Electrochemical study of the corrosion of a Ni-based alloy GH3535 in molten (Li,Na,K)F at 700°C

• Published in: Journal of fluorine chemistry Vol. 178; pp. 14 - 22
• Main Authors: Wang, Yanli, Liu, Huijun, Yu, Guojun, Hou, Juan, Zeng, Chaoliu
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-10-2015
• Subjects: Chromium fluorides; Corrosion; Electrochemical techniques; Molten fluorides; Ni-based alloy GH3535; Chromium fluorides; Electrochemical techniques; Corrosion; Ni-based alloy GH3535; Molten fluorides
• ISSN: 0022-1139; 1873-3328
• DOI: 10.1016/j.jfluchem.2015.06.014

•The corrosion of GH3535 goes on mainly by the preferential dissolution of Cr from the substrate.•The presence of 5%H2O in Ar promotes the cathodic and anodic reactions of GH3535 in molten (Li,Na,K)F.•CrF3 acts as an oxidizer to accelerate the dissolution of Cr from the substrate.
The compatibility of structural materials with molten fluoride salts is an immediate challenge for the application and development of molten salt reactor (MSR) operating at high temperatures. In the present presentation, the corrosion behavior of a nickel-based alloy GH3535 has been examined in an eutectic (Li,Na,K)F melt at 700°C under Ar and Ar-5%H2O, respectively, by some electrochemical techniques. Moreover, the effect of the additive CrF3 with concentrations of 0.09 and 0.18M on the corrosion of the alloy in the melt has also been investigated in an attempt to understand the corrosion mechanism involving the multivalent transition metal Cr ions Cr2+/Cr3+. It is shown that the alloy is in active dissolution state at the corrosion potential and its corrosion occurs mainly through the preferential dissolution of Cr from the substrate, producing a Cr-depleted layer and some internal voids. The introduction of 5%H2O in Ar accelerates obviously the corrosion of the alloy, giving rise to the formation of a wider Cr-depleted layer where some Cr-rich internal oxides are formed over the internal voids. CrF3 itself acts as an oxidizer to accelerate the dissolution of Cr, with a more significant effectiveness observed for a higher CrF3 content.