Facet-Controlled Cu 2 O Support Enhances Catalytic Activity of Pt Nanoparticles for CO Oxidation

Facet-Controlled Cu 2 O Support Enhances Catalytic Activity of Pt Nanoparticles for CO Oxidation

The metal-support interaction plays a crucial role in determining the catalytic activity of supported metal catalysts. Changing the facet of the support is a promising strategy for catalytic control via constructing a well-defined metal-support nanostructure. Herein, we developed cubic and octahedra...

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Published in:The journal of physical chemistry letters Vol. 14; no. 23; pp. 5241 - 5248
Main Authors: Hong, Seunghwa, Kim, Daeho, Kim, Ki-Jeong, Park, Jeong Young
Format: Journal Article
Language:English
Published: United States 15-06-2023
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Abstract The metal-support interaction plays a crucial role in determining the catalytic activity of supported metal catalysts. Changing the facet of the support is a promising strategy for catalytic control via constructing a well-defined metal-support nanostructure. Herein, we developed cubic and octahedral Cu O supports with (100) and (111) facets terminated, respectively, and Pt nanoparticles (NPs) were introduced. The characterizations revealed the facet-dependent encapsulation of the Pt NPs by a CuO layer due to the oxidation of the Cu O support during the CO oxidation reaction. The CuO layer on Pt at cubic Cu O (Pt/c-Cu O) significantly enhanced catalytic performance, while the thicker CuO layer on Pt at octahedral Cu O suppressed CO conversion. The formation of a thin CuO layer is attributed to the dominant Pt-O-Cu bond at the Pt/c-Cu O interface, which suppresses the adsorption of oxygen molecules. This investigation provides insight into designing high-performance catalysts via engineering the interface interaction.
AbstractList The metal-support interaction plays a crucial role in determining the catalytic activity of supported metal catalysts. Changing the facet of the support is a promising strategy for catalytic control via constructing a well-defined metal-support nanostructure. Herein, we developed cubic and octahedral Cu O supports with (100) and (111) facets terminated, respectively, and Pt nanoparticles (NPs) were introduced. The characterizations revealed the facet-dependent encapsulation of the Pt NPs by a CuO layer due to the oxidation of the Cu O support during the CO oxidation reaction. The CuO layer on Pt at cubic Cu O (Pt/c-Cu O) significantly enhanced catalytic performance, while the thicker CuO layer on Pt at octahedral Cu O suppressed CO conversion. The formation of a thin CuO layer is attributed to the dominant Pt-O-Cu bond at the Pt/c-Cu O interface, which suppresses the adsorption of oxygen molecules. This investigation provides insight into designing high-performance catalysts via engineering the interface interaction.
Author Kim, Ki-Jeong
Park, Jeong Young
Hong, Seunghwa
Kim, Daeho
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/37263187$$D View this record in MEDLINE/PubMed
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Cites_doi 10.1038/nchem.2911
10.1021/cr400311p
10.1149/1.1854126
10.1021/acscatal.6b01128
10.1038/nmat4500
10.1126/science.1207272
10.1007/BF00805583
10.1021/acscatal.8b03539
10.1016/j.apcatb.2019.117985
10.1002/anie.200803574
10.1038/s41467-020-17044-4
10.1021/acs.jpclett.2c00080
10.1002/anie.201303912
10.1021/acscatal.5b02617
10.1021/acscatal.1c02340
10.1103/PhysRevB.75.125420
10.1002/anie.201402374
10.1002/anie.201707842
10.1039/C7RA08952J
10.1039/C7RA05950G
10.1021/acs.jpcc.8b08494
10.1038/s41467-020-16674-y
10.1016/j.surfrep.2021.100532
10.1021/acscatal.7b04469
10.1021/acsnano.0c07549
10.1039/D1CC02728J
10.1016/j.apcatb.2023.122704
10.1039/D1CY01269J
10.1038/nature13249
10.1021/acs.jpcc.6b06158
10.1002/anie.202200763
10.1038/s41467-020-15965-8
10.1021/acscatal.6b01509
10.1002/anie.202106805
10.1016/j.apcata.2020.117712
10.1021/jp048867x
10.1021/ja4088743
10.1038/s41929-020-0459-4
10.1002/anie.201103698
10.1038/s41467-018-06903-w
10.1021/ja01014a016
10.1039/C9CC03770E
10.1021/ja3010978
10.3390/ijms24010810
10.1039/FT9969204595
10.1021/acsami.2c20832
10.1021/ja210083d
10.1021/acscatal.7b01951
10.1021/acscatal.3c00262
10.1038/nchem.2607
10.1021/ar400203e
10.1021/acscatal.0c02467
10.1016/0021-9517(84)90003-4
10.1016/j.apcatb.2019.03.081
10.1016/j.apcatb.2020.119716
10.1038/nmat3017
10.1021/acscatal.6b02963
10.1103/PhysRevLett.89.046101
10.1016/j.jcat.2018.08.026
10.1039/C8CE02164C
10.1021/jp1004314
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References ref9/cit9
ref45/cit45
ref3/cit3
ref27/cit27
ref56/cit56
ref16/cit16
ref52/cit52
ref23/cit23
ref8/cit8
ref31/cit31
ref59/cit59
ref2/cit2
ref34/cit34
ref37/cit37
ref20/cit20
ref48/cit48
ref60/cit60
ref17/cit17
ref10/cit10
ref35/cit35
ref53/cit53
ref19/cit19
ref21/cit21
ref42/cit42
ref46/cit46
ref49/cit49
ref13/cit13
ref61/cit61
ref24/cit24
ref38/cit38
ref50/cit50
ref54/cit54
ref6/cit6
ref36/cit36
ref18/cit18
ref11/cit11
ref25/cit25
ref29/cit29
ref32/cit32
ref39/cit39
ref14/cit14
ref57/cit57
ref5/cit5
ref51/cit51
ref43/cit43
ref28/cit28
ref40/cit40
ref26/cit26
ref55/cit55
ref12/cit12
ref15/cit15
ref41/cit41
ref58/cit58
ref22/cit22
ref33/cit33
ref4/cit4
ref30/cit30
ref47/cit47
ref1/cit1
ref44/cit44
ref7/cit7
References_xml – ident: ref20/cit20
  doi: 10.1038/nchem.2911
– ident: ref14/cit14
  doi: 10.1021/cr400311p
– ident: ref31/cit31
  doi: 10.1149/1.1854126
– ident: ref53/cit53
  doi: 10.1021/acscatal.6b01128
– ident: ref25/cit25
  doi: 10.1038/nmat4500
– ident: ref2/cit2
  doi: 10.1126/science.1207272
– ident: ref56/cit56
  doi: 10.1007/BF00805583
– ident: ref3/cit3
  doi: 10.1021/acscatal.8b03539
– ident: ref57/cit57
  doi: 10.1016/j.apcatb.2019.117985
– ident: ref19/cit19
  doi: 10.1002/anie.200803574
– ident: ref7/cit7
  doi: 10.1038/s41467-020-17044-4
– ident: ref48/cit48
  doi: 10.1021/acs.jpclett.2c00080
– ident: ref37/cit37
  doi: 10.1002/anie.201303912
– ident: ref22/cit22
  doi: 10.1021/acscatal.5b02617
– ident: ref17/cit17
  doi: 10.1021/acscatal.1c02340
– ident: ref50/cit50
  doi: 10.1103/PhysRevB.75.125420
– ident: ref35/cit35
  doi: 10.1002/anie.201402374
– ident: ref11/cit11
  doi: 10.1002/anie.201707842
– ident: ref52/cit52
  doi: 10.1039/C7RA08952J
– ident: ref45/cit45
  doi: 10.1039/C7RA05950G
– ident: ref49/cit49
  doi: 10.1021/acs.jpcc.8b08494
– ident: ref27/cit27
  doi: 10.1038/s41467-020-16674-y
– ident: ref15/cit15
  doi: 10.1016/j.surfrep.2021.100532
– ident: ref26/cit26
  doi: 10.1021/acscatal.7b04469
– ident: ref16/cit16
  doi: 10.1021/acsnano.0c07549
– ident: ref29/cit29
  doi: 10.1039/D1CC02728J
– ident: ref40/cit40
  doi: 10.1016/j.apcatb.2023.122704
– ident: ref28/cit28
  doi: 10.1039/D1CY01269J
– ident: ref34/cit34
  doi: 10.1038/nature13249
– ident: ref42/cit42
  doi: 10.1021/acs.jpcc.6b06158
– ident: ref59/cit59
  doi: 10.1002/anie.202200763
– ident: ref21/cit21
  doi: 10.1038/s41467-020-15965-8
– ident: ref23/cit23
  doi: 10.1021/acscatal.6b01509
– ident: ref24/cit24
  doi: 10.1002/anie.202106805
– ident: ref44/cit44
  doi: 10.1016/j.apcata.2020.117712
– ident: ref43/cit43
  doi: 10.1021/jp048867x
– ident: ref1/cit1
  doi: 10.1021/ja4088743
– ident: ref4/cit4
  doi: 10.1038/s41929-020-0459-4
– ident: ref36/cit36
  doi: 10.1002/anie.201103698
– ident: ref8/cit8
  doi: 10.1038/s41467-018-06903-w
– ident: ref13/cit13
  doi: 10.1021/ja01014a016
– ident: ref47/cit47
  doi: 10.1039/C9CC03770E
– ident: ref33/cit33
  doi: 10.1021/ja3010978
– ident: ref41/cit41
  doi: 10.3390/ijms24010810
– ident: ref54/cit54
  doi: 10.1039/FT9969204595
– ident: ref51/cit51
  doi: 10.1021/acsami.2c20832
– ident: ref9/cit9
  doi: 10.1021/ja210083d
– ident: ref10/cit10
  doi: 10.1021/acscatal.7b01951
– ident: ref61/cit61
  doi: 10.1021/acscatal.3c00262
– ident: ref5/cit5
  doi: 10.1038/nchem.2607
– ident: ref46/cit46
  doi: 10.1021/ar400203e
– ident: ref58/cit58
  doi: 10.1021/acscatal.0c02467
– ident: ref55/cit55
  doi: 10.1016/0021-9517(84)90003-4
– ident: ref38/cit38
  doi: 10.1016/j.apcatb.2019.03.081
– ident: ref60/cit60
  doi: 10.1016/j.apcatb.2020.119716
– ident: ref32/cit32
  doi: 10.1038/nmat3017
– ident: ref12/cit12
  doi: 10.1021/acscatal.6b02963
– ident: ref18/cit18
  doi: 10.1103/PhysRevLett.89.046101
– ident: ref6/cit6
  doi: 10.1016/j.jcat.2018.08.026
– ident: ref39/cit39
  doi: 10.1039/C8CE02164C
– ident: ref30/cit30
  doi: 10.1021/jp1004314
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Snippet The metal-support interaction plays a crucial role in determining the catalytic activity of supported metal catalysts. Changing the facet of the support is a...
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