Chemical vapor deposition of entropy-stabilized rock-salt type oxide thin films
•High-entropy oxide (MgCONiCuZn)O synthesized by CVD.•The entropy-stabilized phase is obtained after annealing at 950 °C.•The lattice parameters are close to those of the same material synthesized by solid state or PVD. Here we present the first synthesis of a multi-cationic oxide (MgCoNiCuZn)O by p...
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Published in: | Materials letters Vol. 337; p. 133955 |
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Abstract | •High-entropy oxide (MgCONiCuZn)O synthesized by CVD.•The entropy-stabilized phase is obtained after annealing at 950 °C.•The lattice parameters are close to those of the same material synthesized by solid state or PVD.
Here we present the first synthesis of a multi-cationic oxide (MgCoNiCuZn)O by pulsed liquid injection chemical vapor deposition. The synthesis is performed between 400 °C and 550 °C from five metal–organic precursors simultaneously solubilized in dimethoxyethane (DME). The microstructure of the material was studied using HRTEM with HAADF, SEM, EDS, XPS and XRD before and after annealing. |
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AbstractList | •High-entropy oxide (MgCONiCuZn)O synthesized by CVD.•The entropy-stabilized phase is obtained after annealing at 950 °C.•The lattice parameters are close to those of the same material synthesized by solid state or PVD.
Here we present the first synthesis of a multi-cationic oxide (MgCoNiCuZn)O by pulsed liquid injection chemical vapor deposition. The synthesis is performed between 400 °C and 550 °C from five metal–organic precursors simultaneously solubilized in dimethoxyethane (DME). The microstructure of the material was studied using HRTEM with HAADF, SEM, EDS, XPS and XRD before and after annealing. |
ArticleNumber | 133955 |
Author | Raison, Antoine Wang, Wu Prud'homme, Nathalie Dragoe, Diana Dragoe, Nita |
Author_xml | – sequence: 1 givenname: Antoine orcidid: 0000-0003-1590-7732 surname: Raison fullname: Raison, Antoine organization: Université Paris-Saclay, ICMMO, UMR 8182 CNRS, 91405 Orsay, France – sequence: 2 givenname: Nathalie surname: Prud'homme fullname: Prud'homme, Nathalie organization: Université Paris-Saclay, ICMMO, UMR 8182 CNRS, 91405 Orsay, France – sequence: 3 givenname: Wu surname: Wang fullname: Wang, Wu organization: Southern University of Science and Technology, Department of Physics, Shenzhen 518055, China – sequence: 4 givenname: Diana orcidid: 0000-0002-8536-1205 surname: Dragoe fullname: Dragoe, Diana organization: Université Paris-Saclay, ICMMO, UMR 8182 CNRS, 91405 Orsay, France – sequence: 5 givenname: Nita orcidid: 0000-0002-5142-9021 surname: Dragoe fullname: Dragoe, Nita email: nita.dragoe@universite-paris-saclay.fr organization: Université Paris-Saclay, ICMMO, UMR 8182 CNRS, 91405 Orsay, France |
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Cites_doi | 10.1016/0022-1902(67)80008-3 10.1063/1.5091787 10.1002/adma.201805004 10.1038/s41598-017-13810-5 10.1016/j.surfcoat.2012.12.017 10.1016/j.tsf.2007.03.089 10.1002/adem.200300567 10.1016/S0925-8388(96)02699-0 10.1111/jace.14756 10.1039/D1TC03287A 10.1557/mrc.2018.184 10.1016/j.jallcom.2017.02.070 10.1016/j.jeurceramsoc.2016.09.018 10.1039/C6TA03249D 10.1002/pssr.201600043 10.1038/ncomms9485 10.1016/j.jeurceramsoc.2020.12.021 10.1063/5.0003149 10.1107/S0021889813003531 |
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Snippet | •High-entropy oxide (MgCONiCuZn)O synthesized by CVD.•The entropy-stabilized phase is obtained after annealing at 950 °C.•The lattice parameters are close to... |
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SubjectTerms | Chemical vapor deposition High-entropy oxide Thin film |
Title | Chemical vapor deposition of entropy-stabilized rock-salt type oxide thin films |
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