ONE-POT OXIDATION AND WITTIG OLEFINATION OF ALCOHOLS USING O-IODOXYBENZOIC ACID AND STABLE WITTIG YLIDE

ONE-POT OXIDATION AND WITTIG OLEFINATION OF ALCOHOLS USING O-IODOXYBENZOIC ACID AND STABLE WITTIG YLIDE

Benylic, allylic, and propargylic alcohols, as well as diols, can be oxidized with o-iodoxybenzoic acid (IBX) in the presence of stabilized Wittig ylide [1] to generate α,β-unsaturated ester in one pot. This is useful when the intermediate aldehydes are unstable and difficult to isolate. * IICT comm...

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Bibliographic Details
Published in:Synthetic communications Vol. 31; no. 10; pp. 1499 - 1506
Main Authors: Maiti, Arup, Yadav, J. S.
Format: Journal Article
Language:English
Published: Taylor & Francis Group 01-01-2001
Online Access:Get full text
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Summary:Benylic, allylic, and propargylic alcohols, as well as diols, can be oxidized with o-iodoxybenzoic acid (IBX) in the presence of stabilized Wittig ylide [1] to generate α,β-unsaturated ester in one pot. This is useful when the intermediate aldehydes are unstable and difficult to isolate. * IICT communication no. 4369.
ISSN:0039-7911
1532-2432
DOI:10.1081/SCC-100104061