Tetranuclear [Mn III Mn 3 IV O 4 ] Complexes as Spectroscopic Models of the S 2 State of the Oxygen Evolving Complex in Photosystem II

Despite extensive biochemical, spectroscopic, and computational studies, the mechanism of biological water oxidation by the oxygen evolving complex (OEC) of Photosystem II remains a subject of significant debate. Mechanistic proposals are guided by the characterization of reaction intermediates such...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 140; no. 49; pp. 17175 - 17187
Main Authors:	Lee, Heui Beom, Shiau, Angela A, Oyala, Paul H, Marchiori, David A, Gul, Sheraz, Chatterjee, Ruchira, Yano, Junko, Britt, R David, Agapie, Theodor
Format:	Journal Article
Language:	English
Published:	United States 12-12-2018
Subjects:	Biomimetic Materials - chemical synthesis Biomimetic Materials - chemistry Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Electrochemistry Electron Spin Resonance Spectroscopy Magnetic Phenomena Manganese - chemistry Molecular Structure Oxidation-Reduction Oxygen - chemistry Photosystem II Protein Complex - chemistry Temperature
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