What's Next for First Row Fluorometallacycles?

What's Next for First Row Fluorometallacycles?

Hydrocarbon‐derived metallacycles have been identified as key intermediates in a host of catalyzed transformations of unsaturated organic substrates. In contrast, our knowledge of analogous reactivity of fluorometallacycles is underdeveloped and largely confined to first row metals. Our summary of r...

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Bibliographic Details
Published in:Angewandte Chemie Vol. 136; no. 41
Main Authors: Baker, R. Tom, Mangin, Loïc P.
Format: Journal Article
Language:English
Published: Weinheim Wiley Subscription Services, Inc 07-10-2024
Subjects:
catalysis
fluoroalkenes
fluorometallacycles
Intermediates
mechanism
metal fluorocarbenes
Metals
Organometallic compounds
Substrates
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Description
Summary:Hydrocarbon‐derived metallacycles have been identified as key intermediates in a host of catalyzed transformations of unsaturated organic substrates. In contrast, our knowledge of analogous reactivity of fluorometallacycles is underdeveloped and largely confined to first row metals. Our summary of recent advances aims to inform young investigators of the exciting challenges offered by this pursuit. Key roles for fluorometallacycles in first row metal complex‐catalyzed reactions are summarized and several future prospects identified.
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.202410307