Exploring the benefits of surface analysis techniques to develop double multilayer transfer printing of J-Aggregates cyanine dyes by integrating L-b-L and μCp processes

Layer-by-layer self-assembly (L-b-L assembly) makes possible to obtain polyelectrolyte multilayers (PEMs) and one of the polyelectrolytes could be replaced by a dye molecule to obtain multilayers which may exhibit optical properties of great interest. On the other hand, mu Cp has become a routine te...

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Published in:	Talanta (Oxford) Vol. 250; p. 123731
Main Authors:	Minot, Sylvain, Gablin, Corinne, Gassenq, Alban, Bard, Antoine, Symonds, Clémentine, Benoit, Jean-Michel, Bellessa, Joël, Leonard, Didier, Bessueille, François
Format:	Journal Article
Language:	English
Published:	Elsevier 01-12-2022
Subjects:	Analytical chemistry Chemical Sciences Double printing J-agg cyanine dyes Microcontact printing Surface Imaging Multilayer transfer printing Layer-by-layer
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Abstract	Layer-by-layer self-assembly (L-b-L assembly) makes possible to obtain polyelectrolyte multilayers (PEMs) and one of the polyelectrolytes could be replaced by a dye molecule to obtain multilayers which may exhibit optical properties of great interest. On the other hand, mu Cp has become a routine technique for the preparation of micro -and nanostructured surfaces. In our development in progress of a surface engineering strategy to transfer J-Agg cyanine dyes onto surfaces by integrating L-b-L process and mu Cp, this contribution highlights how surface analysis imaging techniques can bring valuable information for the development of the process involving a double Multilayers Transfer Printing (MTP) with a Moire ' effect. Key parameters sustaining image interpretation are difference in deposit thickness (optical microscopy, atomic force microscopy, scanning electron microscopy), in roughness (atomic force microscopy and scanning electron microscopy), in charge effect (scanning electron microscopy) and the chemical contrast between unprinted and printed areas (time-of-flight secondary ion mass spectrometry).
AbstractList	Layer-by-layer self-assembly (L-b-L assembly) makes possible to obtain polyelectrolyte multilayers (PEMs) and one of the polyelectrolytes could be replaced by a dye molecule to obtain multilayers which may exhibit optical properties of great interest. On the other hand, mu Cp has become a routine technique for the preparation of micro -and nanostructured surfaces. In our development in progress of a surface engineering strategy to transfer J-Agg cyanine dyes onto surfaces by integrating L-b-L process and mu Cp, this contribution highlights how surface analysis imaging techniques can bring valuable information for the development of the process involving a double Multilayers Transfer Printing (MTP) with a Moire ' effect. Key parameters sustaining image interpretation are difference in deposit thickness (optical microscopy, atomic force microscopy, scanning electron microscopy), in roughness (atomic force microscopy and scanning electron microscopy), in charge effect (scanning electron microscopy) and the chemical contrast between unprinted and printed areas (time-of-flight secondary ion mass spectrometry).
ArticleNumber	123731
Author	Minot, Sylvain Benoit, Jean-Michel Gablin, Corinne Gassenq, Alban Bellessa, Joël Bessueille, François Bard, Antoine Symonds, Clémentine Leonard, Didier
Author_xml	– sequence: 1 givenname: Sylvain surname: Minot fullname: Minot, Sylvain – sequence: 2 givenname: Corinne surname: Gablin fullname: Gablin, Corinne – sequence: 3 givenname: Alban surname: Gassenq fullname: Gassenq, Alban – sequence: 4 givenname: Antoine surname: Bard fullname: Bard, Antoine – sequence: 5 givenname: Clémentine surname: Symonds fullname: Symonds, Clémentine – sequence: 6 givenname: Jean-Michel surname: Benoit fullname: Benoit, Jean-Michel – sequence: 7 givenname: Joël surname: Bellessa fullname: Bellessa, Joël – sequence: 8 givenname: Didier surname: Leonard fullname: Leonard, Didier – sequence: 9 givenname: François surname: Bessueille fullname: Bessueille, François
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Keywords	Double printing J-agg cyanine dyes Microcontact printing Surface Imaging Multilayer transfer printing Layer-by-layer
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Snippet	Layer-by-layer self-assembly (L-b-L assembly) makes possible to obtain polyelectrolyte multilayers (PEMs) and one of the polyelectrolytes could be replaced by...
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Title	Exploring the benefits of surface analysis techniques to develop double multilayer transfer printing of J-Aggregates cyanine dyes by integrating L-b-L and μCp processes
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