[C 6H 21N 4][Sb 9S 14O]: Solvothermal synthesis, crystal structure and characterization of the first non-centrosymmetric open Sb–S–O framework containing the new [SbS 2O] building unit

[C 6H 21N 4][Sb 9S 14O] represents the first known oxo-thioantimonate with an organic ion acting as structure director. The compound crystallizes in the non-centrosymmetric space group Cmc2 1 with a = 29.679 ( 2 ) , b = 9.9798 ( 6 ) , c = 11.7155 ( 7 ) Å , V = 3470.1 ( 4 ) Å 3 , Z = 4 . The structur...

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Bibliographic Details
Published in:	Journal of solid state chemistry Vol. 179; no. 10; pp. 3082 - 3086
Main Authors:	Kiebach, Ragnar, Näther, Christian, Peter Sebastian, C., Mosel, Bernd D., Pöttgen, Rainer, Bensch, Wolfgang
Format:	Journal Article
Language:	English
Published:	San Diego, CA Elsevier Inc 2006 Elsevier
Subjects:	ANTIMONATES ANTIMONY OXIDES ANTIMONY SULFIDES BOND LENGTHS Condensed matter: electronic structure, electrical, magnetic, and optical properties Cross-disciplinary physics: materials science; rheology Crystal structure Exact sciences and technology Growth from solutions HYDROTHERMAL SYNTHESIS Magnetic resonances and relaxations in condensed matter, mössbauer effect MATERIALS SCIENCE Methods of crystal growth; physics of crystal growth MOESSBAUER EFFECT Mössbauer effect; other γ-ray spectroscopy Mössbauer spectroscopy ORTHORHOMBIC LATTICES Oxo-thioantimonates Physics SPACE GROUPS SPECTRA Hydrothermal synthesis Oxo-thioantimonates Mössbauer spectroscopy Crystal structure Non centrosymmetric crystals Moessbauer effect Inorganic compounds Semiconductor materials Hybrid material Solvothermal synthesis Thermogravimetry Line widths Differential thermal analysis Experimental study Heat treatments Antimony sulfides Open framework Aqueous solutions Orthorhombic lattices Crystal growth from solutions Ultraviolet visible spectrum Optical materials Tetradentate ligand Organic compounds
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