Reaction of 2-acetyl-5-methyl-2H-1,2,3-diazaphosphole with butane-2,3-diol

Reaction of 2-acetyl-5-methyl-2H-1,2,3-diazaphosphole with butane-2,3-diol

The reaction of 2-acetyl-5-methyl-2 H -1,2,3-diazaphosphole with ( rac )-butane-2,3-diol at temperatures below 0 C leads to the formation of a hydrospirophosphorane containing both a diazaphospholene and a dioxaphospholane ring system and a β-hydroxyalkoxy-1,2,3-diazaphospholene. On heating, these p...

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Bibliographic Details
Published in:Mendeleev communications Vol. 14; no. 5; pp. 212 - 214
Main Authors: Khusainova, Narkis G, Mostovaya, Olga A, Azancheev, Nail M, Litvinov, Igor A, Krivolapov, Dmitry B, Cherkasov, Rafael A
Format: Journal Article
Language:English
Published: 2004
Online Access:Get full text
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Summary:The reaction of 2-acetyl-5-methyl-2 H -1,2,3-diazaphosphole with ( rac )-butane-2,3-diol at temperatures below 0 C leads to the formation of a hydrospirophosphorane containing both a diazaphospholene and a dioxaphospholane ring system and a β-hydroxyalkoxy-1,2,3-diazaphospholene. On heating, these products form a hydrospirotetraoxaphosphorane, its tautomeric monocyclic β-hydroxyalkylphosphite and N -acetyl- N' -isopropylidene-hydrazine.
ISSN:0959-9436
1364-557X
DOI:10.1070/MC2004v014n05ABEH001926