Silyl methallylsulfinates: efficient and powerful agents for the chemoselective silylation of alcohols, polyols, phenols and carboxylic acids

Silyl methallylsulfinates: efficient and powerful agents for the chemoselective silylation of alcohols, polyols, phenols and carboxylic acids

Alcohols, phenols and carboxylic acids are silylated with very good yields in the presence of silyl methallylsulfinates under non-basic conditions and with the formation of volatile co-products.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) no. 10; p. 1297
Main Authors: Huang, Xiaogen, Craita, Cotinica, Awad, Loay, Vogel, Pierre
Format: Journal Article
Language:English
Published: England 14-03-2005
Subjects:
Alcohols - chemistry
Carboxylic Acids - chemistry
Esters - chemical synthesis
Esters - chemistry
Molecular Structure
Phenols - chemistry
Polymers - chemistry
Silanes - chemistry
Stereoisomerism
Sulfur Compounds - chemistry
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Description
Summary:Alcohols, phenols and carboxylic acids are silylated with very good yields in the presence of silyl methallylsulfinates under non-basic conditions and with the formation of volatile co-products.
ISSN:1359-7345
DOI:10.1039/b417894g