Effect of synthesis conditions on the properties of magnetic crosslinked polystyrene microspheres
Abstract In this work, magnetic polymeric microspheres were prepared through the copolymerization of styrene and divinylbenzene in the presence of magnetite synthesized in our laboratory. The effects of magnetite modification with oleic acid, stirring speed, initiator concentration and stabilizer co...
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| Published in: | Polímeros, ciência e tecnologia Vol. 34; no. 3 |
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Associação Brasileira de Polímeros
01-01-2024
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| Abstract | Abstract In this work, magnetic polymeric microspheres were prepared through the copolymerization of styrene and divinylbenzene in the presence of magnetite synthesized in our laboratory. The effects of magnetite modification with oleic acid, stirring speed, initiator concentration and stabilizer concentration on the particles’ properties were studied. The magnetic microspheres were characterized according to morphology, thermal stability, particle size and distribution, and magnetic properties. The microspheres had spherical shape, micrometric size and superparamagnetic properties. Particle size was mainly affected by stirring speed, while particle size dispersion was strongly affected by initiator and stabilizer concentrations. The saturation magnetization of the microspheres was similar to the values reported in the literature for microspheres with the same content of magnetic material. The modification with oleic acid promoted the incorporation of magnetic material. |
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| AbstractList | Abstract In this work, magnetic polymeric microspheres were prepared through the copolymerization of styrene and divinylbenzene in the presence of magnetite synthesized in our laboratory. The effects of magnetite modification with oleic acid, stirring speed, initiator concentration and stabilizer concentration on the particles’ properties were studied. The magnetic microspheres were characterized according to morphology, thermal stability, particle size and distribution, and magnetic properties. The microspheres had spherical shape, micrometric size and superparamagnetic properties. Particle size was mainly affected by stirring speed, while particle size dispersion was strongly affected by initiator and stabilizer concentrations. The saturation magnetization of the microspheres was similar to the values reported in the literature for microspheres with the same content of magnetic material. The modification with oleic acid promoted the incorporation of magnetic material. |
| Author | Bouças, Thiago Alexandre de Oliveira Silva, Manoel Ribeiro da Hui, Wang Shu Costa, Marcos Antonio da Silva Castanharo, Jacira Aparecida Cunha, Henrique Almeida |
| Author_xml | – sequence: 1 givenname: Thiago Alexandre de Oliveira orcidid: 0009-0008-3170-3944 surname: Bouças fullname: Bouças, Thiago Alexandre de Oliveira organization: Universidade do Estado do Rio de Janeiro, Brasil – sequence: 2 givenname: Marcos Antonio da Silva orcidid: 0000-0002-1435-8818 surname: Costa fullname: Costa, Marcos Antonio da Silva organization: Universidade do Estado do Rio de Janeiro, Brasil – sequence: 3 givenname: Henrique Almeida orcidid: 0000-0003-4129-364X surname: Cunha fullname: Cunha, Henrique Almeida organization: Universidade do Estado do Rio de Janeiro, Brasil – sequence: 4 givenname: Manoel Ribeiro da orcidid: 0000-0002-0559-9011 surname: Silva fullname: Silva, Manoel Ribeiro da organization: Universidade Federal de Itajubá, Brasil – sequence: 5 givenname: Wang Shu orcidid: 0000-0001-6608-5770 surname: Hui fullname: Hui, Wang Shu organization: Universidade de São Paulo, Brasil – sequence: 6 givenname: Jacira Aparecida orcidid: 0000-0001-6553-1417 surname: Castanharo fullname: Castanharo, Jacira Aparecida organization: Universidade do Estado do Rio de Janeiro, Brasil |
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| References | Formiga W. J. F. (ref4) 2013; 23 Chae H. S. (ref10) 2018; 219 Philippova O. (ref1) 2011; 47 Queiroz C. N. (ref7) 2023; 17 Lee Y. (ref26) 2003; 89 Santa Maria L. C. (ref8) 2005; 46 Martin C. (ref2) 2004; 43 Yu P. (ref11) 2013; 31 Castanharo J. A. (ref3) 2018; 28 Formiga W. J. F. (ref5) 2023; 17 Chaudhary V. (ref31) 2019; 26 Massart R. (ref19) 1981; 17 Brooks B. (ref27) 2010; 33 Souza F. S. (ref6) 2013; 23 Machado F. (ref17) 2007; 17 Zerfa M. (ref29) 1996; 51 Mendes M. S. L. (ref12) 2022; 5 Conceição B. M. (ref15) 2011; 21 Qin Z. (ref13) 2019; 38 Yuan Q. E. (ref18) 2007; 5 Ramos G. S. M. (ref16) 2020; 138 Atanase L. I. (ref28) 2010; 355 Guo Z. (ref20) 2003; 32 Chatzi E. G. (ref23) 1991; 30 Liu X.-Y. (ref30) 2003; 90 Koneracká M. (ref21) 1999; 201 Pastukhov A. V. (ref9) 2021; 160 Santa Maria L. C. (ref14) 2004; 58 Alroaithi M. (ref22) 2018; 57 Brown D. E. (ref24) 1972; 27 Castanharo J. A. (ref25) 2015; 25 |
| References_xml | – volume: 23 start-page: 262 issue: 2 year: 2013 ident: ref4 article-title: Microesferas poliméricas magnéticas à base de estireno e divinilbenzeno com morfologia casca e núcleo publication-title: Polímeros: Ciência e Tecnologia doi: 10.4322/polimeros.2013.075 contributor: fullname: Formiga W. J. F. – volume: 51 start-page: 3591 issue: 14 year: 1996 ident: ref29 article-title: Vinyl chloride dispersion with relation to suspension polymerization publication-title: Chemical Engineering Science doi: 10.1016/0009-2509(96)00002-4 contributor: fullname: Zerfa M. – volume: 17 issue: 4 year: 2023 ident: ref5 article-title: Influence of benzoyl peroxide and divinylbenzene concentrations on the properties of poly(glycidyl methacrylate-co-divinylbenzene) magnetic microspheres publication-title: Macromolecular Reaction Engineering contributor: fullname: Formiga W. J. F. – volume: 31 start-page: 641 issue: 7 year: 2013 ident: ref11 article-title: Performance of poly(styrene–divinylbenzene) magnetic porous microspheres prepared by suspension polymerization for the adsorption of 2, 4-dichlorophenol and 2, 6-dichlorophenol from aqueous solutions publication-title: Adsorption Science and Technology doi: 10.1260/0263-6174.31.7.641 contributor: fullname: Yu P. – volume: 58 start-page: 3001 issue: 24 year: 2004 ident: ref14 article-title: Characterization of magnetic microspheres based on network styrene and divinylbenzene copolymers publication-title: Materials Letters doi: 10.1016/j.matlet.2004.05.028 contributor: fullname: Santa Maria L. C. – volume: 17 start-page: 1247 issue: 2 year: 1981 ident: ref19 article-title: Preparation of aqueous magnetic liquids in alkaline and acidic media publication-title: IEEE Transactions on Magnetics doi: 10.1109/TMAG.1981.1061188 contributor: fullname: Massart R. – volume: 17 start-page: 166 issue: 2 year: 2007 ident: ref17 article-title: Uma revisão sobre os processos de polimerização em suspensão publication-title: Polímeros: Ciência e Tecnologia doi: 10.1590/S0104-14282007000200016 contributor: fullname: Machado F. – volume: 32 start-page: 776 issue: 7 year: 2003 ident: ref20 article-title: Preparation and characterization of immobilized lipase on magnetic hydrophobic microspheres publication-title: Enzyme and Microbial Technology doi: 10.1016/S0141-0229(03)00051-6 contributor: fullname: Guo Z. – volume: 355 start-page: 29 issue: 1-3 year: 2010 ident: ref28 article-title: Poly(vinyl alcohol-co-vinyl acetate) complex formation with anionic surfactants particle size of nanogels and their disaggregation with sodium dodecyl sulfate publication-title: Colloids and Surfaces. A, Physicochemical and Engineering Aspects doi: 10.1016/j.colsurfa.2009.11.024 contributor: fullname: Atanase L. I. – volume: 25 start-page: 192 issue: 2 year: 2015 ident: ref25 article-title: Microesferas magnéticas à base de poli(metacrilato de metila-co-divinilbenzeno) obtidas por polimerização em suspensão publication-title: Polímeros: Ciência e Tecnologia doi: 10.1590/0104-1428.1666 contributor: fullname: Castanharo J. A. – volume: 23 start-page: 82 issue: 1 year: 2013 ident: ref6 article-title: Síntese e caracterização de copolímeros reticulados à base de estireno, divinilbenzeno e metacrilato de metila com propriedades magnéticas publication-title: Polímeros: Ciência e Tecnologia doi: 10.1590/S0104-14282013005000004 contributor: fullname: Souza F. S. – volume: 89 start-page: 2058 issue: 8 year: 2003 ident: ref26 article-title: Preparation of magnetic ion-exchange resins by the suspension polymerization of styrene with magnetite publication-title: Journal of Applied Polymer Science doi: 10.1002/app.12365 contributor: fullname: Lee Y. – volume: 17 issue: 4 year: 2023 ident: ref7 article-title: Influence of synthesis parameters on the magnetic, thermal, and morphological properties of poly(glycidyl methacrylate-co-divinylbenzene)/magnetite publication-title: Macromolecular Reaction Engineering doi: 10.1002/mren.202200073 contributor: fullname: Queiroz C. N. – volume: 160 start-page: 104823 year: 2021 ident: ref9 article-title: Magnetic sorbents based on hypercrosslinked copolymers of styrene and divinylbenzene with immobilized iron oxides publication-title: Reactive & Functional Polymers doi: 10.1016/j.reactfunctpolym.2021.104823 contributor: fullname: Pastukhov A. V. – volume: 5 start-page: 3 issue: 1 year: 2022 ident: ref12 article-title: Advances in magnetic polymeric styrene-divinylbenzene nanocomposites between magnetite and maghemite nanoparticles: an overview publication-title: Current Applied Polymer Science doi: 10.2174/2452271605666220304091807 contributor: fullname: Mendes M. S. L. – volume: 26 start-page: 102 issue: 5 year: 2019 ident: ref31 article-title: Suspension polymerization technique: parameters affecting polymer properties and application in oxidation reactions publication-title: Journal of Polymer Research doi: 10.1007/s10965-019-1767-8 contributor: fullname: Chaudhary V. – volume: 5 start-page: 26 issue: 1-2 year: 2007 ident: ref18 article-title: Large scale manufacture of magnetic polymer particles using membranes and microfluidic devices publication-title: China Particuology doi: 10.1016/j.cpart.2007.02.001 contributor: fullname: Yuan Q. E. – volume: 30 start-page: 1307 issue: 6 year: 1991 ident: ref23 article-title: Monitoring of drop size distributions in agitated bessels. 2. Effect of stabilizer concentration publication-title: Industrial & Engineering Chemistry Research doi: 10.1021/ie00054a035 contributor: fullname: Chatzi E. G. – volume: 33 start-page: 1737 issue: 11 year: 2010 ident: ref27 article-title: Suspension polymerization processes publication-title: Chemical Engineering & Technology doi: 10.1002/ceat.201000210 contributor: fullname: Brooks B. – volume: 138 start-page: 50318 issue: 18 year: 2020 ident: ref16 article-title: Experimental design to evaluate the efficiency of maghemite nanoparticles incorporation in styrene-divinylbenzene copolymers publication-title: Journal of Applied Polymer Science doi: 10.1002/app.50318 contributor: fullname: Ramos G. S. M. – volume: 57 start-page: 11883 issue: 35 year: 2018 ident: ref22 article-title: Suppressing coalescence and improving uniformity of polymer beads in suspension polymerization using a two-stage stirring protocol publication-title: Industrial & Engineering Chemistry Research doi: 10.1021/acs.iecr.8b01599 contributor: fullname: Alroaithi M. – volume: 27 start-page: 557 issue: 3 year: 1972 ident: ref24 article-title: Drop size distributions of stirred non-coalescing liquid-liquid systems publication-title: Chemical Engineering Science doi: 10.1016/0009-2509(72)87013-1 contributor: fullname: Brown D. E. – volume: 46 start-page: 11288 issue: 25 year: 2005 ident: ref8 article-title: Preparation and characterization of manganese, nickel and cobalt ferrites submicron particles in sulfonated crosslinked networks publication-title: Polymer doi: 10.1016/j.polymer.2005.09.055 contributor: fullname: Santa Maria L. C. – volume: 38 start-page: 764 issue: 8 year: 2019 ident: ref13 article-title: A facile synthesis of magnetite single-crystal particles by employing graphene oxide sheets as template for promising application in magnetic fluid publication-title: Rare Metals doi: 10.1007/s12598-018-1197-5 contributor: fullname: Qin Z. – volume: 21 start-page: 409 issue: 5 year: 2011 ident: ref15 article-title: A study of the initiator concentration’s effect on styrene- divinylbenzene polymerization with iron particles publication-title: Polímeros: Ciência e Tecnologia doi: 10.1590/S0104-14282011005000070 contributor: fullname: Conceição B. M. – volume: 43 start-page: 475 issue: 2 year: 2004 ident: ref2 article-title: Synthesis of a novel magnetic resin and the study of equilibrium in cation exchange with amino acids publication-title: Industrial & Engineering Chemistry Research doi: 10.1021/ie0302239 contributor: fullname: Martin C. – volume: 47 start-page: 542 issue: 4 year: 2011 ident: ref1 article-title: Magnetic polymer beads: recent trends and developments in synthetic design and applications publication-title: European Polymer Journal doi: 10.1016/j.eurpolymj.2010.11.006 contributor: fullname: Philippova O. – volume: 28 start-page: 460 issue: 5 year: 2018 ident: ref3 article-title: Core-shell magnetic particles obtained by seeded suspension polymerization of acrylic monomers publication-title: Polímeros: Ciência e Tecnologia doi: 10.1590/0104-1428.10517 contributor: fullname: Castanharo J. A. – volume: 219 issue: 5 year: 2018 ident: ref10 article-title: Core/shell polystyrene/magnetite hybrid nanoparticles fabricated by pickering emulsion polymerization and their magnetorheological response publication-title: Macromolecular Chemistry and Physics contributor: fullname: Chae H. S. – volume: 201 start-page: 427 issue: 1-3 year: 1999 ident: ref21 article-title: Immobilization of proteins and enzymes to fine magnetic particles publication-title: Journal of Magnetism and Magnetic Materials doi: 10.1016/S0304-8853(99)00005-0 contributor: fullname: Koneracká M. – volume: 90 start-page: 1879 issue: 7 year: 2003 ident: ref30 article-title: Synthesis of novel magnetic polymer microspheres with amphiphilic structure publication-title: Journal of Applied Polymer Science doi: 10.1002/app.12860 contributor: fullname: Liu X.-Y. |
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| Title | Effect of synthesis conditions on the properties of magnetic crosslinked polystyrene microspheres |
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