Higher-order Efficiency Bound and Its Application to Nonlinear Nano-thermoelectrics

Power and efficiency of heat engines are two conflicting objectives, and a tight efficiency bound is expected to give insights on the fundamental properties of the power-efficiency tradeoff. Here we derive an upper bound on the efficiency of steady-state heat engines, which incorporates higher-order...

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Main Authors: Kamijima, Takuya, Otsubo, Shun, Ashida, Yuto, Sagawa, Takahiro
Format: Journal Article
Language:English
Published: 11-03-2021
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Abstract Power and efficiency of heat engines are two conflicting objectives, and a tight efficiency bound is expected to give insights on the fundamental properties of the power-efficiency tradeoff. Here we derive an upper bound on the efficiency of steady-state heat engines, which incorporates higher-order fluctuations of the power. In a prototypical model of nonlinear nanostructured thermoelectrics, we show that the obtained bound is tighter than a well-established efficiency bound based on the thermodynamic uncertainty relation, demonstrating that the higher-order terms have rich information about the thermodynamic efficiency in the nonlinear regime. In particular, we find that the higher-order bound is exactly achieved if the tight coupling condition is satisfied. The obtained bound gives a consistent prediction with the observation that nonlinearity enhances the power-efficiency tradeoff, and would also be useful for various nanoscale engines.
AbstractList Power and efficiency of heat engines are two conflicting objectives, and a tight efficiency bound is expected to give insights on the fundamental properties of the power-efficiency tradeoff. Here we derive an upper bound on the efficiency of steady-state heat engines, which incorporates higher-order fluctuations of the power. In a prototypical model of nonlinear nanostructured thermoelectrics, we show that the obtained bound is tighter than a well-established efficiency bound based on the thermodynamic uncertainty relation, demonstrating that the higher-order terms have rich information about the thermodynamic efficiency in the nonlinear regime. In particular, we find that the higher-order bound is exactly achieved if the tight coupling condition is satisfied. The obtained bound gives a consistent prediction with the observation that nonlinearity enhances the power-efficiency tradeoff, and would also be useful for various nanoscale engines.
Author Ashida, Yuto
Sagawa, Takahiro
Otsubo, Shun
Kamijima, Takuya
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  givenname: Yuto
  surname: Ashida
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  givenname: Takahiro
  surname: Sagawa
  fullname: Sagawa, Takahiro
BackLink https://doi.org/10.48550/arXiv.2103.06554$$DView paper in arXiv
https://doi.org/10.1103/PhysRevE.104.044115$$DView published paper (Access to full text may be restricted)
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Snippet Power and efficiency of heat engines are two conflicting objectives, and a tight efficiency bound is expected to give insights on the fundamental properties of...
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SubjectTerms Physics - Mesoscale and Nanoscale Physics
Physics - Statistical Mechanics
Title Higher-order Efficiency Bound and Its Application to Nonlinear Nano-thermoelectrics
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