[P 3N 3F 5NS(O)Cl] − and [{P 4N 4F 6(NS(Cl)N)} 2] 2−, the first chloro imino- and chloro bis(imino) sulfinates

In CH 3CN solution at −30 °C, [TAS] +[P 3N 3F 5NS(O)F] − ( 2) is formed from TASF and P 3N 3F 5NSO, the compound readily decomposes to give P 3N 3F 6 and [TAS] +[NSO] −. [TAS] +[P 3N 3F 5NS(O)Cl] − ( 3) and [TAS +] 2 [{P 4N 4F 6(NS(Cl)N)} 2] 2− ( 5) were prepared from TASCl and P 3N 3F 5NSO and 1,5-...

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Bibliographic Details
Published in:	Journal of fluorine chemistry Vol. 126; no. 7; pp. 1044 - 1047
Main Authors:	Kingston, Melanie, Lork, Enno, Viets, Detlef, Watson, Paul G., Mews, Rüdiger
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 01-07-2005
Subjects:	Bis(imino)sulfinates Iminosulfinates Phosphazenates Phosphazenophane TAS fluoride X-ray crystallography X-ray crystallography TAS fluoride Bis(imino)sulfinates Iminosulfinates Phosphazenates Phosphazenophane
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Summary:	In CH 3CN solution at −30 °C, [TAS] +[P 3N 3F 5NS(O)F] − ( 2) is formed from TASF and P 3N 3F 5NSO, the compound readily decomposes to give P 3N 3F 6 and [TAS] +[NSO] −. [TAS] +[P 3N 3F 5NS(O)Cl] − ( 3) and [TAS +] 2 [{P 4N 4F 6(NS(Cl)N)} 2] 2− ( 5) were prepared from TASCl and P 3N 3F 5NSO and 1,5-P 4N 4F 6(NSO) 2, respectively, and characterised by X-ray crystallography.
ISSN:	0022-1139 1873-3328
DOI:	10.1016/j.jfluchem.2005.03.009