A Copper(I)-Catalyzed Radical-Relay Reaction Enabling the Intermolecular 1,2-Alkylborylation of Unactivated Olefins

The first catalytic intermolecular 1,2-alkylborylation reaction via a radical-relay mechanism between unactivated olefins, bis­(pinacolato)­diboron, and an alkyl electrophile is reported. Successful implementation of this method requires that the competing boryl substitution of the alkyl electrophil...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 143; no. 13; pp. 5260 - 5268
Main Authors:	Akiyama, Sota, Oyama, Natsuki, Endo, Tsubura, Kubota, Koji, Ito, Hajime
Format:	Journal Article
Language:	English
Published:	United States American Chemical Society 07-04-2021
Online Access:	Get full text
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