Thermodynamic behaviour of the binary systems dimethyl carbonate + n-octane or n-nonane
Isobaric molar heat capacities, densities and speeds of sound were determined for the dimethyl carbonate + n-octane and n-nonane systems at atmospheric pressure covering the whole composition interval and in the temperature range (288.15–308.15 K). From these data, derived properties and excess magn...
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| Published in: | Thermochimica acta Vol. 433; no. 1; pp. 128 - 133 |
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| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
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| Abstract | Isobaric molar heat capacities, densities and speeds of sound were determined for the dimethyl carbonate
+
n-octane and
n-nonane systems at atmospheric pressure covering the whole composition interval and in the temperature range (288.15–308.15
K). From these data, derived properties and excess magnitudes were obtained. A strongly temperature-dependent W-shaped curves against composition were observed for excess isobaric molar heat capacities in both system, showing the other excess magnitudes regular tendencies. From these results, a comparative analysis of the existing differences between the thermodynamic behaviour of the two systems was carried out. |
|---|---|
| AbstractList | Isobaric molar heat capacities, densities and speeds of sound were determined for the dimethyl carbonate
+
n-octane and
n-nonane systems at atmospheric pressure covering the whole composition interval and in the temperature range (288.15–308.15
K). From these data, derived properties and excess magnitudes were obtained. A strongly temperature-dependent W-shaped curves against composition were observed for excess isobaric molar heat capacities in both system, showing the other excess magnitudes regular tendencies. From these results, a comparative analysis of the existing differences between the thermodynamic behaviour of the two systems was carried out. Isobaric molar heat capacities, densities and speeds of sound were determined for the dimethyl carbonate+n--octane and n--nonane systems at atmospheric pressure covering the whole composition interval and in the temperature range (288*15--308*15K). From these data, derived properties and excess magnitudes were obtained. A strongly temperature--dependent W--shaped curves against composition were observed for excess isobaric molar heat capacities in both system, showing the other excess magnitudes regular tendencies. From these results, a comparative analysis of the existing differences between the thermodynamic behaviour of the two systems was carried out. |
| Author | Carballo, E. Romaní, L. Troncoso, J. Tovar, C.A. Pardo, J.M. |
| Author_xml | – sequence: 1 givenname: J.M. surname: Pardo fullname: Pardo, J.M. – sequence: 2 givenname: C.A. surname: Tovar fullname: Tovar, C.A. – sequence: 3 givenname: J. surname: Troncoso fullname: Troncoso, J. – sequence: 4 givenname: E. surname: Carballo fullname: Carballo, E. – sequence: 5 givenname: L. surname: Romaní fullname: Romaní, L. email: romani@uvigo.es |
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| Cites_doi | 10.1139/v03-090 10.1021/je00008a037 10.1139/v02-030 10.1021/je00002a009 10.1016/S0378-3812(00)00491-X 10.1006/jcht.1999.0644 10.1021/je0301794 10.1007/BF02575132 10.1007/BF00648980 10.1121/1.406819 10.1021/je000197a 10.1016/0370-1573(83)90106-0 10.1016/0378-3812(87)80015-8 10.1021/je990325z 10.1006/jcht.1999.0488 10.1039/a704539e 10.1016/S0021-9614(03)00096-X 10.1016/0021-9614(79)90136-8 10.1016/0378-3812(93)85042-K 10.1021/je0342320 10.1121/1.415224 10.1006/jcht.2002.0981 10.1016/S0378-3812(97)00118-0 10.1016/S0378-3812(01)00809-3 10.1021/je0101193 10.1007/BF01131047 |
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| Keywords | Heat capacity Excess magnitudes Dialkyl carbonate n-Alkane Octane Nonane Organic carbonate Hydrocarbon Molar volume Binary system Excess parameter Thermal properties Alkane Thermodynamic properties |
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| Snippet | Isobaric molar heat capacities, densities and speeds of sound were determined for the dimethyl carbonate
+
n-octane and
n-nonane systems at atmospheric... Isobaric molar heat capacities, densities and speeds of sound were determined for the dimethyl carbonate+n--octane and n--nonane systems at atmospheric... |
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| SubjectTerms | Chemical thermodynamics Chemistry Dialkyl carbonate Exact sciences and technology Excess magnitudes General and physical chemistry Heat capacity Mixtures n-Alkane Thermodynamic properties |
| Title | Thermodynamic behaviour of the binary systems dimethyl carbonate + n-octane or n-nonane |
| URI | https://dx.doi.org/10.1016/j.tca.2004.11.022 https://search.proquest.com/docview/28636346 |
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