Front Cover: Photoinitiated Charge Transfer in a Triangular Silver(I) Hydride Complex and Its Oxophilicity (Chem. Eur. J. 48/2019)

UV‐induced hydride‐to‐silver elecTron transfer was evidenced by specific photofragments of mass‐selected dications of a bisphosphine‐stabilized triangular silver(I) hydride complex. The electronic transitions were authenticated by high‐level quantum chemical computations based on the GW method and B...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 25; no. 48; p. 11172
Main Authors:	Kruppa, Sebastian V., Groß, Cedric, Gui, Xin, Bäppler, Florian, Kwasigroch, Björn, Sun, Yu, Diller, Rolf, Klopper, Wim, Niedner‐Schatteburg, Gereon, Riehn, Christoph, Thiel, Werner R.
Format:	Journal Article
Language:	English
Published:	27-08-2019
Subjects:	charge transfer hydride ligands mass spectrometry metal–metal interactions photochemistry silver
Online Access:	Get full text
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Summary:	UV‐induced hydride‐to‐silver elecTron transfer was evidenced by specific photofragments of mass‐selected dications of a bisphosphine‐stabilized triangular silver(I) hydride complex. The electronic transitions were authenticated by high‐level quantum chemical computations based on the GW method and Bethe–Salpeter equation (GW‐BSE). The unique [Ag3(μ3‐H)]2+ scaffold, featuring argentophilic interaction, was unequivocally verified by 1H NMR spectroscopy in concert with X‐ray structural analysis and DFT. More information can be found in the Full Paper by C. Riehn, W. R. Thiel, et al. on page 11269.
Bibliography:	These authors contributed equally to this work.
ISSN:	0947-6539 1521-3765
DOI:	10.1002/chem.201903110