Organotin Compounds in Synthesis of Chemically Modified Silica
It is shown that alkylchlorostannanes can be successfully used for synthesis of chemically modified silica. The hydrolytic stability of the materials obtained is studied. It is revealed that grafted layers of Et3SnCl and Et2SnCl2 can be removed at pH values lower than 4, whereas silica modification...
Saved in:
| Published in: | Journal of colloid and interface science Vol. 241; no. 2; pp. 434 - 438 |
|---|---|
| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Elsevier Inc
15-09-2001
|
| Subjects: | |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | It is shown that alkylchlorostannanes can be successfully used for synthesis of chemically modified silica. The hydrolytic stability of the materials obtained is studied. It is revealed that grafted layers of Et3SnCl and Et2SnCl2 can be removed at pH values lower than 4, whereas silica modification with EtSnCl3 produces layers that are stable at pH values 0–7. Mössbauer spectroscopy of the samples obtained was done; parameters of the spectra are determined. It is found that rigidity of attachment of tin atoms strongly increases in passing from Et3SnCl to Et2SnCl2 and, further, to EtSnCl3. |
|---|---|
| AbstractList | It is shown that alkylchlorostannanes can be successfully used for synthesis of chemically modified silica. The hydrolytic stability of the materials obtained is studied. It is revealed that grafted layers of Et3SnCl and Et2SnCl2 can be removed at pH values lower than 4, whereas silica modification with EtSnCl3 produces layers that are stable at pH values 0–7. Mössbauer spectroscopy of the samples obtained was done; parameters of the spectra are determined. It is found that rigidity of attachment of tin atoms strongly increases in passing from Et3SnCl to Et2SnCl2 and, further, to EtSnCl3. |
| Author | Perfiliev, Yu.D. Lisichkin, G.V. Rzhevsky, D.V. Mingalyov, P.G. |
| Author_xml | – sequence: 1 givenname: P.G. surname: Mingalyov fullname: Mingalyov, P.G. – sequence: 2 givenname: D.V. surname: Rzhevsky fullname: Rzhevsky, D.V. – sequence: 3 givenname: Yu.D. surname: Perfiliev fullname: Perfiliev, Yu.D. – sequence: 4 givenname: G.V. surname: Lisichkin fullname: Lisichkin, G.V. |
| BookMark | eNp1j01LAzEQhoNUsK1ePe8f2HWSbTbJRZDFL6j0UD2HmExsynZTklXov3eXevU0zDDPy_ssyKyPPRJyS6GiAM3d3oZcMQBaiUbyCzKnoHgpKNQzMgdgtFRCiSuyyHk_flHO1Zzcb9KX6eMQ-qKNh2P87l0uxmV76ocd5pCL6It2h4dgTdedirfogg_oim3oxtM1ufSmy3jzN5fk4-nxvX0p15vn1_ZhXVomm6GsVwqllE7Z2jrLqVR-taobA4bWnqNkgltvGm44Y5-NNchBeFACmEInQdZLUp1zbYo5J_T6mMLBpJOmoCd7PdnryV5P9iMgzwCOrX4CJp1twN6iCwntoF0M_6G_LkBibA |
| CitedBy_id | crossref_primary_10_1007_s11172_005_0230_7 |
| Cites_doi | 10.1021/la00036a028 10.1021/ja00055a049 10.1021/om9708844 10.1002/jlac.19636630105 10.1021/ja00086a037 10.1016/S0022-328X(00)88871-3 10.1021/ic00085a061 |
| ContentType | Journal Article |
| Copyright | 2001 Academic Press |
| Copyright_xml | – notice: 2001 Academic Press |
| DBID | AAYXX CITATION |
| DOI | 10.1006/jcis.2001.7685 |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering Chemistry |
| EISSN | 1095-7103 |
| EndPage | 438 |
| ExternalDocumentID | 10_1006_jcis_2001_7685 S0021979701976854 |
| GroupedDBID | --- --K --M -~X .~1 0R~ 1B1 1~. 1~5 29K 457 4G. 53G 5GY 5VS 7-5 71M 8P~ 9JN AABNK AABXZ AACTN AAEDT AAEDW AAEPC AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARLI AAXUO ABFNM ABFRF ABJNI ABMAC ABNEU ABNUV ABXRA ABYKQ ACBEA ACDAQ ACFVG ACGFO ACGFS ACNNM ACRLP ADBBV ADECG ADEWK ADEZE ADFGL ADMUD AEFWE AEKER AENEX AEZYN AFFNX AFKWA AFRZQ AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHPOS AIEXJ AIKHN AITUG AIVDX AJBFU AJOXV AJSZI AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR AZFZN BKOJK BLXMC CAG COF CS3 D-I DM4 DU5 EFBJH EFLBG ENUVR EO8 EO9 EP2 EP3 F5P FDB FGOYB FIRID FLBIZ FNPLU FYGXN G-Q HZ~ IHE J1W KOM LG5 LX6 M24 M41 MAGPM MO0 N9A NEJ O-L O9- OAUVE OGIMB OZT P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SCB SCC SDF SDG SDP SES SMS SPC SPCBC SPD SSG SSK SSM SSQ SSZ T5K TWZ WH7 XPP YQT ZMT ZU3 ~02 ~G- .GJ 4.4 6TJ AAHBH AAXKI AAYXX ABDPE ABXDB ADVLN AEBSH AFJKZ AI. AKRWK ASPBG AVWKF BBWZM CITATION EBS EJD FEDTE G-2 GBLVA HLY HVGLF H~9 NDZJH P-8 SCE SEW VH1 WUQ ZGI ZXP |
| ID | FETCH-LOGICAL-c286t-349e888d9c3cdc5189f4436a0a13f5e8275cfa65a522b6cae507f097029ed8083 |
| ISSN | 0021-9797 |
| IngestDate | Thu Nov 21 23:34:31 EST 2024 Fri Feb 23 02:27:47 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 2 |
| Keywords | hydrolytic stability of grafted layer silica with attached organotin groups Mössbauer spectroscopy |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c286t-349e888d9c3cdc5189f4436a0a13f5e8275cfa65a522b6cae507f097029ed8083 |
| PageCount | 5 |
| ParticipantIDs | crossref_primary_10_1006_jcis_2001_7685 elsevier_sciencedirect_doi_10_1006_jcis_2001_7685 |
| PublicationCentury | 2000 |
| PublicationDate | 2001-09-15 |
| PublicationDateYYYYMMDD | 2001-09-15 |
| PublicationDate_xml | – month: 09 year: 2001 text: 2001-09-15 day: 15 |
| PublicationDecade | 2000 |
| PublicationTitle | Journal of colloid and interface science |
| PublicationYear | 2001 |
| Publisher | Elsevier Inc |
| Publisher_xml | – name: Elsevier Inc |
| References | Nedez, Lefebvre, Choplin (RF7) 1994; 116 Shamov, A. I, Gamma-resonant spectrometer. Author's Inventor Certificate (USSR) 652803, 1978. Nedez, Choplin, Lefebvre, Basset (RF8) 1994; 33 Neumann, Burkhardt (RF16) 1963; 663 Gol'dansky (RF17) 1970 Rachkovsky, Kol'tsov, Aleskovsky (RF4) 1970; 15 de Mallmann, Lot, Perrier (RF10) 1998; 17 Brugemann, S. A., Artsybashev, Yu. A., and Orlov, S. V., The “Univem” program, version 4.50. MNPP “MosTek”, Scentific-Research Institute at Rostov State University, Rostov-na-Donu. Flinn (RF18) 1978 Ballivet-Tkatchenko, dos Santos, Malisova (RF11) 1993; 9 Pande (RF15) 1968; 13 Suzdalev, Gol'dansky, Makarov, Plachinda, Korytko (RF3) 1965; 49 Aleskovsky (RF5) 1978 Kocheshkov, Zemlyansky, Sheverdina, Panov (RF14) 1968 Panichev, Kudryavtsev, Lisichkin (RF6) 1979; 5 Karyagin (RF19) 1963; 148 Nedez, Theolier, Lefebvre (RF9) 1993; 115 Lisichkin, Kudryavtsev, Serdan (RF1) 1986 Lisichkin, Tertykh, Nesterenko (RF2) 1991; 36 Lisichkin (10.1006/jcis.2001.7685_RF1) 1986 10.1006/jcis.2001.7685_RF13 Flinn (10.1006/jcis.2001.7685_RF18) 1978 10.1006/jcis.2001.7685_RF12 Aleskovsky (10.1006/jcis.2001.7685_RF5) 1978 Nedez (10.1006/jcis.2001.7685_RF8) 1994; 33 Kocheshkov (10.1006/jcis.2001.7685_RF14) 1968 Nedez (10.1006/jcis.2001.7685_RF9) 1993; 115 Neumann (10.1006/jcis.2001.7685_RF16) 1963; 663 de Mallmann (10.1006/jcis.2001.7685_RF10) 1998; 17 Suzdalev (10.1006/jcis.2001.7685_RF3) 1965; 49 Lisichkin (10.1006/jcis.2001.7685_RF2) 1991; 36 Nedez (10.1006/jcis.2001.7685_RF7) 1994; 116 Karyagin (10.1006/jcis.2001.7685_RF19) 1963; 148 Gol'dansky (10.1006/jcis.2001.7685_RF17) 1970 Rachkovsky (10.1006/jcis.2001.7685_RF4) 1970; 15 Panichev (10.1006/jcis.2001.7685_RF6) 1979; 5 Pande (10.1006/jcis.2001.7685_RF15) 1968; 13 Ballivet-Tkatchenko (10.1006/jcis.2001.7685_RF11) 1993; 9 |
| References_xml | – volume: 116 start-page: 3039 year: 1994 ident: RF7 publication-title: J. Am. Chem. Soc. contributor: fullname: Choplin – volume: 36 start-page: 695 year: 1991 ident: RF2 publication-title: Zh. Vsesoy. Khim. Obshch. D. I. Mendel. contributor: fullname: Nesterenko – year: 1986 ident: RF1 publication-title: Modified Silicas in Sorption, Catalysis and Chromatography contributor: fullname: Serdan – volume: 13 start-page: 187 year: 1968 ident: RF15 publication-title: J. Organomet. Chem. contributor: fullname: Pande – volume: 17 start-page: 1031 year: 1998 ident: RF10 publication-title: Organometallics contributor: fullname: Perrier – year: 1978 ident: RF5 publication-title: Chemistry of Solids contributor: fullname: Aleskovsky – volume: 148 start-page: 1102 year: 1963 ident: RF19 publication-title: Dokl. Akad. Nauk SSSR contributor: fullname: Karyagin – volume: 49 start-page: 1424 year: 1965 ident: RF3 publication-title: Zh. Eksper. Teoret. Fiz. contributor: fullname: Korytko – volume: 5 start-page: 1141 year: 1979 ident: RF6 publication-title: Koordinat. Khim. contributor: fullname: Lisichkin – year: 1968 ident: RF14 publication-title: Methods of Elementoorganic Chemistry. Germanium, Tin, Lead contributor: fullname: Panov – volume: 15 start-page: 3158 year: 1970 ident: RF4 publication-title: Zh. Neorg. Khim. contributor: fullname: Aleskovsky – volume: 115 start-page: 722 year: 1993 ident: RF9 publication-title: J. Am. Chem. Soc. contributor: fullname: Lefebvre – year: 1970 ident: RF17 publication-title: Chemical Applications of Mössbauer Spectroscopy contributor: fullname: Gol'dansky – start-page: 593 year: 1978 ident: RF18 publication-title: Mössbauer Isomer Shifts contributor: fullname: Flinn – volume: 9 start-page: 3513 year: 1993 ident: RF11 publication-title: Langmuir contributor: fullname: Malisova – volume: 663 start-page: 11 year: 1963 ident: RF16 publication-title: Annalen contributor: fullname: Burkhardt – volume: 33 start-page: 1575 year: 1994 ident: RF8 publication-title: Inorg. Chem. contributor: fullname: Basset – volume: 9 start-page: 3513 year: 1993 ident: 10.1006/jcis.2001.7685_RF11 publication-title: Langmuir doi: 10.1021/la00036a028 contributor: fullname: Ballivet-Tkatchenko – volume: 5 start-page: 1141 year: 1979 ident: 10.1006/jcis.2001.7685_RF6 publication-title: Koordinat. Khim. contributor: fullname: Panichev – start-page: 593 year: 1978 ident: 10.1006/jcis.2001.7685_RF18 contributor: fullname: Flinn – volume: 115 start-page: 722 year: 1993 ident: 10.1006/jcis.2001.7685_RF9 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00055a049 contributor: fullname: Nedez – volume: 17 start-page: 1031 year: 1998 ident: 10.1006/jcis.2001.7685_RF10 publication-title: Organometallics doi: 10.1021/om9708844 contributor: fullname: de Mallmann – volume: 49 start-page: 1424 year: 1965 ident: 10.1006/jcis.2001.7685_RF3 publication-title: Zh. Eksper. Teoret. Fiz. contributor: fullname: Suzdalev – volume: 15 start-page: 3158 year: 1970 ident: 10.1006/jcis.2001.7685_RF4 publication-title: Zh. Neorg. Khim. contributor: fullname: Rachkovsky – year: 1978 ident: 10.1006/jcis.2001.7685_RF5 contributor: fullname: Aleskovsky – volume: 148 start-page: 1102 year: 1963 ident: 10.1006/jcis.2001.7685_RF19 publication-title: Dokl. Akad. Nauk SSSR contributor: fullname: Karyagin – year: 1986 ident: 10.1006/jcis.2001.7685_RF1 contributor: fullname: Lisichkin – year: 1968 ident: 10.1006/jcis.2001.7685_RF14 contributor: fullname: Kocheshkov – volume: 663 start-page: 11 year: 1963 ident: 10.1006/jcis.2001.7685_RF16 publication-title: Annalen doi: 10.1002/jlac.19636630105 contributor: fullname: Neumann – volume: 116 start-page: 3039 year: 1994 ident: 10.1006/jcis.2001.7685_RF7 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00086a037 contributor: fullname: Nedez – volume: 13 start-page: 187 year: 1968 ident: 10.1006/jcis.2001.7685_RF15 publication-title: J. Organomet. Chem. doi: 10.1016/S0022-328X(00)88871-3 contributor: fullname: Pande – volume: 36 start-page: 695 year: 1991 ident: 10.1006/jcis.2001.7685_RF2 publication-title: Zh. Vsesoy. Khim. Obshch. D. I. Mendel. contributor: fullname: Lisichkin – volume: 33 start-page: 1575 year: 1994 ident: 10.1006/jcis.2001.7685_RF8 publication-title: Inorg. Chem. doi: 10.1021/ic00085a061 contributor: fullname: Nedez – ident: 10.1006/jcis.2001.7685_RF12 – year: 1970 ident: 10.1006/jcis.2001.7685_RF17 contributor: fullname: Gol'dansky – ident: 10.1006/jcis.2001.7685_RF13 |
| SSID | ssj0011559 |
| Score | 1.690827 |
| Snippet | It is shown that alkylchlorostannanes can be successfully used for synthesis of chemically modified silica. The hydrolytic stability of the materials obtained... |
| SourceID | crossref elsevier |
| SourceType | Aggregation Database Publisher |
| StartPage | 434 |
| SubjectTerms | hydrolytic stability of grafted layer Mössbauer spectroscopy silica with attached organotin groups |
| Title | Organotin Compounds in Synthesis of Chemically Modified Silica |
| URI | https://dx.doi.org/10.1006/jcis.2001.7685 |
| Volume | 241 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3PT9swFLYKHLYdELBN46dymLRTstpxXOeChGgHTNMuZRM7RW5ii0jQIGiRyl_Pe_GPFI1JY9IuUePWSev39fmL3_P3CPkohAESQlVMmRYxl32M72r4u4uUTmCCFjZiejoefL-QwxEf9XpeqqJr-6-WhjawNe6cfYG1w0WhAV6DzeEIVofjX9m93VzZzNrNfNc3WDSpzXgdL6ZA9Zz6iFcJuFpgLbTaIA0d1yFt53euimhp6spJNWFla4XStNYvBJthde2rRXPfMtPkJAnBnIdLfe8WaYfJz6Rzx7cG7qrbDr_myTC8860G8Fy6SmEnvotfnKCYSWG3Z9oVM79r5klSp00LGdi83ERbxwtUD_NC02XPzKwmloMgW_Kz3K2Aancmn50NwKPgbFDWrS47TeDRKuvmvZCNiAFrit8H6C5-hK-QNQZ-C9zm2tHZ6OJrCEthDNfmDNkf4FVA--Lz07s8z3KWmMv5Bll3ZoyOLFY2SU9Pt8irY1_pb4u8WRKlfEsOA4KigKAITgKCosZEHYIij6DIIugd-fFldH58GrsqG3HJpJjFKc-1lLLKy7SsyozK3HCeCtVXNDWZlmyQlUaJTAFTn4hSaXiCMH0YLJbrSgKDf09Wp81UfyCRyozilWFMocRCSSeKq4q21a1pTqt8m3zyo1LcWDGVwspmiwLHD2ui0gLHb5tQP2iFA7OleAXY9g99dv6hzy553cF2j6zObud6n6zcVfMDZ_tHuXt7LA |
| link.rule.ids | 315,782,786,27933,27934 |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Organotin+Compounds+in+Synthesis+of+Chemically+Modified+Silica&rft.jtitle=Journal+of+colloid+and+interface+science&rft.au=Mingalyov%2C+P.G.&rft.au=Rzhevsky%2C+D.V.&rft.au=Perfiliev%2C+Yu.D.&rft.au=Lisichkin%2C+G.V.&rft.date=2001-09-15&rft.pub=Elsevier+Inc&rft.issn=0021-9797&rft.eissn=1095-7103&rft.volume=241&rft.issue=2&rft.spage=434&rft.epage=438&rft_id=info:doi/10.1006%2Fjcis.2001.7685&rft.externalDocID=S0021979701976854 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0021-9797&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0021-9797&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0021-9797&client=summon |