Synthesis, characterization, and photoluminescence investigations of Al/Co-doped ZnO nanopowder

•Co/Al-doped ZnO nanoparticles were synthesized through solution combustion method.•The structural analysis revealed a hexagonal wurtzite structure of the materials.•Electromagnetic interference (EMI) shielding effect of synthesized material was investigated. Present research describes the use of so...

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Published in:Journal of molecular structure Vol. 1305; p. 137701
Main Authors: Jinendra, Usha, Bilehal, Dinesh, Nagabhushana, B.M., Kumar, Avvaru Praveen, Afzal, Mohd, Shivamallu, Chandan, Majani, Sanjay S, Kollur, Shiva Prasad
Format: Journal Article
Language:English
Published: Elsevier B.V 05-06-2024
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Abstract •Co/Al-doped ZnO nanoparticles were synthesized through solution combustion method.•The structural analysis revealed a hexagonal wurtzite structure of the materials.•Electromagnetic interference (EMI) shielding effect of synthesized material was investigated. Present research describes the use of solution combustion to create ZnO nanoparticles doped with Co and Al. The studies revealed that the synthesized Al/Co-doped ZnO nanopowder has a narrower size distribution, controllable shape, and high crystallinity. Powder X-Ray diffraction (XRD), Scanning Electron Microscopy (SEM), Fourier Transform Infrared spectroscopy (FTIR), and photoluminescence (PL) spectral techniques were utilized to characterize the as-prepared materials. Interestingly, Al-doped ZnO nanoparticles' UV emission peak location showed greater intensity than Co-doped ZnO, which is explained by an increase in non-radiative recombination. The energy gap plot calculates the Tauc gap, along with the color information defined by the CIE. The doping components were combined through mechanical mixing, and their impact on the effectiveness of the electromagnetic interference (EMI) shielding was examined. [Display omitted]
AbstractList •Co/Al-doped ZnO nanoparticles were synthesized through solution combustion method.•The structural analysis revealed a hexagonal wurtzite structure of the materials.•Electromagnetic interference (EMI) shielding effect of synthesized material was investigated. Present research describes the use of solution combustion to create ZnO nanoparticles doped with Co and Al. The studies revealed that the synthesized Al/Co-doped ZnO nanopowder has a narrower size distribution, controllable shape, and high crystallinity. Powder X-Ray diffraction (XRD), Scanning Electron Microscopy (SEM), Fourier Transform Infrared spectroscopy (FTIR), and photoluminescence (PL) spectral techniques were utilized to characterize the as-prepared materials. Interestingly, Al-doped ZnO nanoparticles' UV emission peak location showed greater intensity than Co-doped ZnO, which is explained by an increase in non-radiative recombination. The energy gap plot calculates the Tauc gap, along with the color information defined by the CIE. The doping components were combined through mechanical mixing, and their impact on the effectiveness of the electromagnetic interference (EMI) shielding was examined. [Display omitted]
ArticleNumber 137701
Author Jinendra, Usha
Shivamallu, Chandan
Afzal, Mohd
Nagabhushana, B.M.
Kumar, Avvaru Praveen
Kollur, Shiva Prasad
Bilehal, Dinesh
Majani, Sanjay S
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  surname: Jinendra
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  givenname: Dinesh
  surname: Bilehal
  fullname: Bilehal, Dinesh
  email: drbilehal@gmail.com
  organization: Department of Chemistry, Karnatak University, Dharwad, Karnataka 560 008, India
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  givenname: B.M.
  surname: Nagabhushana
  fullname: Nagabhushana, B.M.
  organization: Department of Chemistry, MSRIT, Bengaluru, Karnataka 560 054, India
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  givenname: Avvaru Praveen
  surname: Kumar
  fullname: Kumar, Avvaru Praveen
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  surname: Afzal
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  organization: Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
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  givenname: Chandan
  surname: Shivamallu
  fullname: Shivamallu, Chandan
  organization: Department of Biotechnology and Bioinformatics, School of Life Sciences, JSS Academy of Higher Education and Research, Myuru, Karnataka 570015, India
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  givenname: Sanjay S
  surname: Majani
  fullname: Majani, Sanjay S
  organization: School of Physical Sciences, Amrita Vishwa Vidyapeetham, Mysuru Campus, Mysuru, Karnataka 570 026, India
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  surname: Kollur
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  email: shivachemist@gmail.com
  organization: School of Physical Sciences, Amrita Vishwa Vidyapeetham, Mysuru Campus, Mysuru, Karnataka 570 026, India
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Snippet •Co/Al-doped ZnO nanoparticles were synthesized through solution combustion method.•The structural analysis revealed a hexagonal wurtzite structure of the...
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SubjectTerms Dopant
EMI shielding
Photoluminescence (PL) studies
SEM
XRD
Title Synthesis, characterization, and photoluminescence investigations of Al/Co-doped ZnO nanopowder
URI https://dx.doi.org/10.1016/j.molstruc.2024.137701
Volume 1305
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