Semihard magnetic properties of TiFe2.5 iron-rich Laves phase and the effect of 4d- and 5d-element-substitutions for Ti
•Magnetic anisotropy of Fe-rich TiFe2.5 Laves phase is uniaxial, but it is weak.•Nb, Mo, Ta, W increase the anisotropy field only below room temperature.•Zr, Hf increase the Curie temperature and lead to a spin reorientation below 200 K.•Maximum coercivity induced via high-energy milling is 2.9% of...
Saved in:
| Published in: | Journal of magnetism and magnetic materials Vol. 583; p. 171080 |
|---|---|
| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
United States
Elsevier B.V
01-10-2023
Elsevier |
| Subjects: | |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | •Magnetic anisotropy of Fe-rich TiFe2.5 Laves phase is uniaxial, but it is weak.•Nb, Mo, Ta, W increase the anisotropy field only below room temperature.•Zr, Hf increase the Curie temperature and lead to a spin reorientation below 200 K.•Maximum coercivity induced via high-energy milling is 2.9% of the anisotropy field.
Rare-earth-free compounds exhibiting modest intrinsic hard magnetic properties may still yield viable permanent magnets if their constituent elements are abundant and inexpensive, and the properties are at least comparable to those of the hard ferrites. In this study, one such compound, the off-stoichiometric TiFe2.5 Laves phase with the hexagonal C14 crystal structure, was found to exhibit – in addition to the already known room-temperature ferromagnetism – a uniaxial, albeit weak, magnetic anisotropy. With a Curie temperature of 422 K, saturation magnetization of 55.3 Am2/kg and magnetic hardness parameter of 0.97 this semihard compound is just below the threshold for being of interest for the development into permanent magnets. Replacing a small fraction of Ti with the 4d Nb and Mo or with the 5d Ta or W increases the anisotropy field, but only below room temperature. Replacing Ti with Zr or Hf increases the Curie temperature and leads to a spin reorientation below 200 K. All these substitutions, as well as combined (Zr,W) and (Nb,W) substitutions, fail to improve the room-temperature intrinsic hard magnetic properties of the Fe-rich Laves phase. Furthermore, an attempt to develop a room-temperature coercivity through high-energy ball-milling yielded a value of 0.026 T, an unusually small 2.9% fraction of the anisotropy field. Defects inherent in the C14 crystal lattice may be responsible for the underperformance. |
|---|---|
| AbstractList | •Magnetic anisotropy of Fe-rich TiFe2.5 Laves phase is uniaxial, but it is weak.•Nb, Mo, Ta, W increase the anisotropy field only below room temperature.•Zr, Hf increase the Curie temperature and lead to a spin reorientation below 200 K.•Maximum coercivity induced via high-energy milling is 2.9% of the anisotropy field.
Rare-earth-free compounds exhibiting modest intrinsic hard magnetic properties may still yield viable permanent magnets if their constituent elements are abundant and inexpensive, and the properties are at least comparable to those of the hard ferrites. In this study, one such compound, the off-stoichiometric TiFe2.5 Laves phase with the hexagonal C14 crystal structure, was found to exhibit – in addition to the already known room-temperature ferromagnetism – a uniaxial, albeit weak, magnetic anisotropy. With a Curie temperature of 422 K, saturation magnetization of 55.3 Am2/kg and magnetic hardness parameter of 0.97 this semihard compound is just below the threshold for being of interest for the development into permanent magnets. Replacing a small fraction of Ti with the 4d Nb and Mo or with the 5d Ta or W increases the anisotropy field, but only below room temperature. Replacing Ti with Zr or Hf increases the Curie temperature and leads to a spin reorientation below 200 K. All these substitutions, as well as combined (Zr,W) and (Nb,W) substitutions, fail to improve the room-temperature intrinsic hard magnetic properties of the Fe-rich Laves phase. Furthermore, an attempt to develop a room-temperature coercivity through high-energy ball-milling yielded a value of 0.026 T, an unusually small 2.9% fraction of the anisotropy field. Defects inherent in the C14 crystal lattice may be responsible for the underperformance. Rare-earth-free compounds exhibiting modest intrinsic hard magnetic properties may still yield viable permanent magnets if their constituent elements are abundant and inexpensive, and the properties are at least comparable to those of the hard ferrites. In this study, one such compound, the off-stoichiometric TiFe2.5 Laves phase with the hexagonal C14 crystal structure, was found to exhibit – in addition to the already known room-temperature ferromagnetism – a uniaxial, albeit weak, magnetic anisotropy. With a Curie temperature of 422 K, saturation magnetization of 55.3 Am2/kg and magnetic hardness parameter of 0.97 this semihard compound is just below the threshold for being of interest for the development into permanent magnets. Replacing a small fraction of Ti with the 4d Nb and Mo or with the 5d Ta or W increases the anisotropy field, but only below room temperature. Replacing Ti with Zr or Hf increases the Curie temperature and leads to a spin reorientation below 200 K. All these substitutions, as well as combined (Zr,W) and (Nb,W) substitutions, fail to improve the room-temperature intrinsic hard magnetic properties of the Fe-rich Laves phase. Furthermore, an attempt to develop a room-temperature coercivity through high-energy ball-milling yielded a value of 0.026 T, an unusually small 2.9% fraction of the anisotropy field. Here, defects inherent in the C14 crystal lattice may be responsible for the underperformance. |
| ArticleNumber | 171080 |
| Author | Han, Chaoya Gabay, A.M. Hadjipanayis, G.C. Ni, Chaoying |
| Author_xml | – sequence: 1 givenname: A.M. orcidid: 0000-0002-4812-186X surname: Gabay fullname: Gabay, A.M. email: gabay@udel.edu organization: Department of Physics and Astronomy, University of Delaware, Newark, DE 19716, USA – sequence: 2 givenname: Chaoya surname: Han fullname: Han, Chaoya email: chyhan@udel.edu organization: Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA – sequence: 3 givenname: Chaoying orcidid: 0000-0001-6043-508X surname: Ni fullname: Ni, Chaoying email: cni@udel.edu organization: Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA – sequence: 4 givenname: G.C. surname: Hadjipanayis fullname: Hadjipanayis, G.C. email: hadji@udel.edu organization: Department of Physics and Astronomy, University of Delaware, Newark, DE 19716, USA |
| BackLink | https://www.osti.gov/servlets/purl/1992242$$D View this record in Osti.gov |
| BookMark | eNp9kE9PAyEQxTnUxFb9Ap6I912Bhf2TeDGNVZMmHqxnQtnBpelCA7TGby9rPXuaZOa9X968BZo57wChW0pKSmh9vyt34ziWjLCqpA0lLZmhOakIL9pWVJdoEeOOEEJ5W8_R1zuMdlChx6P6dJCsxofgDxCShYi9wRu7AlYKbIN3RbB6wGt1yqfDoCJg5XqcBsBgDOg06Xlf_G5FX8AeRnCpiMdtTDYdk_UuYuNDhl6jC6P2EW7-5hX6WD1tli_F-u35dfm4LjRr2lR0xvCOq5aJbd0wzbuOGMaZqNtWm6YzYLbM9LwWglfU1HVDBNT5MwoKemG21RW6O3N9jiCjtgn0oL1zOa6kXccyLYvYWaSDjzGAkYdgRxW-JSVy6lTu5NSpnDqV506z6eFsghz_ZCFMdHAaehsmeO_tf_Yf-VODLg |
| Cites_doi | 10.1107/S0021889895014920 10.1021/ja01195a024 10.1016/j.scriptamat.2012.04.036 10.1063/1.5079727 10.1063/1.5006488 10.1103/PhysRevB.101.014426 10.1016/j.actamat.2019.05.041 10.1002/pssb.19680290124 10.1016/S0304-8853(98)00298-4 10.1063/1.4868696 10.1063/1.1658924 10.1007/BF02868286 10.1143/JPSJ.25.1189 10.1016/0378-4363(86)90492-4 10.1109/TMAG.2013.2245868 10.1016/j.jmst.2020.05.042 10.1016/j.actamat.2018.07.049 10.1016/0022-5088(86)90690-9 10.3390/cryst10060430 10.1103/PhysRevB.96.064422 10.1002/pssr.201700184 10.1063/1.361206 10.1016/0304-8853(86)90014-4 10.1016/j.scriptamat.2015.09.021 10.1016/0022-5088(88)90347-5 10.1063/1.5097081 10.1016/j.intermet.2004.02.010 10.1109/TMAG.2011.2166975 10.1109/TMAG.2023.3280849 10.1103/PhysRevB.98.214431 |
| ContentType | Journal Article |
| Copyright | 2023 Elsevier B.V. |
| Copyright_xml | – notice: 2023 Elsevier B.V. |
| CorporateAuthor | Univ. of Delaware, Newark, DE (United States) |
| CorporateAuthor_xml | – name: Univ. of Delaware, Newark, DE (United States) |
| DBID | AAYXX CITATION OIOZB OTOTI |
| DOI | 10.1016/j.jmmm.2023.171080 |
| DatabaseName | CrossRef OSTI.GOV - Hybrid OSTI.GOV |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Physics |
| ExternalDocumentID | 1992242 10_1016_j_jmmm_2023_171080 S0304885323007308 |
| GroupedDBID | --K --M -~X .~1 0R~ 1B1 1RT 1~. 1~5 4.4 457 4G. 5GY 6OB 7-5 71M 8P~ 9JN AABNK AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAXUO ABFNM ABMAC ABNEU ABYKQ ACDAQ ACFVG ACGFS ACIWK ACRLP ADBBV ADEZE AEBSH AEKER AENEX AFKWA AFTJW AGUBO AGYEJ AHHHB AIEXJ AIKHN AITUG AIVDX AJOXV ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EO8 EO9 EP2 EP3 F5P FDB FIRID FNPLU FYGXN G-Q GBLVA IHE J1W K-O KOM M24 M38 M41 MO0 N9A O-L O9- OAUVE OGIMB OZT P-8 P-9 P2P PC. Q38 RNS ROL RPZ SCU SDF SDG SDP SES SEW SPC SPCBC SPD SSQ SSZ T5K XPP ZMT ~02 ~G- 29K 5VS AAQFI AAQXK AAXKI AAYXX ABXDB ACNNM ADMUD AFFNX AFJKZ AGHFR AKRWK ASPBG AVWKF AZFZN BBWZM CITATION D-I EJD FGOYB G-2 HMV HZ~ NDZJH R2- RIG SMS SPG WUQ XXG OIOZB OTOTI |
| ID | FETCH-LOGICAL-c278t-9ff494a825b672c4990f2425688cf79fefb2fd4655431f66705e61481eaed5fb3 |
| ISSN | 0304-8853 |
| IngestDate | Mon Jul 29 06:04:08 EDT 2024 Thu Sep 26 19:04:08 EDT 2024 Fri Feb 23 02:36:02 EST 2024 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Rare-earth-free magnets Spin–orbit coupling Magnetic anisotropy Laves phase |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c278t-9ff494a825b672c4990f2425688cf79fefb2fd4655431f66705e61481eaed5fb3 |
| Notes | USDOE Office of Science (SC), Basic Energy Sciences (BES) SC0022168; DE SC0022168 |
| ORCID | 0000-0001-6043-508X 0000-0002-4812-186X 000000024812186X 000000016043508X |
| OpenAccessLink | https://www.osti.gov/servlets/purl/1992242 |
| ParticipantIDs | osti_scitechconnect_1992242 crossref_primary_10_1016_j_jmmm_2023_171080 elsevier_sciencedirect_doi_10_1016_j_jmmm_2023_171080 |
| PublicationCentury | 2000 |
| PublicationDate | 2023-10-01 |
| PublicationDateYYYYMMDD | 2023-10-01 |
| PublicationDate_xml | – month: 10 year: 2023 text: 2023-10-01 day: 01 |
| PublicationDecade | 2020 |
| PublicationPlace | United States |
| PublicationPlace_xml | – name: United States |
| PublicationTitle | Journal of magnetism and magnetic materials |
| PublicationYear | 2023 |
| Publisher | Elsevier B.V Elsevier |
| Publisher_xml | – name: Elsevier B.V – name: Elsevier |
| References | Brückner, Perthel, Kleinstück, Schulze (b0060) 1968; 29 Gabay, Hadjipanayis (b0050) 2019; 9 A.M. Gabay, Chaoya Han, Chaoying Ni, G.C. Hadjipanayis, Assessment of directionally solidified eutectic Sm–Fe(Co)–Ti alloys as permanent magnet materials, IEEE Trans. Magn., in press, doi: 10.1109/TMAG.2023.3280849. Stein, Palm, Sauthoff (b0155) 2004; 12 Zhang, Li, Valloppilly, Skomski, Shield, Sellmyer (b0085) 2014; 115 Coey (b0005) 2011; 47 Wang, Jo, Wu (b0090) 2008; 92 Cui, Kramer, Zhou, Liu, Gabay, Hadjipanayis, Balasubramanian, Sellmyer (b0020) 2018; 158 Arapan, Nieves, Herper, Legut (b0110) 2020; 101 Goll, Gross, Loeffler, Pflanz, Vogel, Kopp, Grubesa, Schneider (b0030) 2017 Cui, Marinescu, Liu (b0115) 2013; 49 Kim, Kwon, Lee, Yu (b0120) 2013; 49 Edström (b0025) 2017; 96 Gabay, Hadjipanayis (b0045) 2018; 8 Nakamichi (b0075) 1968; 25 Werwiński, Edström, Rusz, Hedlund, Gunnarsson, Svedlindh, Cedervall, Sahlberg (b0100) 2018; 98 Blazina, Trojko (b0140) 1986; 119 Murray (b0065) 1981; 2 Pauling (b0135) 1947; 69 Macrí, Enzo, Cowlam, Rose, Principi, Gupta (b0165) 1996; 79 Hirosawa, Nishino, Miyashita (b0010) 2017; 8 Kumar, Kashyap, Balamurugan, Shield, Sellmyer, Skomski (b0095) 2014; 26 Goll, Loeffler, Pflanz, Gross, Schneider (b0040) 2017 Wassermann, Rellinghaus, Roessel, Pepperhoff (b0070) 1998; 190 Coey (b0015) 2012; 67 Asrar, Meshkov, Sokolovskaya (b0145) 1988; 144 Van der Kraan, Buschow (b0150) 1986; 138 L. Kyvala, M. Tchaplianka, A.B. Shick, S. Khmelevskyi, D. Legut, Large uniaxial magnetic anisotropy of hexagonal Fe-Hf-Sb alloys, Cryst. 10 (2020) 430,doi: 10.3390/cryst10060430. Kraus, Nolze (b0125) 1996; 29 Yang, Kong, Lu, Zhang, Yang, Yan, Li, Du (b0175) 2021; 62 Wertheim, Wernick, Sherwood (b0080) 1970; 41 Chung, Yang, Shiojiri, Hsiao, Li, Tsao, Shi, Lin, Yang (b0170) 2019; 174 Skomski, Coey (b0160) 2016; 112 Durst, Kronmüller (b0130) 1986; 59 Thakur, Rani, Tomar, Gupta, Kashyap (b0105) 2019; 2093 Goll (10.1016/j.jmmm.2023.171080_b0040) 2017 Goll (10.1016/j.jmmm.2023.171080_b0030) 2017 Yang (10.1016/j.jmmm.2023.171080_b0175) 2021; 62 Hirosawa (10.1016/j.jmmm.2023.171080_b0010) 2017; 8 Wertheim (10.1016/j.jmmm.2023.171080_b0080) 1970; 41 Gabay (10.1016/j.jmmm.2023.171080_b0050) 2019; 9 Blazina (10.1016/j.jmmm.2023.171080_b0140) 1986; 119 Werwiński (10.1016/j.jmmm.2023.171080_b0100) 2018; 98 Wassermann (10.1016/j.jmmm.2023.171080_b0070) 1998; 190 Murray (10.1016/j.jmmm.2023.171080_b0065) 1981; 2 Asrar (10.1016/j.jmmm.2023.171080_b0145) 1988; 144 Edström (10.1016/j.jmmm.2023.171080_b0025) 2017; 96 Kraus (10.1016/j.jmmm.2023.171080_b0125) 1996; 29 Arapan (10.1016/j.jmmm.2023.171080_b0110) 2020; 101 Chung (10.1016/j.jmmm.2023.171080_b0170) 2019; 174 10.1016/j.jmmm.2023.171080_b0035 10.1016/j.jmmm.2023.171080_b0055 Coey (10.1016/j.jmmm.2023.171080_b0015) 2012; 67 Cui (10.1016/j.jmmm.2023.171080_b0020) 2018; 158 Skomski (10.1016/j.jmmm.2023.171080_b0160) 2016; 112 Kim (10.1016/j.jmmm.2023.171080_b0120) 2013; 49 Stein (10.1016/j.jmmm.2023.171080_b0155) 2004; 12 Durst (10.1016/j.jmmm.2023.171080_b0130) 1986; 59 Pauling (10.1016/j.jmmm.2023.171080_b0135) 1947; 69 Nakamichi (10.1016/j.jmmm.2023.171080_b0075) 1968; 25 Thakur (10.1016/j.jmmm.2023.171080_b0105) 2019; 2093 Zhang (10.1016/j.jmmm.2023.171080_b0085) 2014; 115 Macrí (10.1016/j.jmmm.2023.171080_b0165) 1996; 79 Gabay (10.1016/j.jmmm.2023.171080_b0045) 2018; 8 Cui (10.1016/j.jmmm.2023.171080_b0115) 2013; 49 Van der Kraan (10.1016/j.jmmm.2023.171080_b0150) 1986; 138 Wang (10.1016/j.jmmm.2023.171080_b0090) 2008; 92 Brückner (10.1016/j.jmmm.2023.171080_b0060) 1968; 29 Kumar (10.1016/j.jmmm.2023.171080_b0095) 2014; 26 Coey (10.1016/j.jmmm.2023.171080_b0005) 2011; 47 |
| References_xml | – volume: 138 start-page: 55 year: 1986 end-page: 62 ident: b0150 article-title: The publication-title: Physica B+C contributor: fullname: Buschow – volume: 115 start-page: 17A769 year: 2014 ident: b0085 article-title: Development and intrinsic properties of hexagonal ferromagnetic (Zr, Ti)F publication-title: J. Appl. Phys. contributor: fullname: Sellmyer – volume: 92 year: 2008 ident: b0090 article-title: Magnetic properties of Fe-5 publication-title: Appl. Phys. Lett. contributor: fullname: Wu – volume: 9 year: 2019 ident: b0050 article-title: Semi-hard magnetic nanocomposites based on out-of-equilibrium Fe publication-title: AIP Adv. contributor: fullname: Hadjipanayis – volume: 190 start-page: 289 year: 1998 end-page: 301 ident: b0070 article-title: Relation between structure and magnetism of Ti publication-title: J. Magn. Magn. Mater contributor: fullname: Pepperhoff – volume: 49 start-page: 3322 year: 2013 end-page: 3325 ident: b0115 article-title: Ferromagnetic tetragonal L1 publication-title: IEEE Trans. Magn. contributor: fullname: Liu – volume: 174 start-page: 351 year: 2019 end-page: 368 ident: b0170 article-title: An atomic scale structural investigation of nanometre-sized η precipitates in the 7050 aluminium alloy publication-title: Acta Mater. contributor: fullname: Yang – volume: 62 start-page: 203 year: 2021 end-page: 213 ident: b0175 article-title: Self-accommodated defect structures modifying the growth of Laves phase publication-title: J. Mater. Sci. Technol. contributor: fullname: Du – volume: 69 start-page: 542 year: 1947 end-page: 553 ident: b0135 article-title: Atomic radii and interatomic distances in metals publication-title: J. Am. Chem. Soc. contributor: fullname: Pauling – volume: 2 start-page: 320 year: 1981 end-page: 334 ident: b0065 article-title: The Fe-Ti (iron-titanium) system publication-title: Bull. Alloy Phase Diagr. contributor: fullname: Murray – volume: 119 start-page: 297 year: 1986 end-page: 305 ident: b0140 article-title: Structural investigations of the Nb publication-title: J. Less-Common Met. contributor: fullname: Trojko – start-page: 1700184 year: 2017 ident: b0030 article-title: Hard magnetic off-stoichiometric (Fe, Sb) publication-title: Phys. Status Solidi RRL contributor: fullname: Schneider – volume: 67 start-page: 524 year: 2012 end-page: 529 ident: b0015 article-title: Permanent magnets: Plugging the gap publication-title: Scr. Mater. contributor: fullname: Coey – volume: 158 start-page: 118 year: 2018 end-page: 213 ident: b0020 article-title: Current progress and future challenges in rare-earth-free permanent magnets publication-title: Acta Mater. contributor: fullname: Sellmyer – volume: 96 year: 2017 ident: b0025 article-title: Magnetocrystalline anisotropy of Laves phase Fe publication-title: Rev. B contributor: fullname: Edström – volume: 2093 year: 2019 ident: b0105 article-title: Enhancement of magnetic anisotropy of Fe publication-title: AIP Conf. Proc. contributor: fullname: Kashyap – volume: 26 year: 2014 ident: b0095 article-title: Permanent magnetism of intermetallic compounds between light and heavy transition-metal elements publication-title: J. Phys.: Condens. Matter contributor: fullname: Skomski – volume: 101 year: 2020 ident: b0110 article-title: Computational screening of Fe-Ta hard magnetic phases publication-title: Phys. Rev. B contributor: fullname: Legut – volume: 8 year: 2017 ident: b0010 article-title: Perspectives for high-performance permanent magnets: applications, coercivity, and new materials publication-title: Adv. Nat. Sci.: Nanosci. Nanotechnol. contributor: fullname: Miyashita – volume: 112 start-page: 3 year: 2016 end-page: 8 ident: b0160 article-title: Magnetic anisotropy — How much is enough for a permanent magnet? publication-title: Scr. Mater. contributor: fullname: Coey – volume: 29 start-page: 301 year: 1996 end-page: 303 ident: b0125 article-title: Powder Cell - a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns publication-title: J. Appl. Crystallogr. contributor: fullname: Nolze – volume: 12 start-page: 713 year: 2004 end-page: 720 ident: b0155 article-title: Structure and stability of Laves phases. Part I. Critical assessment of factors controlling Laves phase stability publication-title: Intermetallics contributor: fullname: Sauthoff – volume: 47 start-page: 4671 year: 2011 end-page: 4681 ident: b0005 article-title: Hard magnetic materials: A perspective publication-title: IEEE Trans. Magn. contributor: fullname: Coey – start-page: 1700221 year: 2017 ident: b0040 article-title: Hard magnetic Laves-type (Fe, Si) publication-title: Phys. Status Solidi RRL contributor: fullname: Schneider – volume: 49 start-page: 2101805 year: 2013 ident: b0120 article-title: Coercivity and phase evolution in mechanically milled (FeCo) publication-title: IEEE Trans. Magn. contributor: fullname: Yu – volume: 8 year: 2018 ident: b0045 article-title: Assessment of off-stoichiometric Zr publication-title: AIP Adv. contributor: fullname: Hadjipanayis – volume: 79 start-page: 3730 year: 1996 end-page: 3738 ident: b0165 article-title: The study of nonequilibrium Fe–Ti alloys prepared by high-energy mechanical deformation publication-title: J. Appl. Phys. contributor: fullname: Gupta – volume: 29 start-page: 211 year: 1968 end-page: 216 ident: b0060 article-title: Magnetic properties of ZrFe publication-title: Physica Status Solidi B contributor: fullname: Schulze – volume: 25 start-page: 1189 year: 1968 ident: b0075 article-title: Ferro- and antiferromagnetism of the Laves phase compound in Fe-Ti alloy system publication-title: J. Phys. Soc. Japan contributor: fullname: Nakamichi – volume: 59 start-page: 86 year: 1986 end-page: 94 ident: b0130 article-title: Determination of intrinsic magnetic material parameters of Nd publication-title: J. Magn. Magn. Mater. contributor: fullname: Kronmüller – volume: 41 start-page: 1325 year: 1970 end-page: 1326 ident: b0080 article-title: Model for the composition-dependent ferromagnetic to antiferromagnetic transition in Fe publication-title: J. Appl. Phys. contributor: fullname: Sherwood – volume: 144 start-page: 41 year: 1988 end-page: 52 ident: b0145 article-title: Phase equilibria in ternary alloys based on iron-group metals and containing refractory metals (Mo, W, Nb, Ta) publication-title: J. Less-Common Met. contributor: fullname: Sokolovskaya – volume: 98 year: 2018 ident: b0100 article-title: Magnetocrystalline anisotropy of Fe publication-title: Phys. Rev. B contributor: fullname: Sahlberg – volume: 29 start-page: 301 year: 1996 ident: 10.1016/j.jmmm.2023.171080_b0125 article-title: Powder Cell - a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns publication-title: J. Appl. Crystallogr. doi: 10.1107/S0021889895014920 contributor: fullname: Kraus – volume: 69 start-page: 542 year: 1947 ident: 10.1016/j.jmmm.2023.171080_b0135 article-title: Atomic radii and interatomic distances in metals publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01195a024 contributor: fullname: Pauling – volume: 67 start-page: 524 year: 2012 ident: 10.1016/j.jmmm.2023.171080_b0015 article-title: Permanent magnets: Plugging the gap publication-title: Scr. Mater. doi: 10.1016/j.scriptamat.2012.04.036 contributor: fullname: Coey – volume: 9 year: 2019 ident: 10.1016/j.jmmm.2023.171080_b0050 article-title: Semi-hard magnetic nanocomposites based on out-of-equilibrium Fe2+δNb and Fe2+δTa Laves phases publication-title: AIP Adv. doi: 10.1063/1.5079727 contributor: fullname: Gabay – volume: 8 year: 2018 ident: 10.1016/j.jmmm.2023.171080_b0045 article-title: Assessment of off-stoichiometric Zr33-xFe52+xSi15 C14 Laves phase compounds as permanent magnet materials publication-title: AIP Adv. doi: 10.1063/1.5006488 contributor: fullname: Gabay – volume: 101 year: 2020 ident: 10.1016/j.jmmm.2023.171080_b0110 article-title: Computational screening of Fe-Ta hard magnetic phases publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.101.014426 contributor: fullname: Arapan – volume: 174 start-page: 351 year: 2019 ident: 10.1016/j.jmmm.2023.171080_b0170 article-title: An atomic scale structural investigation of nanometre-sized η precipitates in the 7050 aluminium alloy publication-title: Acta Mater. doi: 10.1016/j.actamat.2019.05.041 contributor: fullname: Chung – volume: 29 start-page: 211 year: 1968 ident: 10.1016/j.jmmm.2023.171080_b0060 article-title: Magnetic properties of ZrFe2 and TiFe2 within their homogeneity range publication-title: Physica Status Solidi B doi: 10.1002/pssb.19680290124 contributor: fullname: Brückner – volume: 190 start-page: 289 year: 1998 ident: 10.1016/j.jmmm.2023.171080_b0070 article-title: Relation between structure and magnetism of TixFe100-x alloys within the C14 Laves-phase stability range publication-title: J. Magn. Magn. Mater. doi: 10.1016/S0304-8853(98)00298-4 contributor: fullname: Wassermann – volume: 115 start-page: 17A769 year: 2014 ident: 10.1016/j.jmmm.2023.171080_b0085 article-title: Development and intrinsic properties of hexagonal ferromagnetic (Zr, Ti)Fe2 publication-title: J. Appl. Phys. doi: 10.1063/1.4868696 contributor: fullname: Zhang – volume: 8 year: 2017 ident: 10.1016/j.jmmm.2023.171080_b0010 article-title: Perspectives for high-performance permanent magnets: applications, coercivity, and new materials publication-title: Adv. Nat. Sci.: Nanosci. Nanotechnol. contributor: fullname: Hirosawa – volume: 41 start-page: 1325 year: 1970 ident: 10.1016/j.jmmm.2023.171080_b0080 article-title: Model for the composition-dependent ferromagnetic to antiferromagnetic transition in Fe2Ti publication-title: J. Appl. Phys. doi: 10.1063/1.1658924 contributor: fullname: Wertheim – volume: 2 start-page: 320 year: 1981 ident: 10.1016/j.jmmm.2023.171080_b0065 article-title: The Fe-Ti (iron-titanium) system publication-title: Bull. Alloy Phase Diagr. doi: 10.1007/BF02868286 contributor: fullname: Murray – volume: 25 start-page: 1189 year: 1968 ident: 10.1016/j.jmmm.2023.171080_b0075 article-title: Ferro- and antiferromagnetism of the Laves phase compound in Fe-Ti alloy system publication-title: J. Phys. Soc. Japan doi: 10.1143/JPSJ.25.1189 contributor: fullname: Nakamichi – volume: 49 start-page: 2101805 year: 2013 ident: 10.1016/j.jmmm.2023.171080_b0120 article-title: Coercivity and phase evolution in mechanically milled (FeCo)2B-type hard magnetic alloy publication-title: IEEE Trans. Magn. contributor: fullname: Kim – volume: 138 start-page: 55 year: 1986 ident: 10.1016/j.jmmm.2023.171080_b0150 article-title: The 57Fe Mössbauer isomer shift in intermetallic compounds of iron publication-title: Physica B+C doi: 10.1016/0378-4363(86)90492-4 contributor: fullname: Van der Kraan – volume: 49 start-page: 3322 year: 2013 ident: 10.1016/j.jmmm.2023.171080_b0115 article-title: Ferromagnetic tetragonal L10-type MnGa isotropic nanocrystalline microparticles publication-title: IEEE Trans. Magn. doi: 10.1109/TMAG.2013.2245868 contributor: fullname: Cui – volume: 62 start-page: 203 year: 2021 ident: 10.1016/j.jmmm.2023.171080_b0175 article-title: Self-accommodated defect structures modifying the growth of Laves phase publication-title: J. Mater. Sci. Technol. doi: 10.1016/j.jmst.2020.05.042 contributor: fullname: Yang – volume: 158 start-page: 118 year: 2018 ident: 10.1016/j.jmmm.2023.171080_b0020 article-title: Current progress and future challenges in rare-earth-free permanent magnets publication-title: Acta Mater. doi: 10.1016/j.actamat.2018.07.049 contributor: fullname: Cui – volume: 119 start-page: 297 year: 1986 ident: 10.1016/j.jmmm.2023.171080_b0140 article-title: Structural investigations of the Nb1−xSixT2 and Nb1−xAlxT2 (T = Cr, Mn, Fe Co, Ni) systems publication-title: J. Less-Common Met. doi: 10.1016/0022-5088(86)90690-9 contributor: fullname: Blazina – ident: 10.1016/j.jmmm.2023.171080_b0035 doi: 10.3390/cryst10060430 – volume: 96 year: 2017 ident: 10.1016/j.jmmm.2023.171080_b0025 article-title: Magnetocrystalline anisotropy of Laves phase Fe2Ta1−xWx from first principles: Effect of 3d-5d hybridization, Phys publication-title: Rev. B doi: 10.1103/PhysRevB.96.064422 contributor: fullname: Edström – start-page: 1700184 year: 2017 ident: 10.1016/j.jmmm.2023.171080_b0030 article-title: Hard magnetic off-stoichiometric (Fe, Sb)2+xHf1-x intermetallic phase publication-title: Phys. Status Solidi RRL doi: 10.1002/pssr.201700184 contributor: fullname: Goll – volume: 79 start-page: 3730 issue: 7 year: 1996 ident: 10.1016/j.jmmm.2023.171080_b0165 article-title: The study of nonequilibrium Fe–Ti alloys prepared by high-energy mechanical deformation publication-title: J. Appl. Phys. doi: 10.1063/1.361206 contributor: fullname: Macrí – volume: 59 start-page: 86 year: 1986 ident: 10.1016/j.jmmm.2023.171080_b0130 article-title: Determination of intrinsic magnetic material parameters of Nd2Fe14B from magnetic measurements of sintered Nd15Fe77B8 magnets publication-title: J. Magn. Magn. Mater. doi: 10.1016/0304-8853(86)90014-4 contributor: fullname: Durst – volume: 112 start-page: 3 year: 2016 ident: 10.1016/j.jmmm.2023.171080_b0160 article-title: Magnetic anisotropy — How much is enough for a permanent magnet? publication-title: Scr. Mater. doi: 10.1016/j.scriptamat.2015.09.021 contributor: fullname: Skomski – volume: 144 start-page: 41 year: 1988 ident: 10.1016/j.jmmm.2023.171080_b0145 article-title: Phase equilibria in ternary alloys based on iron-group metals and containing refractory metals (Mo, W, Nb, Ta) publication-title: J. Less-Common Met. doi: 10.1016/0022-5088(88)90347-5 contributor: fullname: Asrar – volume: 2093 year: 2019 ident: 10.1016/j.jmmm.2023.171080_b0105 article-title: Enhancement of magnetic anisotropy of Fe5PB2 with W substitution: ab-initio study publication-title: AIP Conf. Proc. doi: 10.1063/1.5097081 contributor: fullname: Thakur – volume: 26 issue: 6 year: 2014 ident: 10.1016/j.jmmm.2023.171080_b0095 article-title: Permanent magnetism of intermetallic compounds between light and heavy transition-metal elements publication-title: J. Phys.: Condens. Matter contributor: fullname: Kumar – start-page: 1700221 year: 2017 ident: 10.1016/j.jmmm.2023.171080_b0040 article-title: Hard magnetic Laves-type (Fe, Si)2Zr phase in the known Fe–Si–Zr ternary system publication-title: Phys. Status Solidi RRL contributor: fullname: Goll – volume: 92 year: 2008 ident: 10.1016/j.jmmm.2023.171080_b0090 article-title: Magnetic properties of Fe-5d (Os, Ir, and Pt) nanowires encapsulated in carbon nanotubes publication-title: Appl. Phys. Lett. contributor: fullname: Wang – volume: 12 start-page: 713 year: 2004 ident: 10.1016/j.jmmm.2023.171080_b0155 article-title: Structure and stability of Laves phases. Part I. Critical assessment of factors controlling Laves phase stability publication-title: Intermetallics doi: 10.1016/j.intermet.2004.02.010 contributor: fullname: Stein – volume: 47 start-page: 4671 year: 2011 ident: 10.1016/j.jmmm.2023.171080_b0005 article-title: Hard magnetic materials: A perspective publication-title: IEEE Trans. Magn. doi: 10.1109/TMAG.2011.2166975 contributor: fullname: Coey – ident: 10.1016/j.jmmm.2023.171080_b0055 doi: 10.1109/TMAG.2023.3280849 – volume: 98 year: 2018 ident: 10.1016/j.jmmm.2023.171080_b0100 article-title: Magnetocrystalline anisotropy of Fe5PB2 and its alloys with Co and 5d elements: A combined first-principles and experimental study publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.98.214431 contributor: fullname: Werwiński |
| SSID | ssj0001486 |
| Score | 2.4705756 |
| Snippet | •Magnetic anisotropy of Fe-rich TiFe2.5 Laves phase is uniaxial, but it is weak.•Nb, Mo, Ta, W increase the anisotropy field only below room temperature.•Zr,... Rare-earth-free compounds exhibiting modest intrinsic hard magnetic properties may still yield viable permanent magnets if their constituent elements are... |
| SourceID | osti crossref elsevier |
| SourceType | Open Access Repository Aggregation Database Publisher |
| StartPage | 171080 |
| SubjectTerms | Laves phase Magnetic anisotropy MATERIALS SCIENCE Rare-earth-free magnets Spin-orbit coupling |
| Title | Semihard magnetic properties of TiFe2.5 iron-rich Laves phase and the effect of 4d- and 5d-element-substitutions for Ti |
| URI | https://dx.doi.org/10.1016/j.jmmm.2023.171080 https://www.osti.gov/servlets/purl/1992242 |
| Volume | 583 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1LaxsxEBaOQ6GX0idN0xYdejNa1rur1fpoEqdpaXOxC7kt2pXUrMEP6oSSf58ZvTY0uLSFXhYjtLKs72NmJH8zIuQDbw0XslWsnFQFbFB0zmQjG6YN-JKmyGVq08XO5-LisjqdFbPBIAhJ-7b_ijS0AdaYOfsXaMdBoQE-A-bwBNTh-Ue4z_Wqw0yq0Up-X2OGIkqwtqieduVlF92ZzhI-wvQ2BkbwavRFYuXZ7RX4s6indDIP7F8oZlu5YtpJzdkOjI1VGFgRHeoUF92eINdPwl_EEacEYbJbiyj_Aegs3NPka9JbxaAI2NxG73HRxbbgdZ0BXXZg2OStq5nwMTlJ7h9oZL00zp-yPci0cdldacGqyhUWDpabuztwHngBdyCxTJarFRYbyPJkLFBL2fu8qESc48A4LmzF0NpVB-QwA5sFJvNw-ml2-Tm6ddg3uj--_UR8BpYTC_76TfuinOEG8LkXwCyekiceFDp1lHlGBnr9nDyyCuB294L8DMShASXaE4duDPXEoZE41BKHWuJQgJcCcagjDvYH4tjWfcShQBwY9CX5djZbnJwzfysHazNRXbOJMcWkkFXGm1JkLeyYU4P71rKqWiMmRpsmMwrL8kFsaspSpFxjtdmxllpx0-SvyHC9WevXhI5lXipRlFg2r5BGSegrRKOVKrMmVfyIjMIq1ltXfKUOqsRljWte45rXbs2PCA8LXfvw0YWFNfDit-8dIyr4DtZNblFgBi-hLht-15t_HPWYPO7J_ZYMr3_c6HfkYKdu3ntm3QEmzJsB |
| link.rule.ids | 230,315,782,786,887,27933,27934 |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Semihard+magnetic+properties+of+TiFe2.5+iron-rich+Laves+phase+and+the+effect+of+4d-+and+5d-element-substitutions+for+Ti&rft.jtitle=Journal+of+magnetism+and+magnetic+materials&rft.au=Gabay%2C+A.M.&rft.au=Han%2C+Chaoya&rft.au=Ni%2C+Chaoying&rft.au=Hadjipanayis%2C+G.C.&rft.date=2023-10-01&rft.pub=Elsevier+B.V&rft.issn=0304-8853&rft.volume=583&rft_id=info:doi/10.1016%2Fj.jmmm.2023.171080&rft.externalDocID=S0304885323007308 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0304-8853&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0304-8853&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0304-8853&client=summon |