New type of atropisomerism in metal complexes. Preparation and resolution of (3,4-diacetyl-2,5-hexanedionato)bis[(2,2',2"-triaminotriethylamine)cobalt(III)] ion

• Published in: Journal of the American Chemical Society Vol. 108; no. 24; pp. 7630 - 7632
• Main Authors: Nakano, Yoshiharu, Yoshikawa, Yuzo, Kondo, Hiroshi
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 01-11-1986
• Subjects: Atomic and molecular physics; Exact sciences and technology; General molecular conformation and symmetry; stereochemistry; Molecular properties and interactions with photons; Physics; Properties of molecules and molecular ions; Cationic complex; Circular dichroism spectrum; Molecular structure; Cobalt III Complexes; Organic ligand; Experimental study; Absorption spectrum; Inorganic compound; Atropoisomerism; Optical resolution; Complexes Mixed; Saturated aliphatic compound; Enantiomer; Absolute configuration; Ultraviolet visible spectrum; Electronic transition; Tetraketone; NMR spectrum
• ISSN: 0002-7863; 1520-5126
• DOI: 10.1021/ja00284a029