Reactions of an anionic chelate phosphane/borata-alkene ligand with [Rh(nbd)Cl] 2 , [Rh(CO) 2 Cl] 2 and [Ir(cod)Cl] 2

Borata-alkenes can serve as anionic olefin equivalent ligands in transition metal chemistry. A chelate ligand of this type is described and used for metal coordination. Deprotonation of the Mes P(CH ) B(C F ) frustrated Lewis pair in the α-CH[B] position gave the methylene-bridged phosphane/borata-a...

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Bibliographic Details

Published in:	Chemical science (Cambridge) Vol. 11; no. 28; pp. 7349 - 7355
Main Authors:	Watanabe, Kohei, Ueno, Atsushi, Tao, Xin, Škoch, Karel, Jie, Xiaoming, Vagin, Sergei, Rieger, Bernhard, Daniliuc, Constantin G, Letzel, Matthias C, Kehr, Gerald, Erker, Gerhard
Format:	Journal Article
Language:	English
Published:	England Royal Society of Chemistry 28-07-2020
Subjects:	Alkenes Anions Carbon monoxide Catalysts Chelates Crystallography Dimers Ligands Rhodium Transition metals
Online Access:	Get full text
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