Green corrosion inhibitor for mild steel extracted from soybean leaves

The use of green-soluble inhibitors in the corrosive medium as alternatives to traditional inhibitors has increased due to the toxicity of the commonly used substances. These novel substances are selected owing to their low cost, ease of application as well as maintenance, and low environmental risk...

Full description

Saved in:

Bibliographic Details
Published in:	Chemical engineering communications Vol. 211; no. 5; pp. 697 - 706
Main Authors:	Pepe, Alfonso, Tito, Florencia R., Mandri, Alejo D., Dommarco, Ricardo C., Pepe, Andrés
Format:	Journal Article
Language:	English
Published:	Philadelphia Taylor & Francis 03-05-2024 Taylor & Francis Ltd
Subjects:	Agricultural waste Byproducts Corrosion inhibitors Corrosion potential Corrosion prevention Corrosion products Corrosion rate Efficiency Evaluation Glycine max Langmuir adsorption Low carbon steels Medium carbon steels Percolation Sodium chloride Soybeans vegetable by-products Weight loss measurement
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Abstract	The use of green-soluble inhibitors in the corrosive medium as alternatives to traditional inhibitors has increased due to the toxicity of the commonly used substances. These novel substances are selected owing to their low cost, ease of application as well as maintenance, and low environmental risk. This work aims to evaluate ethanolic-water extracts from post-harvest soybean (Glycine max) by-products as corrosion inhibitors for mild steel in an aggressive medium of sodium chloride. Soybean extracts were obtained by percolation at a controlled flow rate and temperature. To evaluate the anticorrosive efficiency, polarization curves of AISI 1030 steel were carried out at 1 and 7 days of immersion with different concentrations of the soybean extract. Weight loss measurements were carried out alongside potentiodynamic measurements. The steel samples were analyzed by scanning electron microscopy. The soybean extracts obtained reduced the corrosion rate of the steel, showing an efficiency of 30% at day 1. The inhibition efficiency increased up to 80% after 7 days of incubation with 2000 ppm of the extract. A Langmuir adsorption model was fitted to weight loss measurements. K ads and ΔG ads obtained from the model were characteristic of physisorption. The corrosion potential was shifted toward more negative values, classifying the ethanolic-water soybean extract as a cathodic inhibitor. The steel surface for the samples incubated with 2000 ppm of soybean extract was greatly improved showing significantly fewer agglomeration of corrosion products. Soybean leaves are a promising by-product useful to produce ethanolic-water extracts to be used as green corrosion inhibitors.
AbstractList	The use of green-soluble inhibitors in the corrosive medium as alternatives to traditional inhibitors has increased due to the toxicity of the commonly used substances. These novel substances are selected owing to their low cost, ease of application as well as maintenance, and low environmental risk. This work aims to evaluate ethanolic-water extracts from post-harvest soybean (Glycine max) by-products as corrosion inhibitors for mild steel in an aggressive medium of sodium chloride. Soybean extracts were obtained by percolation at a controlled flow rate and temperature. To evaluate the anticorrosive efficiency, polarization curves of AISI 1030 steel were carried out at 1 and 7 days of immersion with different concentrations of the soybean extract. Weight loss measurements were carried out alongside potentiodynamic measurements. The steel samples were analyzed by scanning electron microscopy. The soybean extracts obtained reduced the corrosion rate of the steel, showing an efficiency of 30% at day 1. The inhibition efficiency increased up to 80% after 7 days of incubation with 2000 ppm of the extract. A Langmuir adsorption model was fitted to weight loss measurements. K ads and ΔG ads obtained from the model were characteristic of physisorption. The corrosion potential was shifted toward more negative values, classifying the ethanolic-water soybean extract as a cathodic inhibitor. The steel surface for the samples incubated with 2000 ppm of soybean extract was greatly improved showing significantly fewer agglomeration of corrosion products. Soybean leaves are a promising by-product useful to produce ethanolic-water extracts to be used as green corrosion inhibitors. The use of green-soluble inhibitors in the corrosive medium as alternatives to traditional inhibitors has increased due to the toxicity of the commonly used substances. These novel substances are selected owing to their low cost, ease of application as well as maintenance, and low environmental risk. This work aims to evaluate ethanolic-water extracts from post-harvest soybean (Glycine max) by-products as corrosion inhibitors for mild steel in an aggressive medium of sodium chloride. Soybean extracts were obtained by percolation at a controlled flow rate and temperature. To evaluate the anticorrosive efficiency, polarization curves of AISI 1030 steel were carried out at 1 and 7 days of immersion with different concentrations of the soybean extract. Weight loss measurements were carried out alongside potentiodynamic measurements. The steel samples were analyzed by scanning electron microscopy. The soybean extracts obtained reduced the corrosion rate of the steel, showing an efficiency of 30% at day 1. The inhibition efficiency increased up to 80% after 7 days of incubation with 2000 ppm of the extract. A Langmuir adsorption model was fitted to weight loss measurements. Kads and ΔGads obtained from the model were characteristic of physisorption. The corrosion potential was shifted toward more negative values, classifying the ethanolic-water soybean extract as a cathodic inhibitor. The steel surface for the samples incubated with 2000 ppm of soybean extract was greatly improved showing significantly fewer agglomeration of corrosion products. Soybean leaves are a promising by-product useful to produce ethanolic-water extracts to be used as green corrosion inhibitors.
Author	Pepe, Andrés Pepe, Alfonso Tito, Florencia R. Mandri, Alejo D. Dommarco, Ricardo C.
Author_xml	– sequence: 1 givenname: Alfonso orcidid: 0000-0002-8449-8453 surname: Pepe fullname: Pepe, Alfonso organization: Bioengineering Department, H. Lee Moffitt Cancer Center & Research Institute – sequence: 2 givenname: Florencia R. surname: Tito fullname: Tito, Florencia R. organization: Instituto de Investigaciones Biológicas, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Universidad Nacional de Mar del Plata – sequence: 3 givenname: Alejo D. surname: Mandri fullname: Mandri, Alejo D. organization: Instituto de Investigaciones en Ciencia y Tecnología de Materiales (INTEMA), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Universidad Nacional de Mar del Plata – sequence: 4 givenname: Ricardo C. surname: Dommarco fullname: Dommarco, Ricardo C. organization: Instituto de Investigaciones en Ciencia y Tecnología de Materiales (INTEMA), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Universidad Nacional de Mar del Plata – sequence: 5 givenname: Andrés surname: Pepe fullname: Pepe, Andrés organization: Instituto de Investigaciones en Ciencia y Tecnología de Materiales (INTEMA), Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Universidad Nacional de Mar del Plata
BookMark	eNp9kE1LAzEQhoNUsK3-BCHgeWs-N-lNKbYKBS96DtnsLKbsJjXZqv337tJ69TDM5XnfYZ4ZmoQYAKFbShaUaHJPyFKXQsgFI4wvGNNCcXaBplSWvJCM0AmajkwxQldolvOOEMo5pVO03iSAgF1MKWYfA_bhw1e-jwk3w3S-rXHuAVoMP32yrocaNyl2OMdjBTbgFuwX5Gt02dg2w815z9H7-ult9VxsXzcvq8dt4Zgu-6IWSlMFVWmtlBJkpcDxRimhgdcVE0C50BRIDcBBNJIIKrmjzlaClIwBn6O7U-8-xc8D5N7s4iGF4aRhS85UqYnmAyVPlBueygkas0--s-loKDGjMvOnzIzKzFnZkHs45XwYnu_sd0xtbXp7bGNqkg3OZ8P_r_gF0FJ0Tg
Cites_doi	10.1038/s41598-022-18226-4 10.1111/1750-3841.15765 10.1016/B978-0-12-815270-6.00011-6 10.1007/s10311-021-01332-6 10.1016/j.corsci.2009.08.050 10.1016/j.ejpe.2019.01.001 10.1016/B978-0-12-809197-5.00001-3 10.1016/j.ejpe.2014.05.007 10.1016/j.corsci.2013.08.025 10.7324/JAPS.2016.60225 10.1016/j.matpr.2020.04.202 10.3389/fphar.2021.775034 10.1016/j.colsurfa.2020.124824 10.1088/1757-899X/290/1/012087 10.1007/s11164-012-0677-8 10.1007/s11164-015-2227-7 10.3390/molecules27072111 10.1080/01694243.2019.1576353 10.3389/fnut.2021.661693 10.1186/s13020-018-0177-x 10.3390/electrochem3020013 10.5772/intechopen.94634 10.1016/j.jtice.2016.02.027 10.3390/molecules24010048 10.1080/14786419.2017.1280490 10.1038/s41598-023-30571-6 10.1021/acsomega.9b00632 10.1016/j.carbpol.2020.115945 10.4028/www.scientific.net/JERA.35.208
ContentType	Journal Article
Copyright	2023 Taylor & Francis Group, LLC 2023 2023 Taylor & Francis Group, LLC
Copyright_xml	– notice: 2023 Taylor & Francis Group, LLC 2023 – notice: 2023 Taylor & Francis Group, LLC
DBID	AAYXX CITATION 7U5 8FD L7M
DOI	10.1080/00986445.2023.2284732
DatabaseName	CrossRef Solid State and Superconductivity Abstracts Technology Research Database Advanced Technologies Database with Aerospace
DatabaseTitle	CrossRef Technology Research Database Advanced Technologies Database with Aerospace Solid State and Superconductivity Abstracts
DatabaseTitleList	Technology Research Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Engineering
EISSN	1563-5201
EndPage	706
ExternalDocumentID	10_1080_00986445_2023_2284732 2284732
Genre	Research Articles
GroupedDBID	-~X .7F .QJ 0BK 0R~ 29B 2DF 30N 3YN 4.4 5GY 5VS AAAVI AAENE AAJMT AALDU AAMIU AAPUL AAQRR ABCCY ABDBF ABFIM ABHAV ABJNI ABJVF ABLIJ ABPEM ABQHQ ABTAI ABXUL ABXYU ACGEJ ACGFS ACGOD ACIWK ACTIO ADCVX ADGTB ADXPE AEGYZ AEISY AENEX AEOZL AEPSL AEYOC AFKVX AFOLD AFWLO AGDLA AGMYJ AHDLD AIJEM AIRXU AJWEG AKBVH AKOOK ALMA_UNASSIGNED_HOLDINGS ALQZU AQRUH AVBZW AWYRJ BLEHA CCCUG CE4 CS3 DKSSO DU5 EAP EBS EST ESX E~A E~B FUNRP FVPDL GTTXZ HF~ HZ~ H~P IPNFZ J.P KYCEM L8X LJTGL M4Z NA5 O9- P2P PQQKQ RIG RNANH ROSJB RTWRZ S-T SNACF TEN TFL TFT TFW TNC TTHFI TWF UT5 UU3 V1K ZGOLN ~02 ~S~ AAYXX ABPAQ AHDZW CITATION DGEBU H13 NX~ TBQAZ TDBHL TUROJ 7U5 8FD L7M
ID	FETCH-LOGICAL-c286t-d47817eb6aa555e5b7ec3f7748e3db24e13481e0dee3e4f504153c1cab40622e3
IEDL.DBID	TFW
ISSN	0098-6445
IngestDate	Fri Nov 15 20:28:59 EST 2024 Fri Nov 22 02:00:09 EST 2024 Thu Feb 29 06:31:30 EST 2024
IsPeerReviewed	true
IsScholarly	true
Issue	5
Language	English
LinkModel	DirectLink
MergedId	FETCHMERGED-LOGICAL-c286t-d47817eb6aa555e5b7ec3f7748e3db24e13481e0dee3e4f504153c1cab40622e3
ORCID	0000-0002-8449-8453
PQID	2932768083
PQPubID	53066
PageCount	10
ParticipantIDs	proquest_journals_2932768083 informaworld_taylorfrancis_310_1080_00986445_2023_2284732 crossref_primary_10_1080_00986445_2023_2284732
PublicationCentury	2000
PublicationDate	2024-05-03
PublicationDateYYYYMMDD	2024-05-03
PublicationDate_xml	– month: 05 year: 2024 text: 2024-05-03 day: 03
PublicationDecade	2020
PublicationPlace	Philadelphia
PublicationPlace_xml	– name: Philadelphia
PublicationTitle	Chemical engineering communications
PublicationYear	2024
Publisher	Taylor & Francis Taylor & Francis Ltd
Publisher_xml	– name: Taylor & Francis – name: Taylor & Francis Ltd
References	e_1_3_5_28_1 e_1_3_5_26_1 e_1_3_5_25_1 e_1_3_5_24_1 e_1_3_5_23_1 e_1_3_5_22_1 e_1_3_5_3_1 e_1_3_5_2_1 Osarolube E (e_1_3_5_27_1) 2008; 3 e_1_3_5_9_1 e_1_3_5_21_1 e_1_3_5_8_1 e_1_3_5_20_1 Komesu A (e_1_3_5_14_1) 2023 e_1_3_5_5_1 e_1_3_5_4_1 International Monetary Fund Staff (e_1_3_5_11_1) 2004 e_1_3_5_7_1 e_1_3_5_6_1 e_1_3_5_18_1 e_1_3_5_17_1 e_1_3_5_16_1 e_1_3_5_38_1 e_1_3_5_15_1 e_1_3_5_37_1 e_1_3_5_13_1 Roberge PR. (e_1_3_5_29_1) 2019 e_1_3_5_36_1 e_1_3_5_35_1 e_1_3_5_12_1 e_1_3_5_33_1 Guo L (e_1_3_5_10_1) 2022 e_1_3_5_19_1 e_1_3_5_32_1 Verma DK (e_1_3_5_34_1) 2015; 7 e_1_3_5_31_1 e_1_3_5_30_1
References_xml	– ident: e_1_3_5_17_1 doi: 10.1038/s41598-022-18226-4 – ident: e_1_3_5_19_1 doi: 10.1111/1750-3841.15765 – ident: e_1_3_5_22_1 doi: 10.1016/B978-0-12-815270-6.00011-6 – volume-title: Eco-friendly corrosion inhibitors: principles, designing and applications year: 2022 ident: e_1_3_5_10_1 contributor: fullname: Guo L – volume: 3 start-page: 224 issue: 6 year: 2008 ident: e_1_3_5_27_1 article-title: Corrosion behaviour of mild and high carbon steels in various acidic media publication-title: Sci Res Essays contributor: fullname: Osarolube E – ident: e_1_3_5_2_1 doi: 10.1007/s10311-021-01332-6 – start-page: 60 volume-title: Waste management year: 2023 ident: e_1_3_5_14_1 contributor: fullname: Komesu A – ident: e_1_3_5_33_1 doi: 10.1016/j.corsci.2009.08.050 – ident: e_1_3_5_4_1 doi: 10.1016/j.ejpe.2019.01.001 – ident: e_1_3_5_38_1 doi: 10.1016/B978-0-12-809197-5.00001-3 – ident: e_1_3_5_15_1 doi: 10.1016/j.ejpe.2014.05.007 – ident: e_1_3_5_18_1 doi: 10.1016/j.corsci.2013.08.025 – ident: e_1_3_5_30_1 doi: 10.7324/JAPS.2016.60225 – ident: e_1_3_5_20_1 doi: 10.1016/j.matpr.2020.04.202 – ident: e_1_3_5_24_1 doi: 10.3389/fphar.2021.775034 – ident: e_1_3_5_31_1 doi: 10.1016/j.colsurfa.2020.124824 – ident: e_1_3_5_8_1 doi: 10.1088/1757-899X/290/1/012087 – ident: e_1_3_5_32_1 doi: 10.1007/s11164-012-0677-8 – ident: e_1_3_5_35_1 doi: 10.1007/s11164-015-2227-7 – volume-title: Handbook of corrosion engineering year: 2019 ident: e_1_3_5_29_1 contributor: fullname: Roberge PR. – ident: e_1_3_5_25_1 doi: 10.3390/molecules27072111 – ident: e_1_3_5_7_1 doi: 10.1080/01694243.2019.1576353 – ident: e_1_3_5_16_1 doi: 10.3389/fnut.2021.661693 – ident: e_1_3_5_37_1 doi: 10.1186/s13020-018-0177-x – ident: e_1_3_5_5_1 doi: 10.3390/electrochem3020013 – ident: e_1_3_5_36_1 doi: 10.5772/intechopen.94634 – ident: e_1_3_5_12_1 doi: 10.1016/j.jtice.2016.02.027 – ident: e_1_3_5_9_1 – ident: e_1_3_5_21_1 doi: 10.3390/molecules24010048 – ident: e_1_3_5_23_1 doi: 10.1080/14786419.2017.1280490 – ident: e_1_3_5_28_1 – volume: 7 start-page: 2225 year: 2015 ident: e_1_3_5_34_1 article-title: Corrosion inhibition of mild steel by extract of bryophyllum pinnatum leaves in acidic solution publication-title: Chem Mater Res contributor: fullname: Verma DK – ident: e_1_3_5_3_1 doi: 10.1038/s41598-023-30571-6 – volume-title: Global financial stability report, april 2004: market developments and issues year: 2004 ident: e_1_3_5_11_1 contributor: fullname: International Monetary Fund Staff – ident: e_1_3_5_13_1 doi: 10.1021/acsomega.9b00632 – ident: e_1_3_5_6_1 doi: 10.1016/j.carbpol.2020.115945 – ident: e_1_3_5_26_1 doi: 10.4028/www.scientific.net/JERA.35.208
SSID	ssj0013311
Score	2.411519
Snippet	The use of green-soluble inhibitors in the corrosive medium as alternatives to traditional inhibitors has increased due to the toxicity of the commonly used...
SourceID	proquest crossref informaworld
SourceType	Aggregation Database Publisher
StartPage	697
SubjectTerms	Agricultural waste Byproducts Corrosion inhibitors Corrosion potential Corrosion prevention Corrosion products Corrosion rate Efficiency Evaluation Glycine max Langmuir adsorption Low carbon steels Medium carbon steels Percolation Sodium chloride Soybeans vegetable by-products Weight loss measurement
Title	Green corrosion inhibitor for mild steel extracted from soybean leaves
URI	https://www.tandfonline.com/doi/abs/10.1080/00986445.2023.2284732 https://www.proquest.com/docview/2932768083
Volume	211
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
link	http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1LT8MwDI5gJzjwRgwGyoFrx5qka3ucYNNOXBiCW5Q0jpg0OrRuSPx77D6ACSEOcGykRJFjf3ZS-zNjl30jVKZ8GkDqZaDQ4QbWpypwntybw0FPb7rju_j2MbkZEk3OoKmFobRKukP7iiiixGoybmOLJiPuijgw0Y1HXWr93RUEsJJQmDi3UaMno4fP_wgyDBvWTJrS1PD8tMqad1rjLv2G1aUDGu3-w9b32E4dffJBpS77bAPyA7b9hZPwkI3KTByOl1LcIR4an-ZPU4t2v-C4Tf48nTmOmgEzjrBecj07TjUqvJi_WTA5n4F5heKI3Y-Gk-txUDdbCDKR9JeBo5pTapBiTBRFENkYMukxOExAOisUhFSyCz0HIEH5iEr7ZRZmxmJIIATIY9bK5zmcMG7iLEPgcDYRDn2ksuBE0ktS6zzCGag26zZC1i8Vp4YOP6hKKwFpEpCuBdRm6dej0MvyMcNXnUe0_GVupzk3XZtnoTHGETE1HZGnf1j6jG3hpyrTH2WHtZaLFZyzzcKtLkotfAcaPNhy
link.rule.ids	315,782,786,1455,1509,27933,27934,58021,59734,60523
linkProvider	Taylor & Francis
linkToHtml	http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV1LT8MwDI5gHIADb8RgQA5cO9Yk3dojgk1DjF0YglvUNI6YNDq0BxL_HrtdxyaEOMC1USLLST47rv2ZsYt6LFSiXORB5KSn0OB6xkXKs47Mm8WPjmK67YdG9zm8aRJNzrwWhtIq6Q3tcqKIDKvpclMwukiJuyQSTLTjQZV6f1cFIaxEGF5D51gSf36v9fT1J0H6fsGbSXOKKp6fllmyT0vspd_QOjNBre3_EH6Hbc0cUH6Vn5hdtgLpHttcoCXcZ60sGYfjuxRFxH3j_fSlb_DqjzjKyV_7A8vxcMCAI7JndM-WU5kKHw8_DMQpH0D8DuMD9thq9q7b3qzfgpeIsD7xLJWdUo-UOA6CAALTgEQ69A9DkNYIBT5V7ULNAkhQLqDqfpn4SWzQKxAC5CErpcMUjhiPG0mC2GFNKCyaSWXAirAWRsY6RDRQZVYttKzfcloN7c_ZSnMFaVKQnimozKLFvdCTLJ7h8uYjWv4yt1JsnJ7d0LFGN0c0qO-IPP7D0udsvd277-jObffuhG3gkMqyIWWFlSajKZyy1bGdnmVH8hPbWdyW
linkToPdf	http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV3dS8MwEA86QfTBb3E6NQ--dq5JurWPw60oyhCc6FtomgsOZpV9CP733rWrboj4oK8NCccl-d1devc7xs6aiVCpcpEHkZOeQoPrGRcpzzoybxY_OnrTvbxr9R7DTpdoctplLQylVVIM7QqiiByr6XK_WldmxJ0TByaa8aBOrb_rggBWIgqvNBtFVNWPH75-JEjfL2kzaU5ZxPPTMgvmaYG89BtY5xYo3vwH2bfYxsz95O3ivGyzJch22PocKeEui_NUHI5RKUqIu8YH2dPA4MUfcRSTPw-GluPRgCFHXM_Jni2nIhU-fnk3kGR8CMkbjPfYfdztX1x6s24LXirC5sSzVHRKHVKSJAgCCEwLUunQOwxBWiMU-FSzCw0LIEG5gGr7ZeqniUGfQAiQ-6ySvWRwwHjSSlNEDmtCYdFIKgNWhI0wMtYhnoGqsnqpZP1akGpo_5OrtFCQJgXpmYKqLJrfCj3JXzNc0XpEy1_m1sp907P7Odbo5IgWdR2Rh39Y-pSt3nZifXPVuz5iazii8lRIWWOVyWgKx2x5bKcn-YH8ADTR2zo
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Green+corrosion+inhibitor+for+mild+steel+extracted+from+soybean+leaves&rft.jtitle=Chemical+engineering+communications&rft.au=Pepe%2C+Alfonso&rft.au=Tito%2C+Florencia+R.&rft.au=Mandri%2C+Alejo+D.&rft.au=Dommarco%2C+Ricardo+C.&rft.date=2024-05-03&rft.pub=Taylor+%26+Francis&rft.issn=0098-6445&rft.eissn=1563-5201&rft.volume=211&rft.issue=5&rft.spage=697&rft.epage=706&rft_id=info:doi/10.1080%2F00986445.2023.2284732&rft.externalDocID=2284732
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0098-6445&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0098-6445&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0098-6445&client=summon