Commercial turpentine oil enriched with α-terpineol using an acid heterogeneous catalyst

The hydration of α-pinene, limonene, β-pinene, and commercial turpentine oil in the presence of strong acidic cation exchange resin Amberlyst-15 was studied. The acid catalytic hydration was performed in a batch reactor, and the effect of solvent at various temperatures and reaction times was evalua...

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Published in:	Revista Facultad de Ingeniería
Main Authors:	Aguas-Caballero, Iván de Jesús, Villa-Holguín, Aída Luz, Alarcón-Durango, Edwin Alexis
Format:	Journal Article
Language:	English
Published:	Universidad de Antioquia 01-07-2024
Subjects:	a-pinene a-terpineol Amberlyst-15 hydration Turpentine
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Abstract	The hydration of α-pinene, limonene, β-pinene, and commercial turpentine oil in the presence of strong acidic cation exchange resin Amberlyst-15 was studied. The acid catalytic hydration was performed in a batch reactor, and the effect of solvent at various temperatures and reaction times was evaluated. The main hydration product obtained from α-pinene was α-terpineol with a yield of 36 % (4 h, 70 °C, 2-propanol as solvent); however, the selected catalytic system was even more active to obtain α-terpineol when β-pinene was used as a substrate, obtaining α-terpineol yield of 38 % in 2 h of reaction. For the hydration of turpentine (70 °C, turpentine:water:2-propanol mass ratio of 1:0.5:2, 15 % w/w catalyst) the composition of reaction mixture after 4 h was 35 % w/w of α-terpineol, 8 % w/w of α-pinene, and 0.5 % w/w of β –pinene, which correspond to a final content of α-terpineol similar to the concentration obtained when α-pinene was used as a substrate (36 % w/w).
AbstractList	The hydration of α-pinene, limonene, β-pinene, and commercial turpentine oil in the presence of strong acidic cation exchange resin Amberlyst-15 was studied. The acid catalytic hydration was performed in a batch reactor, and the effect of solvent at various temperatures and reaction times was evaluated. The main hydration product obtained from α-pinene was α-terpineol with a yield of 36 % (4 h, 70 °C, 2-propanol as solvent); however, the selected catalytic system was even more active to obtain α-terpineol when β-pinene was used as a substrate, obtaining α-terpineol yield of 38 % in 2 h of reaction. For the hydration of turpentine (70 °C, turpentine:water:2-propanol mass ratio of 1:0.5:2, 15 % w/w catalyst) the composition of reaction mixture after 4 h was 35 % w/w of α-terpineol, 8 % w/w of α-pinene, and 0.5 % w/w of β –pinene, which correspond to a final content of α-terpineol similar to the concentration obtained when α-pinene was used as a substrate (36 % w/w).
Author	Aguas-Caballero, Iván de Jesús Villa-Holguín, Aída Luz Alarcón-Durango, Edwin Alexis
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Title	Commercial turpentine oil enriched with α-terpineol using an acid heterogeneous catalyst
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