Evolution of Solid Phase Homochirality for a Proteinogenic Amino Acid
The inexorable evolution of solid-phase single chirality is demonstrated for the first time for a proteinogenic amino acid. Enantioenrichment is observed both under attrition-enhanced conditions and without the aid of particle grinding. Differences in the form of the conversion profiles for the proc...
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| Published in: | Journal of the American Chemical Society Vol. 130; no. 46; pp. 15274 - 15275 |
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| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
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American Chemical Society
19-11-2008
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| Abstract | The inexorable evolution of solid-phase single chirality is demonstrated for the first time for a proteinogenic amino acid. Enantioenrichment is observed both under attrition-enhanced conditions and without the aid of particle grinding. Differences in the form of the conversion profiles for the process under the two sets of conditions provide suggestions concerning the mechanism of the transformation. |
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| AbstractList | The inexorable evolution of solid-phase single chirality is demonstrated for the first time for a proteinogenic amino acid. Enantioenrichment is observed both under attrition-enhanced conditions and without the aid of particle grinding. Differences in the form of the conversion profiles for the process under the two sets of conditions provide suggestions concerning the mechanism of the transformation. |
| Author | Viedma, Cristobal Ortiz, José E Izumi, Toshiko Torres, Trinidad de Blackmond, Donna G |
| Author_xml | – sequence: 1 givenname: Cristobal surname: Viedma fullname: Viedma, Cristobal – sequence: 2 givenname: José E surname: Ortiz fullname: Ortiz, José E – sequence: 3 givenname: Trinidad de surname: Torres fullname: Torres, Trinidad de – sequence: 4 givenname: Toshiko surname: Izumi fullname: Izumi, Toshiko – sequence: 5 givenname: Donna G surname: Blackmond fullname: Blackmond, Donna G |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/18954052$$D View this record in MEDLINE/PubMed |
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| Copyright | Copyright © 2008 American Chemical Society |
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| Snippet | The inexorable evolution of solid-phase single chirality is demonstrated for the first time for a proteinogenic amino acid. Enantioenrichment is observed both... |
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| SubjectTerms | Amino Acids - chemistry Molecular Structure Proteins - chemistry Stereoisomerism |
| Title | Evolution of Solid Phase Homochirality for a Proteinogenic Amino Acid |
| URI | http://dx.doi.org/10.1021/ja8074506 https://api.istex.fr/ark:/67375/TPS-0VWDVNTQ-7/fulltext.pdf https://www.ncbi.nlm.nih.gov/pubmed/18954052 https://search.proquest.com/docview/69783496 |
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