A Mononuclear and High-Spin Tetrahedral Ti II Complex

A high-spin, mononuclear Ti complex, [(Tp )TiCl] [Tp = hydridotris(3- -butyl-5-methylpyrazol-1-yl)borate], confined to a tetrahedral ligand-field environment, has been prepared by reduction of the precursor [(Tp )TiCl ] with KC . Complex [(Tp )TiCl] has a A ground state (assuming symmetry based on s...

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Bibliographic Details
Published in:Inorganic chemistry Vol. 59; no. 24; pp. 17834 - 17850
Main Authors: Reinholdt, Anders, Pividori, Daniel, Laughlin, Alexander L, DiMucci, Ida M, MacMillan, Samantha N, Jafari, Mehrafshan G, Gau, Michael R, Carroll, Patrick J, Krzystek, J, Ozarowski, Andrew, Telser, Joshua, Lancaster, Kyle M, Meyer, Karsten, Mindiola, Daniel J
Format: Journal Article
Language:English
Published: United States American Chemical Society (ACS) 21-12-2020
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