Nitronyl-nitroxide PCP-pincer complexes of palladium and nickel: synthesis and an EPR study

The possibility of the application of nitronyl-nitroxide ligand (NIT) as a spin label for the study of the composition of transition metals complexes with M-NIT bonds by EPR spectroscopy was explored using PCP-pincer complexes of Pd and Ni as examples.

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Bibliographic Details
Published in:Russian chemical bulletin Vol. 71; no. 7; pp. 1527 - 1532
Main Authors: Kozhanov, K. A., Cherkasov, V. K., Bubnov, M. P.
Format: Journal Article
Language:English
Published: New York Springer US 01-07-2022
Springer Nature B.V
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Description
Summary:The possibility of the application of nitronyl-nitroxide ligand (NIT) as a spin label for the study of the composition of transition metals complexes with M-NIT bonds by EPR spectroscopy was explored using PCP-pincer complexes of Pd and Ni as examples.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-022-3560-9