Substance Detection and Identification Using Frequency Doubling of the THz Broadband Pulse

• Published in: Chemosensors Vol. 10; no. 7; p. 275
• Main Authors: Trofimov, Vyacheslav A., Varentsova, Svetlana A., Yang, Yongqiang, Cai, Zihao
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01-07-2022
• Subjects: Absorption; Broadband; broadband THz pulse; doubled absorption frequency; frequency doubling; Identification; Methods; pulsed THz time-domain spectroscopy; Quantitative analysis; SDA-method; Second harmonic generation; substance with inhomogeneous surface
• ISSN: 2227-9040; 2227-9040
• DOI: 10.3390/chemosensors10070275

We propose and discuss an effective tool for substance detection and identification using a broadband THz pulse that is based on frequency conversion near the substance absorption frequencies. With this aim, we analyze the evolution of spectral intensities at the doubled absorption frequencies in order to prove their similarity to those at which the absorption of THz pulse energy occurs. This analysis is provided for both artificial THz signals and the real signals reflected from the substances under consideration. We demonstrate the feasibility of the proposed approach in the detection and identification of substances with an inhomogeneous surface, which is the most difficult case for practice, by using the method of spectral dynamic analysis and integral correlation criteria.