Recycling of collagen from solid tannery waste and prospective utilization as adhesives. [version 1; peer review: awaiting peer review]

• Published in: F1000 research Vol. 13; p. 1228
• Main Authors: Flores Tapia, Nelly Esther, Brito Moina, Hannibal, Peñafiel, Rodney, Pérez Aldás, Lander Vinicio
• Format: Journal Article
• Language: English
• Published: 2024
• Subjects: collagen; solid tannery wastes; animal glue; collagen adhesives; bio-adhesive; recycled
• ISSN: 2046-1402; 2046-1402
• DOI: 10.12688/f1000research.155450.1

Abstract
This study explores the innovative potential of recycled collagen derived from tannery waste for use in high-performance adhesive formulations. The leather industry generates significant amounts of solid waste, primarily from chromium-tanned leather, which poses substantial environmental challenges. Recent advancements in recycling techniques have opened new avenues for repurposing this waste, particularly through collagen extraction, which comprises about 30-35% of tannery residues. This research systematically reviews the methods and applications of collagen extraction, highlighting the material's versatility and environmental benefits when used as a bio-adhesive.
The review identifies key challenges such as low water resistance, shear strength, and adhesiveness in collagen-based adhesives compared to synthetic counterparts. However, innovative solutions are emerging, including the incorporation of silane coupling agents and cross-linking technologies that significantly improve the water resistance and mechanical properties of these adhesives. Economic analyses further support the viability of using tannery waste-derived collagen in adhesive production, aligning with global sustainability goals and reducing reliance on petrochemical-based adhesives.
Despite these advancements, the transition from laboratory research to commercial applications remains a significant challenge. Current studies primarily focus on small-scale experiments, with limited pilot-scale studies available. Nonetheless, the potential for collagen-based adhesives to replace harmful chemicals in industrial applications is promising, especially in sectors requiring biodegradable and non-toxic materials. This review concludes that while significant progress has been made, further research is necessary to overcome existing limitations and fully realize the commercial potential of collagen-based adhesives derived from tannery waste.