Morphological transition in the cellular structure of single crystals of nickel-tungsten alloys near the congruent melting point

• Published in: Crystallography reports Vol. 50; no. S1; pp. S130 - S135
• Main Authors: Azhazha, V. M., Ladygin, A. N., Sverdlov, V. Ja, Zhemanyuk, P. D., Klochikhin, V. V.
• Format: Journal Article
• Language: English
• Published: United States 01-01-2005
• Subjects: BINARY ALLOY SYSTEMS; CRYSTAL GROWTH; CRYSTAL STRUCTURE; CRYSTALLIZATION; IMPURITIES; MATERIALS SCIENCE; MELTING POINTS; MICROHARDNESS; MICROSTRUCTURE; MONOCRYSTALS; MORPHOLOGY; NICKEL ALLOYS; TEMPERATURE GRADIENTS; TUNGSTEN ALLOYS
• DOI: 10.1134/1.2133988
• EISSN: 1562-689X
• ISSN: 1063-7745

The structure and microhardness of single crystals of nickel-tungsten alloys containing 25-36 wt % W are investigated. The temperature gradient at the crystallization front and the velocity of the crystallization front are the variable parameters of directional crystallization. It is found that, when the velocity of the crystallization front is 4 mm/min, the morphology of the cellular structure of the single crystals grown from nickel-tungsten alloys changes from square cells to hexagonal cells at a tungsten content of greater than or equal to 31 wt %. As the velocity of the crystallization front increases to 10 mm/min, no morphological transition occurs. It is shown that impurities play an important role in the formation of a cellular structure with cells of different types.