Enantioselective Si–H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes

We report the first example of enantioselective, intermolecular diarylcarbene insertion into Si–H bonds for the synthesis of silicon-stereogenic silanes. Dirhodium­(II) carboxylates catalyze an Si–H insertion using carbenes derived from diazo compounds where selective formation of an enantioenriched...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 142; no. 27; pp. 11674 - 11679
Main Authors:	Jagannathan, Jake R, Fettinger, James C, Shaw, Jared T, Franz, Annaliese K
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 08-07-2020
Subjects:	Catalysis Hydrogen - chemistry Methane - analogs & derivatives Methane - chemistry Molecular Structure Organometallic Compounds - chemistry Silanes - chemical synthesis Silanes - chemistry Silicon - chemistry Stereoisomerism
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