Identification of Photolysis Products of Aqueous Sodium Thiosulfate Solutions
The results of identification of photolysis products of air-saturated aqueous solutions of Na 2 S 2 O 3 irradiated with a KrCl excimer lamp are presented. Using spectrophotometry, HPLC, IR spectroscopy, and mass spectrometry, it has been shown that intermediate photolysis products are colloidal sulf...
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| Published in: | High energy chemistry Vol. 57; no. Suppl 3; pp. S397 - S401 |
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| Main Authors: | , , , , , |
| Format: | Journal Article |
| Language: | English |
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| Abstract | The results of identification of photolysis products of air-saturated aqueous solutions of Na
2
S
2
O
3
irradiated with a KrCl excimer lamp are presented. Using spectrophotometry, HPLC, IR spectroscopy, and mass spectrometry, it has been shown that intermediate photolysis products are colloidal sulfur and tetrathionate and pentathionate ions, which photodegrade to form sulfur, sulfate ions, and hydrogen sulfide during further UV irradiation involving atmospheric oxygen and solvent molecules. Reactions for the formation of detected photolysis products have been proposed. |
|---|---|
| AbstractList | The results of identification of photolysis products of air-saturated aqueous solutions of Na
2
S
2
O
3
irradiated with a KrCl excimer lamp are presented. Using spectrophotometry, HPLC, IR spectroscopy, and mass spectrometry, it has been shown that intermediate photolysis products are colloidal sulfur and tetrathionate and pentathionate ions, which photodegrade to form sulfur, sulfate ions, and hydrogen sulfide during further UV irradiation involving atmospheric oxygen and solvent molecules. Reactions for the formation of detected photolysis products have been proposed. The results of identification of photolysis products of air-saturated aqueous solutions of Na2S2O3 irradiated with a KrCl excimer lamp are presented. Using spectrophotometry, HPLC, IR spectroscopy, and mass spectrometry, it has been shown that intermediate photolysis products are colloidal sulfur and tetrathionate and pentathionate ions, which photodegrade to form sulfur, sulfate ions, and hydrogen sulfide during further UV irradiation involving atmospheric oxygen and solvent molecules. Reactions for the formation of detected photolysis products have been proposed. |
| Author | Egorov, N. B. Isaeva, E. A. Zherin, I. I. Kulikova, A. V. Dmitrieva, A. A. Voroshilov, F. A. |
| Author_xml | – sequence: 1 givenname: N. B. surname: Egorov fullname: Egorov, N. B. email: egorov@tpu.ru organization: Tomsk Polytechnic University – sequence: 2 givenname: E. A. surname: Isaeva fullname: Isaeva, E. A. organization: Tomsk Polytechnic University – sequence: 3 givenname: A. A. surname: Dmitrieva fullname: Dmitrieva, A. A. organization: Tomsk Polytechnic University – sequence: 4 givenname: A. V. surname: Kulikova fullname: Kulikova, A. V. organization: Tomsk Polytechnic University – sequence: 5 givenname: F. A. surname: Voroshilov fullname: Voroshilov, F. A. organization: Tomsk Polytechnic University – sequence: 6 givenname: I. I. surname: Zherin fullname: Zherin, I. I. organization: Tomsk Polytechnic University |
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| Cites_doi | 10.1016/S0022-0248(01)02280-1 10.1016/S0022-0248(98)00985-3 10.1021/cm302482d 10.1134/S0018143920010051 10.1007/978-3-319-56387-9 10.1016/j.jphotochem.2022.113818 10.1002/ceat.201800705 10.1016/j.tsf.2004.06.137 10.1016/j.hydromet.2019.105212 10.1002/chem.202004952 10.1143/JJAP.49.062302 10.1016/j.mssp.2014.04.024 10.1016/S0021-9673(00)00221-1 10.3390/met9111178 10.1007/s10311-018-0716-9 10.1063/1.3160117 10.1016/j.jphotochem.2011.04.018 10.1021/j100786a035 10.4028/www.scientific.net/SSP.222.187 10.1134/S0018143922030043 10.1021/acs.jpca.3c02082 10.1039/C6RA08447H 10.1021/acs.chemmater.7b04387 10.1016/0076-6879(94)43037-3 |
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| Copyright | Pleiades Publishing, Ltd. 2023. ISSN 0018-1439, High Energy Chemistry, 2023, Vol. 57, Suppl. 3, pp. S397–S401. © Pleiades Publishing, Ltd., 2023. |
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| Keywords | sodium thiosulfate Raffo sol photolysis products hydrogen sulfide stationary photolysis excimer lamps polythionate ions |
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| Snippet | The results of identification of photolysis products of air-saturated aqueous solutions of Na
2
S
2
O
3
irradiated with a KrCl excimer lamp are presented.... The results of identification of photolysis products of air-saturated aqueous solutions of Na2S2O3 irradiated with a KrCl excimer lamp are presented. Using... |
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| SubjectTerms | Aqueous solutions Chemistry Chemistry and Materials Science Excimers Hydrogen sulfide Infrared spectroscopy Irradiation Mass spectrometry Photolysis Physical Chemistry Sodium thiosulfate Spectrophotometry Sulfur Ultraviolet radiation |
| Title | Identification of Photolysis Products of Aqueous Sodium Thiosulfate Solutions |
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