Mixed Azide-Terminated Monolayers: A Platform for Modifying Electrode Surfaces

We have prepared and characterized mixed self-assembled monolayers (SAM) on gold electrodes from azido alkane thiols and various ω-functionalized alkane thiols. In the presence of copper(I) catalysts, these azide-modified surfaces are shown to react rapidly and quantitatively with terminal acetylene...

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Bibliographic Details
Published in:	Langmuir Vol. 22; no. 6; pp. 2457 - 2464
Main Authors:	Collman, James P, Devaraj, Neal K, Eberspacher, Todd P. A, Chidsey, Christopher E. D
Format:	Journal Article
Language:	English
Published:	Washington, DC American Chemical Society 14-03-2006
Subjects:	Azides - chemistry Catalysis Chemistry Electrochemistry - instrumentation Electrodes Exact sciences and technology General and physical chemistry Spectrum Analysis - methods Surface Properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Photoelectron Self assembly Monolayer Gold Surface reaction Thiol Hydrocarbon Reaction order Transition metal Modified catalyst X ray Metallocene Acetylene Electrodes Azides Mixed monolayer Chemistry Alkane Electrochemistry Reaction time Copper I Rate constant
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