Effects of alkaline-earth fluorides and OH− on spectroscopic properties of Yb3+ doped TeO2–ZnO–B2O3 based glasses
New kinds of Yb2O3-doped boro-tellurite (TeO2–ZnO–B2O3) based glasses were prepared by introducing alkaline-earth fluorides (MgF2, CaF2, SrF2, and BaF2). Their structural and spectroscopic properties were investigated by Raman and absorption spectra measurements. Dehydration ability of alkaline-eart...
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| Published in: | Journal of luminescence Vol. 140; pp. 26 - 29 |
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| Abstract | New kinds of Yb2O3-doped boro-tellurite (TeO2–ZnO–B2O3) based glasses were prepared by introducing alkaline-earth fluorides (MgF2, CaF2, SrF2, and BaF2). Their structural and spectroscopic properties were investigated by Raman and absorption spectra measurements. Dehydration ability of alkaline-earth fluorides was studied. The OH can have an obvious effect on fluorescence lifetime of Yb3+, when OH concentration is higher than NOH=4.66×1019cm−3. For TeO2–ZnO–B2O3–BaF2 glass system, the peak values of integrated absorption and emission cross-sections achieve 7.44×104pm3 and 1.416pm2, respectively. It indicates that the Yb3+-doped boro-tellurite glasses containing alkaline-earth fluorides are potential materials for waveguide laser, and optical amplifier.
► Structure of boro-tellurite glasses was studied by Raman spectra. ► Different alkaline-earth fluorides were introduced into tellurite glasses. ► Dehydration ability of fluorides was evaluated with FTIR spectra. ► The relationship between Yb3+ lifetime and OH-concentration was studied. |
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| AbstractList | New kinds of Yb2O3-doped boro-tellurite (TeO2–ZnO–B2O3) based glasses were prepared by introducing alkaline-earth fluorides (MgF2, CaF2, SrF2, and BaF2). Their structural and spectroscopic properties were investigated by Raman and absorption spectra measurements. Dehydration ability of alkaline-earth fluorides was studied. The OH can have an obvious effect on fluorescence lifetime of Yb3+, when OH concentration is higher than NOH=4.66×1019cm−3. For TeO2–ZnO–B2O3–BaF2 glass system, the peak values of integrated absorption and emission cross-sections achieve 7.44×104pm3 and 1.416pm2, respectively. It indicates that the Yb3+-doped boro-tellurite glasses containing alkaline-earth fluorides are potential materials for waveguide laser, and optical amplifier.
► Structure of boro-tellurite glasses was studied by Raman spectra. ► Different alkaline-earth fluorides were introduced into tellurite glasses. ► Dehydration ability of fluorides was evaluated with FTIR spectra. ► The relationship between Yb3+ lifetime and OH-concentration was studied. |
| Author | Zheng, Ruilin Wei, Wei Wang, Pengfei Peng, Bo Xu, Shennuo |
| Author_xml | – sequence: 1 givenname: Shennuo surname: Xu fullname: Xu, Shennuo organization: State Key Laboratory of Transient Optics and Photonics, Xi'an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi'an 710119, PR China – sequence: 2 givenname: Pengfei surname: Wang fullname: Wang, Pengfei organization: State Key Laboratory of Transient Optics and Photonics, Xi'an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi'an 710119, PR China – sequence: 3 givenname: Ruilin surname: Zheng fullname: Zheng, Ruilin organization: Key Laboratory for Organic Electronics & Information Displays, Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, Nanjing 210046, PR China – sequence: 4 givenname: Wei surname: Wei fullname: Wei, Wei email: weiwei@njupt.edu.cn organization: State Key Laboratory of Transient Optics and Photonics, Xi'an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi'an 710119, PR China – sequence: 5 givenname: Bo surname: Peng fullname: Peng, Bo email: bpeng@opt.ac.cn organization: State Key Laboratory of Transient Optics and Photonics, Xi'an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi'an 710119, PR China |
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| Keywords | Raman spectra Emission cross-section Boro-tellurite glass Alkaline-earth fluorides Boron oxide Doping Glass Fluorescence Zinc Oxides Dehydration Tellurites Tellurite glass Strontium fluoride Zinc oxide Absorption spectra Calcium fluoride Transition element compounds Doped materials Binary compounds Lifetime Ytterbium oxides Ytterbium additions II-VI semiconductors Tellurium oxide Magnesium fluoride Magnesium Fluorides |
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| Snippet | New kinds of Yb2O3-doped boro-tellurite (TeO2–ZnO–B2O3) based glasses were prepared by introducing alkaline-earth fluorides (MgF2, CaF2, SrF2, and BaF2). Their... |
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| SubjectTerms | Alkaline-earth fluorides Boro-tellurite glass Condensed matter: electronic structure, electrical, magnetic, and optical properties Emission cross-section Exact sciences and technology Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of bulk materials and thin films Photoluminescence Physics Raman spectra |
| Title | Effects of alkaline-earth fluorides and OH− on spectroscopic properties of Yb3+ doped TeO2–ZnO–B2O3 based glasses |
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