The effect of yttrium on oxide scale growth on Co-Al-W-based superalloys
The study on the individual role of yttrium (Y) and Y-related phases during scale formation on Co-9Al-9 W (at%) and other Co-based alloys during isothermal and cyclic oxidation at 900 °C was performed. The addition of Y increased the oxidation resistance of Co-(Ni)-Al-W alloys, especially under cycl...
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| Published in: | Corrosion science Vol. 208; p. 110674 |
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01-11-2022
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| Abstract | The study on the individual role of yttrium (Y) and Y-related phases during scale formation on Co-9Al-9 W (at%) and other Co-based alloys during isothermal and cyclic oxidation at 900 °C was performed. The addition of Y increased the oxidation resistance of Co-(Ni)-Al-W alloys, especially under cyclic conditions due to an oxide keying effect related to the internal oxidation of Y-containing phase constituents. The Y-containing oxide areas corresponded in number, size, shape, and spatial distribution to the original Y-rich particles in the alloy. The mechanism describing the formation of Y-related oxides within the oxide scale was proposed.
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•Improvement of oxidation resistance of Co-Al-W-based alloys by Y-addition.•Formation of Y-rich oxide inclusions connected with the “keying” effect.•Preferential oxidation of Y-containing alloys via Y-rich intermetallic phases.•Oxidation of Y contained in YCo5 to Y2O3 in the internal oxidation zone and formation of Y2WO6 in the middle oxide zone.•Heritage of oxide inclusions morphology from Y-rich intermetallic phases. |
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| AbstractList | The study on the individual role of yttrium (Y) and Y-related phases during scale formation on Co-9Al-9 W (at%) and other Co-based alloys during isothermal and cyclic oxidation at 900 °C was performed. The addition of Y increased the oxidation resistance of Co-(Ni)-Al-W alloys, especially under cyclic conditions due to an oxide keying effect related to the internal oxidation of Y-containing phase constituents. The Y-containing oxide areas corresponded in number, size, shape, and spatial distribution to the original Y-rich particles in the alloy. The mechanism describing the formation of Y-related oxides within the oxide scale was proposed.
[Display omitted]
•Improvement of oxidation resistance of Co-Al-W-based alloys by Y-addition.•Formation of Y-rich oxide inclusions connected with the “keying” effect.•Preferential oxidation of Y-containing alloys via Y-rich intermetallic phases.•Oxidation of Y contained in YCo5 to Y2O3 in the internal oxidation zone and formation of Y2WO6 in the middle oxide zone.•Heritage of oxide inclusions morphology from Y-rich intermetallic phases. |
| ArticleNumber | 110674 |
| Author | Chmiela, Bartosz Myalska-Głowacka, Hanna Migas, Damian Matus, Krzysztof Moskal, Grzegorz Swadźba, Radosław |
| Author_xml | – sequence: 1 givenname: Damian surname: Migas fullname: Migas, Damian email: damian.migas@polsl.pl organization: Silesian University of Technology, Department of Materials Technologies, Krasińskiego St. 8, 40–019 Katowice, Poland – sequence: 2 givenname: Bartosz surname: Chmiela fullname: Chmiela, Bartosz organization: Silesian University of Technology, Department of Materials Technologies, Krasińskiego St. 8, 40–019 Katowice, Poland – sequence: 3 givenname: Hanna surname: Myalska-Głowacka fullname: Myalska-Głowacka, Hanna organization: Silesian University of Technology, Department of Materials Technologies, Krasińskiego St. 8, 40–019 Katowice, Poland – sequence: 4 givenname: Grzegorz surname: Moskal fullname: Moskal, Grzegorz organization: Silesian University of Technology, Department of Materials Technologies, Krasińskiego St. 8, 40–019 Katowice, Poland – sequence: 5 givenname: Krzysztof surname: Matus fullname: Matus, Krzysztof organization: Silesian University of Technology, Materials Research Laboratory, Konarskiego 18A St., 44–100 Gliwice, Poland – sequence: 6 givenname: Radosław surname: Swadźba fullname: Swadźba, Radosław organization: Łukasiewicz Research Network - Institute for Ferrous Metallurgy, 44–100 Gliwice, Poland |
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| Keywords | Reactive elements effect Oxidation Superalloys Yttrium γ–γ′ cobalt-based superalloys |
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| Title | The effect of yttrium on oxide scale growth on Co-Al-W-based superalloys |
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