Dioxygenation of Sterically Hindered (Ethene)RhI and -IrI Complexes to (Peroxo)RhIII and (Ethene)(peroxo)IrIII Complexes

New cationic, five‐coordinate bis(ethene)iridium(I) complexes [(κ3‐Me3‐tpa)IrI(ethene)2]+ (12+) and [(κ3‐Me2‐dpa‐Me)IrI(ethene)2]+ (13+) have been prepared {Me3‐tpa = N,N,N‐tris[(6‐methyl‐2‐pyridyl)methyl]amine, Me2‐dpa‐Me = N‐methyl‐N,N‐bis[(6‐methyl‐2‐pyridyl)methyl]amine}. Complexes 12+ and 13+ l...

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Bibliographic Details

Published in:	European journal of inorganic chemistry Vol. 2002; no. 10; pp. 2671 - 2680
Main Authors:	de Bruin, Bas, Peters, Theo P. J., Wilting, Jos B. M., Thewissen, Simone, Smits, Jan M. M., Gal, Anton W.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 01-10-2002 WILEY‐VCH Verlag
Subjects:	Alkene ligands Iridium Oxidations O−O activation Peroxo ligands
Online Access:	Get full text
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