Light- and heat-induced shape deformation polyurethane actuators that combine self-healing capabilities
Materials commonly experience physical damage during regular usage, and the implementation of self-healing materials can effectively repair this damage, thereby prolonging the lifespan of the materials. We have successfully synthesized a polyurethane material, S-PU, by introducing azobenzene and rev...
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Published in: | Materials today communications Vol. 39; p. 109102 |
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01-06-2024
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Abstract | Materials commonly experience physical damage during regular usage, and the implementation of self-healing materials can effectively repair this damage, thereby prolonging the lifespan of the materials. We have successfully synthesized a polyurethane material, S-PU, by introducing azobenzene and reversible disulfide bonds through co-polymerization. The S-PU film not only exhibits light-induced bending, heat-induced recovery ability, but also good self-healing properties. The disulfide bonds in S-PU accelerate the dynamic exchange as the polymer chains flow under heated conditions, enabling self-repairing without affecting the mechanical properties of the material. S-PU is a self-repairing material that can repair damage in a variety of ways. By combining dual-stimulus response characteristics with self-healing properties, this work provides a new idea for self-healing materials and opens more directions for the practical application of the material.
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AbstractList | Materials commonly experience physical damage during regular usage, and the implementation of self-healing materials can effectively repair this damage, thereby prolonging the lifespan of the materials. We have successfully synthesized a polyurethane material, S-PU, by introducing azobenzene and reversible disulfide bonds through co-polymerization. The S-PU film not only exhibits light-induced bending, heat-induced recovery ability, but also good self-healing properties. The disulfide bonds in S-PU accelerate the dynamic exchange as the polymer chains flow under heated conditions, enabling self-repairing without affecting the mechanical properties of the material. S-PU is a self-repairing material that can repair damage in a variety of ways. By combining dual-stimulus response characteristics with self-healing properties, this work provides a new idea for self-healing materials and opens more directions for the practical application of the material.
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ArticleNumber | 109102 |
Author | Li, Naqi Zhang, Yujie Cui, Zhishuai Guan, Zhenghui Ren, Zhihui Dong, Chen |
Author_xml | – sequence: 1 givenname: Zhihui surname: Ren fullname: Ren, Zhihui email: renzhh@nwu.edu.cn – sequence: 2 givenname: Yujie surname: Zhang fullname: Zhang, Yujie – sequence: 3 givenname: Chen surname: Dong fullname: Dong, Chen – sequence: 4 givenname: Naqi surname: Li fullname: Li, Naqi – sequence: 5 givenname: Zhishuai surname: Cui fullname: Cui, Zhishuai – sequence: 6 givenname: Zhenghui surname: Guan fullname: Guan, Zhenghui email: guanzhh@nwu.edu.cn |
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Keywords | Stimulus-responsive Copolymerization Self-healing material |
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