Microstructure, hardness, and wear resistance of annealed Fe-based bulk metallic glasses by spark plasma sintering

Aiming at the issues of small critical size and low glass forming ability of Fe-based amorphous alloys, this work focuses on solving the problem of preparing both large size and excellent properties. The highly dense FeCrMoBC bulk metallic glasses with diameter of 20 mm were prepared by spark plasma...

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Published in:Applied physics. A, Materials science & processing Vol. 130; no. 10
Main Authors: Dong, Weiwei, Dong, Minshuai, Peng, Junlong, Gong, Wendi, Zhu, Shigen
Format: Journal Article
Language:English
Published: Berlin/Heidelberg Springer Berlin Heidelberg 01-10-2024
Springer Nature B.V
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Abstract Aiming at the issues of small critical size and low glass forming ability of Fe-based amorphous alloys, this work focuses on solving the problem of preparing both large size and excellent properties. The highly dense FeCrMoBC bulk metallic glasses with diameter of 20 mm were prepared by spark plasma sintering, and the key role of heat treatment on the microstructure and properties of Fe-based bulk metallic glasses was investigated. The microstructure of Fe-based bulk metallic glasses was adjusted by annealing treatment, and the effects of annealing on the hardness and wear resistance of Fe-based bulk metallic glasses were studied. The results show that annealing induces partial crystallization of the alloy to construct in-situ amorphous nanocrystalline composites. After annealing at 650 °C for 1 h, Fe-based bulk metallic glasses precipitated Cr 23 C 6 and B 6 Fe 23 hard nanocrystalline phases. The highest Vickers hardness, highest fracture toughness, lowest friction coefficient, wear volume and wear rate were obtained, with values of 1514.68Hv, 2.81 MPa·m 1/2 ,0.59, 4.72 × 10 − 3 mm 3 and 2.62 × 10 − 6 mm 3 ·N − 1 ·m − 1 , respectively. Abrasive wear is the main form of wear, and the wear resistance is superior to that of GCr15. FeCrMoBC bulk metallic glasses exhibit outstanding hardness and wear resistance, providing new material options for the manufacture of high-performance advanced equipment.
AbstractList Aiming at the issues of small critical size and low glass forming ability of Fe-based amorphous alloys, this work focuses on solving the problem of preparing both large size and excellent properties. The highly dense FeCrMoBC bulk metallic glasses with diameter of 20 mm were prepared by spark plasma sintering, and the key role of heat treatment on the microstructure and properties of Fe-based bulk metallic glasses was investigated. The microstructure of Fe-based bulk metallic glasses was adjusted by annealing treatment, and the effects of annealing on the hardness and wear resistance of Fe-based bulk metallic glasses were studied. The results show that annealing induces partial crystallization of the alloy to construct in-situ amorphous nanocrystalline composites. After annealing at 650 °C for 1 h, Fe-based bulk metallic glasses precipitated Cr 23 C 6 and B 6 Fe 23 hard nanocrystalline phases. The highest Vickers hardness, highest fracture toughness, lowest friction coefficient, wear volume and wear rate were obtained, with values of 1514.68Hv, 2.81 MPa·m 1/2 ,0.59, 4.72 × 10 − 3 mm 3 and 2.62 × 10 − 6 mm 3 ·N − 1 ·m − 1 , respectively. Abrasive wear is the main form of wear, and the wear resistance is superior to that of GCr15. FeCrMoBC bulk metallic glasses exhibit outstanding hardness and wear resistance, providing new material options for the manufacture of high-performance advanced equipment.
Aiming at the issues of small critical size and low glass forming ability of Fe-based amorphous alloys, this work focuses on solving the problem of preparing both large size and excellent properties. The highly dense FeCrMoBC bulk metallic glasses with diameter of 20 mm were prepared by spark plasma sintering, and the key role of heat treatment on the microstructure and properties of Fe-based bulk metallic glasses was investigated. The microstructure of Fe-based bulk metallic glasses was adjusted by annealing treatment, and the effects of annealing on the hardness and wear resistance of Fe-based bulk metallic glasses were studied. The results show that annealing induces partial crystallization of the alloy to construct in-situ amorphous nanocrystalline composites. After annealing at 650 °C for 1 h, Fe-based bulk metallic glasses precipitated Cr23C6 and B6Fe23 hard nanocrystalline phases. The highest Vickers hardness, highest fracture toughness, lowest friction coefficient, wear volume and wear rate were obtained, with values of 1514.68Hv, 2.81 MPa·m1/2,0.59, 4.72 × 10− 3mm3 and 2.62 × 10− 6mm3·N− 1·m− 1, respectively. Abrasive wear is the main form of wear, and the wear resistance is superior to that of GCr15. FeCrMoBC bulk metallic glasses exhibit outstanding hardness and wear resistance, providing new material options for the manufacture of high-performance advanced equipment.
ArticleNumber 712
Author Dong, Weiwei
Peng, Junlong
Zhu, Shigen
Dong, Minshuai
Gong, Wendi
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Keywords Fe-based amorphous nanocrystalline composites
Spark plasma sintering
Vickers hardness
Wear resistance
Annealing treatment
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Snippet Aiming at the issues of small critical size and low glass forming ability of Fe-based amorphous alloys, this work focuses on solving the problem of preparing...
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SubjectTerms Abrasion resistance
Abrasive wear
Amorphous alloys
Amorphous materials
Annealing
Bulk density
Characterization and Evaluation of Materials
Coefficient of friction
Condensed Matter Physics
Crystallization
Diamond pyramid hardness
Fracture toughness
Heat treatment
Iron
Machines
Manufacturing
Metallic glasses
Microstructure
Nanotechnology
Optical and Electronic Materials
Particulate composites
Physics
Physics and Astronomy
Plasma sintering
Processes
Spark plasma sintering
Surfaces and Interfaces
Thin Films
Wear rate
Wear resistance
Title Microstructure, hardness, and wear resistance of annealed Fe-based bulk metallic glasses by spark plasma sintering
URI https://link.springer.com/article/10.1007/s00339-024-07884-y
https://www.proquest.com/docview/3103415907
Volume 130
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