Upconversion luminescence and temperature sensing characteristics of Ho3+/Yb3+ co-doped tellurite glasses

• Published in: Journal of non-crystalline solids Vol. 571; p. 121055
• Main Authors: Doğan, Anıl, Erdem, Murat, Esmer, Kadir, Eryürek, Gönül
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-11-2021
• Subjects: Color tunability; Optical thermometry; Telluride glasses; Upconversion; Optical thermometry; Color tunability; Upconversion; Telluride glasses
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/j.jnoncrysol.2021.121055

•Strong UC green, red, and IR emissions are observed under 975 nm excitation.•With pump power color coordinates shift from green to the red zone.•Maximum absolute temperature sensitivity is 0.011 K−1 observed at 503 K.
The upconversion emission spectra of Yb3+/Ho3+co-doped TeO2-ZnO-BaO glasses were studied for solid-state lighting and optical thermometry. The studied glasses were prepared using the melt quenching technique. The green and red UC emissions of Ho3+ions are due to two-photon absorptions, which cause the various energy transfer processes. The studied glasses show tunable color properties and high-temperature sensor sensitivity. Color coordinates on the CIE chromaticity diagram of those were affected by the pump power and shifted from green to red region at higher Ho3+concentrations. The 5F5 level and (3F4,5S2) levels of Ho3+ are found to be thermally coupled levels. The energy difference (ΔE) between these levels is calculated as 2463.66 cm−1. Among the studied glasses, Yb3+(3.0 mol%)/Ho3+(0.15 mol %) co-doped TeO2-ZnO-BaO show the highest absolute sensitivity of 0.011K−1 at 503K. In the light of conducted observations, the studied glasses are proposed as a good candidate material for lighting and optical temperature sensing.
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