Construction of heterointerfaces and honeycomb-like structure for ultrabroad microwave absorption
[Display omitted] Heterointerface design is an effective strategy to improve the effective absorption bandwidth in electromagnetic wave EMW absorbing materials. In this paper, honeycomb-like Fe-doped tremella carbide composites (FCT) with a large number of heterogeneous interfaces were obtained by i...
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Published in: | Journal of colloid and interface science Vol. 627; pp. 102 - 112 |
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01-12-2022
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Abstract | [Display omitted]
Heterointerface design is an effective strategy to improve the effective absorption bandwidth in electromagnetic wave EMW absorbing materials. In this paper, honeycomb-like Fe-doped tremella carbide composites (FCT) with a large number of heterogeneous interfaces were obtained by in-situ construction of multiphase composite particles (Fe3C, Fe3O4, and a-Fe) during the carbonization process. The effects of Fe doping on the phase, structure, morphology, and absorption properties of FCT were investigated. The results show that the porous structure and the heterogeneous interface can significantly improve the electromagnetic wave absorption performance of FCT. Iron doping introduces a heterogeneous multiphase structure into FCT, which increases the interfacial loss and magnetic loss of the material, thereby improving the overall impedance matching of the material. FCT-4 composite exhibited excellent microwave attenuation capability with a reflection loss of −34.6 dB. Simultaneously, the widest effective absorption bandwidth is up to 8.84 GHz (9.16–18 GHz) with a matching thickness of 2.8 mm, which covers almost the entire X (8–12 GHz) and Ku (12–18 GHz) bands. Thus, this paper provides an effective strategy for the preparation of excellent electromagnetic wave absorbing materials by in situ construction of heterointerfaces. |
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AbstractList | [Display omitted]
Heterointerface design is an effective strategy to improve the effective absorption bandwidth in electromagnetic wave EMW absorbing materials. In this paper, honeycomb-like Fe-doped tremella carbide composites (FCT) with a large number of heterogeneous interfaces were obtained by in-situ construction of multiphase composite particles (Fe3C, Fe3O4, and a-Fe) during the carbonization process. The effects of Fe doping on the phase, structure, morphology, and absorption properties of FCT were investigated. The results show that the porous structure and the heterogeneous interface can significantly improve the electromagnetic wave absorption performance of FCT. Iron doping introduces a heterogeneous multiphase structure into FCT, which increases the interfacial loss and magnetic loss of the material, thereby improving the overall impedance matching of the material. FCT-4 composite exhibited excellent microwave attenuation capability with a reflection loss of −34.6 dB. Simultaneously, the widest effective absorption bandwidth is up to 8.84 GHz (9.16–18 GHz) with a matching thickness of 2.8 mm, which covers almost the entire X (8–12 GHz) and Ku (12–18 GHz) bands. Thus, this paper provides an effective strategy for the preparation of excellent electromagnetic wave absorbing materials by in situ construction of heterointerfaces. |
Author | Wang, Yiqun Ren, Lianggui Wu, Guanglei He, Yongchao Deng, Shuanglin He, Qinchuan Wu, Dan |
Author_xml | – sequence: 1 givenname: Yongchao surname: He fullname: He, Yongchao organization: College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, Sichuan 610059, China – sequence: 2 givenname: Yiqun surname: Wang fullname: Wang, Yiqun email: wangyiqun17@cdut.edu.cn organization: College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, Sichuan 610059, China – sequence: 3 givenname: Lianggui surname: Ren fullname: Ren, Lianggui organization: College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, Sichuan 610059, China – sequence: 4 givenname: Qinchuan surname: He fullname: He, Qinchuan organization: College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, Sichuan 610059, China – sequence: 5 givenname: Dan surname: Wu fullname: Wu, Dan organization: College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, Sichuan 610059, China – sequence: 6 givenname: Shuanglin surname: Deng fullname: Deng, Shuanglin organization: College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, Sichuan 610059, China – sequence: 7 givenname: Guanglei surname: Wu fullname: Wu, Guanglei email: wuguanglei@qdu.edu.cn, wuguanglei@mail.xjtu.edu.cn organization: Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, China |
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