New type of atropisomerism in metal complexes. Preparation and resolution of (3,4-diacetyl-2,5-hexanedionato)bis[(2,2',2"-triaminotriethylamine)cobalt(III)] ion

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Published in:Journal of the American Chemical Society Vol. 108; no. 24; pp. 7630 - 7632
Main Authors: Nakano, Yoshiharu, Yoshikawa, Yuzo, Kondo, Hiroshi
Format: Journal Article
Language:English
Published: Washington, DC American Chemical Society 01-11-1986
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Author Kondo, Hiroshi
Yoshikawa, Yuzo
Nakano, Yoshiharu
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  surname: Yoshikawa
  fullname: Yoshikawa, Yuzo
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  givenname: Hiroshi
  surname: Kondo
  fullname: Kondo, Hiroshi
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Issue 24
Keywords Cationic complex
Circular dichroism spectrum
Molecular structure
Cobalt III Complexes
Organic ligand
Experimental study
Absorption spectrum
Inorganic compound
Atropoisomerism
Optical resolution
Complexes Mixed
Saturated aliphatic compound
Enantiomer
Absolute configuration
Ultraviolet visible spectrum
Electronic transition
Tetraketone
NMR spectrum
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PublicationTitle Journal of the American Chemical Society
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PublicationYear 1986
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SubjectTerms Atomic and molecular physics
Exact sciences and technology
General molecular conformation and symmetry; stereochemistry
Molecular properties and interactions with photons
Physics
Properties of molecules and molecular ions
Title New type of atropisomerism in metal complexes. Preparation and resolution of (3,4-diacetyl-2,5-hexanedionato)bis[(2,2',2"-triaminotriethylamine)cobalt(III)] ion
URI http://dx.doi.org/10.1021/ja00284a029
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