRD results showed peak broadening and disappearance in nanocomposites when compared to the peaks for nanotubes, indicating the better dispersion of nanotubes in the matrix. Owing to the hydrophilicity of nanotubes the nanocomposites exhibited enhanced water sorption properties. At higher temperature nano filler reinforced PVA showed better thermal stability and flammability due to barrier effect.
AbstractList Natural halloysite nano clay with tubular structure was used for the preparation of polyvinyl alcohol (PVA) nanocomposites. A systematic and detailed study was conducted on the effect of nanotubes on the properties such as flame retardancy, water absorption capacity, and thermal stability of poly (vinyl alcohol) matrix. Morphological and structural characterizations of nanocomposites were performed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and fourier transform infra red (FTIR) spectroscopy. XRD results showed peak broadening and disappearance in nanocomposites when compared to the peaks for nanotubes, indicating the better dispersion of nanotubes in the matrix. Owing to the hydrophilicity of nanotubes the nanocomposites exhibited enhanced water sorption properties. At higher temperature nano filler reinforced PVA showed better thermal stability and flammability due to barrier effect.
Author M.P., Rahana
P., Selvin Thomas
K.I., Suresh
V., Saranya
Stephen, Ranimol
V.P., Swapna
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  givenname: Selvin Thomas
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  fullname: P., Selvin Thomas
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  givenname: Ranimol
  surname: Stephen
  fullname: Stephen, Ranimol
  email: ranistephen@gmail.com
  organization: Post Graduate & Research Department of Chemistry, St. Joseph’s College
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Issue 1
Keywords Flame retardant
Halloysite nanotubes
Poly (vinyl alcohol)
Thermal degradation
Language English
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Snippet Natural halloysite nano clay with tubular structure was used for the preparation of polyvinyl alcohol (PVA) nanocomposites. A systematic and detailed study was...
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SubjectTerms Chemistry
Chemistry and Materials Science
Materials Science
Polymer Sciences
Research Article
Title Thermal properties of poly (vinyl alcohol)(PVA)/halloysite nanotubes reinforced nanocomposites
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